Process for purifying organic solvents

Patent metadata

Field	Value
Publication number	US-12521709-B2
Application number	US-201917594902-A
Country	US
Kind code	B2
Filing date	Jul 4, 2019
Priority date	Jul 4, 2019
Publication date	Jan 13, 2026
Grant date	Jan 13, 2026

Abstract

A process for purifying (i) a hydrophilic organic solvent, (ii) a hydrolysable organic solvent, or (iii) a mixture of a hydrophilic organic solvent and a hydrolysable organic solvent by removing ionic contaminants from the hydrophilic organic solvent, from the hydrolysable organic solvent, or from the mixture of a hydrophilic and a hydrolysable organic solvent without generation of by-product impurities, the process including the steps of contacting the hydrophilic organic solvent, the hydrolysable organic solvent, or the mixture of hydrophilic and hydrolysable organic solvents with a mixed bed of ion exchange resin; wherein the mixed bed of ion exchange resin includes a mixture of: (a) a weak-acid cationic ion exchange resin and (b) a weak-base anionic ion exchange resin.

First claim

What is claimed is:

1 . A process for purifying a mixture of a hydrophilic organic solvent and a hydrolysable organic solvent by removing ionic contaminants from the mixture of the hydrophilic and the hydrolysable organic solvent without increment of organic impurities, the process comprising contacting the mixture of hydrophilic and hydrolysable organic solvents with a mixed bed of ion exchange resin; wherein the mixed bed of ion exchange resin comprises a mixture of: (a) a weak-acid cationic ion exchange resin and (b) a weak-base anionic ion exchange resin.

2 . The process of claim 1 , wherein the ionic contaminants include metallic and non-metallic ionic contaminants.

3 . The process of claim 1 , wherein the weak-acid cationic ion exchange resin is a macroreticular type resin and the weak-base anionic ion exchange resin is a macroreticular type resin.

4 . The process of claim 1 , wherein the mixture of hydrophilic organic solvent and hydrolysable organic solvent is a mixture of propylene glycol mono methyl ether and propylene glycol mono methyl ether acetate and the ratio of propylene glycol mono methyl ether and propylene glycol mono methyl ether acetate can be 1/99 to 99/1.

5 . The process of claim 1 , wherein the combination of the macroreticular type weak-acid cationic ion exchange resin and the macroreticular type weak-base anionic ion exchange resin is a blend ratio of from 80:20 to 20:80 in chemical equivalency; and at the same time, is a blend ratio of from 80:20 to 20:80 in solvated volume.

6 . The process of claim 1 , wherein the metal contaminant level of the solvent after the solvent is subjected to ion-exchange resin treatment is less than 50 parts per trillion.

7 . The process of claim 1 , wherein the hydrolysable organic solvent is a compound having an ester bond.

8 . A process for removing ionic contaminants from an organic solvent, comprising the steps of:
(a) preparing a mixed bed of ion exchange resin comprising a cationic ion exchange resin and an anionic ion exchange resin, wherein the cationic ion exchange resin is a weak-acid cationic ion exchange resin; and wherein the anionic ion exchange resin is a weak-base anionic ion exchange resin, and (b) contacting a mixture of a hydrophilic organic solvent and a hydrolysable organic solvent with the mixed bed of ion exchange resin of step (a).

9 . The process of claim 8 , wherein the step (b) is conducted by flowing the mixture of a hydrophilic organic solvent and a hydrolysable organic solvent-organie in a column filled with the mixed bed of ion exchange resin.

10 . The process of claim 9 , wherein the flow speed of the organic solvent is from 1 bed volume/hour to 100 bed volume/hour.

Assignees

• Dow Global Technologies Llc

Inventors

• Jiang Qi
• Ohba Kaoru

Classifications

• B01D15/363

  Anion-exchange · CPC title

• B01D15/362

  Cation-exchange · CPC title

• B01J39/07

  in the weakly acidic form · CPC title

• B01J41/07

  in the weakly basic form · CPC title

• C07C69/14

  of monohydroxylic compounds · CPC title