Exhaust gas emissions abatement system

Patent metadata

Field	Value
Publication number	US-12521696-B2
Application number	US-202018001615-A
Country	US
Kind code	B2
Filing date	Nov 11, 2020
Priority date	Jun 25, 2020
Publication date	Jan 13, 2026
Grant date	Jan 13, 2026

Abstract

A system for removing methane oxidation catalyst (MOC) poisons from an exhaust gas including a methane abatement unit that may receive the exhaust gas having methane (CH 4 )and the MOC poisons. The methane abatement unit includes a guard bed that may remove the MOC poisons from the exhaust gas and may generate an intermediate exhaust gas having the CH 4 and devoid of the MOC poisons. The guard bed includes a MOC poisons capturing component having a first transition metal oxide, an aluminum oxide (Al 2 O 3 ) support material, and a dolomite-derived support material. The methane abatement unit also includes a MOC bed fluidly coupled to and positioned downstream from the guard bed. The MOC bed includes a MOC and may remove CH 4 from the intermediate exhaust gas to generate a treated exhaust gas having less than approximately 200 parts per million volume (ppmv) CH 4 .

First claim

We claim:

1 . A system for removing methane oxidation catalyst (MOC) poisons from an exhaust gas, comprising:
a methane abatement unit configured to receive the exhaust gas comprising methane (CH 4 ) and the MOC poisons, wherein the methane abatement unit comprises:
a guard bed configured to remove the MOC poisons from the exhaust gas and to generate an intermediate exhaust gas comprising the CH 4 and devoid of the MOC poisons, wherein the guard bed comprises a MOC poisons capturing component comprising a first transition metal oxide, an aluminum oxide (Al 2 O 3 ) support material, and a dolomite-derived support material, and wherein the MOC poisons capturing component is a co-extrudate of the first transition metal oxide, the Al 2 O 3 support material, and the dolomite-derived support material such that the MOC capturing component is a single component; and
a MOC bed fluidly coupled to and positioned downstream from the guard bed, wherein the MOC bed comprises a MOC and is configured to remove CH 4 from the intermediate exhaust gas to generate a treated exhaust gas having less than approximately 200 parts per million volume (ppmv) CH 4 .

2 . The system of claim 1 , wherein the guard bed is a single layer bed.

3 . The system of claim 1 , wherein the first transition metal oxide concentration in the MOC poisons capturing component is between approximately 3-20% wt.

4 . The system of claim 1 , wherein the dolomite-derived support material is dolomite (CaMg(CO 3 ) 2 ), calcium magnesium oxide (CaMgO 2 ), a mixture of lime (CaO) and MgO, or a combination thereof.

5 . The system of claim 1 , wherein the first transition metal oxide is an oxide of manganese (Mn), vanadium (V), copper (Cu), and combinations thereof.

6 . A method for removing methane oxidation catalyst (MOC) poisons from an exhaust gas, comprising:
feeding the exhaust gas comprising methane (CH 4 ) and the MOC poisons to a methane abatement unit comprising a guard bed and a MOC bed fluidly coupled to and downstream from the guard bed; contacting the exhaust gas with a MOC poisons capturing component disposed within the guard bed, wherein the MOC poisons capturing component comprises a first transition metal oxide, an aluminum oxide (Al 2 O 3 ) support material, and a dolomite-derived support material, and wherein the MOC poisons capturing component is a co-extrudate of the first transition metal oxide, the Al 2 O 3 support material, and the dolomite-derived support material such that the MOC capturing component is a single component; and removing the MOC poisons from the exhaust gas to generate an intermediate exhaust gas devoid of MOC poisons and comprising the CH 4 .

7 . The method of claim 6 , wherein the contacting step comprises passing the exhaust gas through a single layer of the MOC poisons capturing component.

8 . The method of claim 6 , comprising feeding the intermediate gas to the MOC bed having a MOC and removing the CH 4 from the intermediate gas to generate a treated exhaust gas having less than approximately 200 parts per million volume (ppmv) CH 4 .

9 . A methane oxidation catalyst (MOC) poisons capturing component for removing MOC poisons from an exhaust gas, comprising:
an aluminum oxide (Al 2 O 3 ) support material having a first porosity; a dolomite-derived support material having a second porosity that is less than the first porosity; a first transition metal oxide wherein a concentration of the first transition metal oxide is between approximately 1-25 weight % (wt %), and wherein the MOC poisons capturing component is a co-extrudate of the first transition metal oxide, the Al 2 O 3 support material, and the dolomite-derived support material such that the MOC capturing component is a single component; and
wherein the MOC poisons capturing component removes sulfur dioxide (SO 2 ), phosphorus (P), calcium (Ca), zinc (Zn), silicon (Si) and ash.

10 . The MOC poisons capturing component of claim 9 , wherein the dolomite-derived support material is dolomite (CaMg(CO 3 ) 2 ), calcium magnesium oxide (CaMgO 2 ), a mixture of lime (CaO) and MgO, or a combination thereof.

11 . The MOC poisons capturing component of claim 9 , wherein the transition metal oxide is an oxide of manganese (Mn), vanadium (V), copper (Cu), and combinations thereof.

12 . The MOC poisons capturing component of claim 9 , wherein the first porosity is greater than approximately 2.0 milliliters (mL)/gram (g).

13 . The MOC poisons capturing component of claim 9 , wherein the second porosity is less than approximately 0.2 mL/g.

14 . A system for removing methane oxidation catalyst (MOC) poisons from an exhaust gas, comprising:
a methane abatement unit configured to receive the exhaust gas comprising methane (CH 4 ) and the MOC poisons, wherein the methane abatement unit comprises:
a guard bed configured to remove the MOC poisons from the exhaust gas and to generate an intermediate exhaust gas comprising the CH 4 and devoid of the MOC poisons, wherein the guard bed comprises a MOC poisons capturing component comprising a first layer comprising a first transition metal oxide and an aluminum oxide (Al 2 O 3 ) support material, and a second layer comprising a second transition metal oxide and a dolomite-derived support material, and wherein the second transition metal is the same or different from the first transition metal; and
a MOC bed fluidly coupled to and positioned downstream from the guard bed, wherein the MOC bed comprises a MOC and is configured to remove CH 4 from the intermediate exhaust gas to generate a treated exhaust gas having less than approximately 200 parts per million volume (ppmv) CH 4 .

15 . The system of claim 14 , wherein the guard bed is a single layer bed.

16 . The system of claim 14 , wherein the first transition metal oxide concentration in the MOC poisons capturing component is between approximately 3-20% wt.

17 . The system of claim 14 , wherein the dolomite-derived support material is dolomite (CaMg(CO 3 ) 2 ), calcium magnesium oxide (CaMgO 2 ), a mixture of lime (CaO) and MgO, or a combination thereof.

18 . The system of claim 14 , wherein the first transition metal oxide is an oxide of manganese (Mn), vanadium (V), copper (Cu), and combinations thereof.

Assignees

• Shell Usa Inc

Inventors

• Tanev Peter Tanev
• Miao Shaojun
• Soorholtz Mario

Classifications

• B01J35/638

  more than 1.0 ml/g · CPC title

• B01J35/635

  0.5-1.0 ml/g · CPC title

• F01N2370/02

  used in catalytic reactors · CPC title

• F01N3/2803

  characterised by structure, by material or by manufacturing of catalyst support · CPC title

• B01J23/83

  with rare earths or actinides · CPC title