Multilayer dissolvable solid article with specific aspect ratio

Patent metadata

Field	Value
Publication number	US-12522788-B2
Application number	US-202117368893-A
Country	US
Kind code	B2
Filing date	Jul 7, 2021
Priority date	Jan 15, 2019
Publication date	Jan 13, 2026
Grant date	Jan 13, 2026

Abstract

This provides an improved dissolvable solid article with a specific aspect ratio. Such dissolvable solid article has a multilayer structure comprising two or more flexible, dissolvable, porous sheets, while each of which comprises a water-soluble polymer and a surfactant and is characterized by a Percent Open Cell Content of from 80% to 100% and an Overall Average Pore Size of from 100 μm to 2000 μm. The multilayer dissolvable solid article is characterized by a maximum dimension D and a minimum dimension z; and wherein the ratio of D/z ranges from 1 to 10.

First claim

What is claimed is:

1 . A dissolvable solid article comprising two or more flexible, dissolvable, porous sheets having a length and a thickness, wherein:
each of said two or more sheets comprises a water-soluble polymer and a surfactant, a top region adjacent a top surface and a bottom region adjacent a bottom surface and a middle region disposed between the top and bottom regions; an Average Pore Size ratio of the bottom region to the top region is from about 0.6 to about 1.5 and is characterized by a Percent Open Cell Content of from 80% to 100% and an Overall Average Pore Size of from 100 μm to 2000 μm and a ratio of the length to thickness of about 10:1 or more; each of said two or more sheets comprises an Average Cell Wall Thickness of from 65 μm to 200 μm and a basis weight of from 50 grams/m 2 to 250 grams/m 2 ; said dissolvable solid article is characterized by a maximum dimension D and a minimum dimension z; the ratio of D/z ranges from 1 to 10; and the top region comprises a top Average Pore Size, the bottom region comprises a bottom Average Pore Size, and the middle region comprises a middle Average Pore Size, wherein a relative standard deviation between the top Average Pore Size, the bottom Average Pore Size and the middle Average Pore Size is about 20% or less.

2 . The dissolvable solid article of claim 1 , wherein the ratio of D/z ranges from 1.4 to 9.

3 . The dissolvable solid article according to claim 1 , wherein the minimum dimension z ranges from 3 mm to 20 cm.

4 . The dissolvable solid article according to claim 1 , wherein each of said two or more sheets is characterized by a thickness of 0.5 mm to 4 mm.

5 . The dissolvable solid article according to claim 1 , said article comprising from 4 to 50 of said flexible, dissolvable, porous sheets.

6 . The dissolvable solid article according to claim 1 , wherein said article is characterized by a density of 0.05 grams/cm 3 to 0.5 grams/cm 3 .

7 . The dissolvable solid article according to claim 1 , wherein at least one of said two or more flexible, dissolvable, porous sheets comprises from 15% to 30% of said water-soluble polymer by total weight of said sheet; and wherein said at least one sheet further comprises from 30% to 65%, of said surfactant by total weight of said sheet.

8 . The dissolvable solid article according to claim 7 , wherein said at least one sheet further comprises from 2% to 12%, of a plasticizer by total weight of said sheet; and wherein optionally said at least one sheet further comprises one or more additional ingredients selected from the group consisting of fabric care actives, dishwashing actives, hard surface cleaning actives, beauty and/or skin care actives, personal cleansing actives, hair care actives, oral care actives, feminine care actives, baby care actives, and any combinations thereof.

9 . The dissolvable solid article according to claim 1 , wherein each of said two or more flexible, dissolvable, porous sheets is characterized by:
a Percent Open Cell Content of from 85% to 100%; and an Overall Average Pore Size of 200 μm to 600 μm; and a final moisture content of from 1% to 20%, by weight of said article; and a thickness of from 0.6 mm to 3.5 mm; and a density of from 0.05 grams/cm 3 to 0.5 grams/cm 3 ; and a Specific Surface Area of from 0.04 m 2 /g to 0.22 m 2 /g.

10 . The dissolvable solid article according to claim 1 , wherein said two or more flexible, dissolvable, porous sheets comprise a first sheet of a first color and a second sheet of a second, different color, and wherein said first and second sheets are visible from an external surface of said dissolvable solid article.

11 . The dissolvable solid article according to claim 10 , wherein said first sheet comprises a first benefit agent; wherein the second sheet comprise a second, different benefit agent; and wherein said first color provides a visual cue indicative of said first benefit agent, and said second color provides a visual cue indicative of said second benefit agent.

12 . The dissolvable solid article according to claim 1 , comprising at least one functional ingredient located within a central region between two adjacent flexible, dissolvable, porous sheets, wherein said at least one functional ingredient is selected from the group consisting of cleaning actives, personal care actives, and combinations thereof; and wherein the cleaning actives are selected from the group consisting of surfactants, free perfumes, encapsulated perfumes, perfume microcapsules, silicones, softening agents, enzymes, bleaches, colorants, builders, rheology modifiers, pH modifiers, and combinations thereof, and wherein the personal care actives are selected from the group consisting of emollients, humectants, conditioning agents, and combinations thereof.

13 . The dissolvable solid article according to claim 1 , further comprising an Average Pore Size ratio of the bottom region to the middle region of from about 0.5 to about 1.5.

14 . The dissolvable solid article according to claim 1 , wherein an Average Pore Size ratio of the bottom region to the top region is from about 0.7 to about 1.4.

15 . The dissolvable solid article according to claim 1 , wherein an Average Pore Size ratio of the bottom region to the top region is from about 1.0 to about 1.2.

16 . The dissolvable solid article according to claim 1 , wherein the relative standard deviation between the top Average Pore Size, the bottom Average Pore Size and the middle Average Pore Size is about 15% or less.

Assignees

• Procter & Gamble

Inventors

• Tan Hongsing
• Glenn Jr Robert Wayne
• Mac Namara Carl David
• Huang Xu
• Pei Ruizhi
• Okada Toshiyuki

Classifications

• C11D3/0005

  Other compounding ingredients characterised by their effect · CPC title

• A61Q19/00

  Preparations for care of the skin · CPC title

• A61K8/0208

  Tissues; Wipes; Patches · CPC title

• C11D3/386

  Preparations containing enzymes {, e.g. protease or amylase} · CPC title

• C11D3/395

  Bleaching agents · CPC title