The invention claimed is:
1 . A bundled yarn, comprising:
plural fibers integrated by a sizing agent, wherein the sizing agent is a modified polyvinyl alcohol comprising a plurality of a structural unit (X) comprising a carboxylate unit, derived from an unsaturated carboxylic acid or derivative thereof in polymerized form, in range of from 2 to 9 mol. %, taking an amount of all monomer units as 100 mol. %, wherein the structural unit (X) comprises a structural unit of formula (X1) and (X2):
X being H or a methyl group and Y being H, an alkali metal atom, or an alkyl group having 1 to 5 carbon atoms,
wherein an X1/(X1+X2) molar amount ratio is in a range of from 0.90 to 0.99,
wherein the modified polyvinyl alcohol has a saponification degree of 85 mol. % or higher, and
wherein the bundled yarn has a fiber separation degree of 90% or higher.
2 . The bundled yarn of claim 1 , wherein the modified polyvinyl alcohol has a viscosity-average polymerization degree in a range of from 100 to 5,000.
3 . The bundled yarn of claim 1 , wherein the saponification degree of the modified poly vinyl alcohol is in a range of from 88 to 100 mol. %.
4 . The bundled yarn of claim 1 , wherein the unsaturated carboxylic acid or derivative thereof comprises a (meth)acrylic acid, a (meth)acrylic acid alkyl ester, a (meth)acrylic acid metal salt, or a mixture of two or more of any of these.
5 . The bundled yarn of claim 1 , wherein, in formula (X1) and/or (X2)
X is a methyl group.
6 . The bundled yarn of claim 1 , wherein the plural fibers are poly vinyl alcohol fibers.
7 . The bundled yarn of claim 1 , wherein the plural fibers have an average fiber diameter in a range of from 3 to 900 μm.
8 . The bundled yarn of claim 1 , wherein the plural fibers have an aspect ratio in a range of from 50 to 2,500.
9 . The bundled yarn of claim 1 , having a fiber agglomeration degree of 10% or lower.
10 . The bundled yarn of claim 1 , wherein the saponification degree of the modified polyvinyl alcohol is in a range of from 90 to 99.9 mol. %.
11 . The bundled yarn of claim 1 , wherein the saponification degree of the modified polyvinyl alcohol is in a range of from 95 to 99.8 mol. %.
12 . The bundled yarn of claim 1 , wherein the modified polyvinyl alcohol has a viscosity-average polymerization degree in a range of from 100 to 4,000.
13 . The bundled yarn of claim 1 , wherein the modified polyvinyl alcohol has a viscosity-average polymerization degree in a range of from 300 to 3,500.
14 . The bundled yarn of claim 1 , wherein, in formula (X1) and (X2), X is H.
15 . The bundled yarn of claim 1 , wherein, in formula (X1) and (X2), X is a methyl group.
16 . The bundled yarn of claim 1 , wherein, in formula (X1) and/or (X2), Y is an alkyl group having 1 to 5 carbon atoms.
17 . The bundled yarn of claim 1 , wherein, in formula (X1) and/or (X2), Y is H.
18 . The bundled yarn of claim 1 , wherein, in formula (X1) and/or (X2), Y is an alkali metal atom.
19 . A hydraulic composition, comprising:
the bundled yarn of claim 1 ; a cement component; an aggregate; and water.
20 . A molded body, obtained by curing the hydraulic composition of claim 19 .