Carbon dioxide reaction apparatus

Patent metadata

Field	Value
Publication number	US-12522934-B2
Application number	US-202318301711-A
Country	US
Kind code	B2
Filing date	Apr 17, 2023
Priority date	Mar 23, 2020
Publication date	Jan 13, 2026
Grant date	Jan 13, 2026

Abstract

CO 2 reaction methods may include: supplying CO 2 -containing gas to a first accommodation part (AP) of an electrochemical reaction cell (ERC) from a first supply unit, the ERC including the first AP, a second AP, a cathode in the first AP, and an anode in the second AP; supplying an electrolytic solution containing H 2 O to the second AP; controlling ERC temperature to 60 to 150° C. so discharged gas and discharged solution discharged from the first and second APs are 60 to 100° C.; supplying current to the electrodes, reducing the CO 2 at the reduction electrode and discharge gas from the first AP, and oxidizing H 2 O and discharge the solution containing O 2 and CO 2 from the second AP; separating O 2 and CO 2 gas from the discharged solution; combusting the O 2 to produce CO 2 , and discharging mixed-CO 2 gas containing combustion CO 2 and CO 2 ; and supplying the mixed-CO 2 gas to the first AP.

First claim

What is claimed is:

1 . A carbon dioxide reaction method, comprising:
separating and recovering carbon dioxide gas from a CO 2 generation source to obtain a separated and recovered gas containing carbon dioxide; supplying the separated and recovered gas containing carbon dioxide to a first accommodation part of an electrochemical reaction cell from a first supply unit, the electrochemical reaction cell including the first accommodation part, a second accommodation part, a diaphragm provided between the first accommodation part and the second accommodation part, a reduction electrode arranged in the first accommodation part, and an oxidation electrode arranged in the second accommodation part; supplying an electrolytic solution containing water to the second accommodation part of the electrochemical reaction cell; controlling a temperature of the electrochemical reaction cell in a range of from 60° C. to 150° C. so that temperatures of a discharged gas discharged from the first accommodation part and a discharged solution discharged from the second accommodation part become a temperature in a range of from 60° C. to 100° C.; supplying an electric current from a power supply to the reduction electrode and the oxidation electrode, to reduce the carbon dioxide in the reduction electrode and discharge the discharged gas having the temperature in a range of from 60° C. to 100° C. from the first accommodation part, and to oxidize water in the oxidation electrode and discharge the discharged solution containing oxygen and first carbon dioxide, which moves to the second accommodation part from the first accommodation part through the diaphragm, and having the temperature in a range of from 60° C. to 100° C. from the second accommodation part; separating a gas component containing oxygen and the first carbon dioxide and a solution component in the discharged solution; combusting the gas component containing the oxygen and the first carbon dioxide of the discharged solution from the second accommodation part to produce second carbon dioxide by combusting the oxygen, and discharging a mixing carbon dioxide gas containing the second carbon dioxide, produced by combustion, and the first carbon dioxide contained originally in the gas component, the gas component being combusted in a boiler different from the CO 2 generation source connected to the second accommodation part via a gas/liquid separation part which separates the gas component and the solution component; and mixing the second carbon dioxide with the separated and recovered gas containing carbon dioxide to be supplied to the first accommodation part.

2 . The method of claim 1 , wherein the temperature of the electrochemical reaction cell is controlled in a range of from 80° C. to 150° C.

3 . The method of claim 1 , wherein a current density of the electric current supplied from the power supply is 100 mA/cm 2 or more and 1.5 A/cm 2 or less.

4 . The method of claim 1 , wherein a volume ratio of carbon dioxide and oxygen in the gas component of the discharged solution is CO 2 :O 2 is in a range of from 4:6 to 8:2.

Assignees

• Toshiba Kk

Inventors

• Mikoshiba Satoshi
• MOTOSHIGE Asahi
• Kitagawa Ryota
• Ono Akihiko
• Kofuji Yusuke
• Kudo Yuki

Classifications

• C25B9/77

  having diaphragms · CPC title

• C25B9/19

  with diaphragms · CPC title

• C25B3/26

  of carbon dioxide · CPC title

• C25B15/087

  Recycling of electrolyte to electrochemical cell · CPC title

• C25B15/083

  Separating products · CPC title