Porous membrane including perfluoroalkoxy alkane (PFA)-based melt-extruded film and having pores controlled by biaxial stretching, and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-12521694-B2
Application number	US-202318195722-A
Country	US
Kind code	B2
Filing date	May 10, 2023
Priority date	May 27, 2022
Publication date	Jan 13, 2026
Grant date	Jan 13, 2026

Abstract

There are provided a porous membrane including a perfluoroalkoxy alkane (PFA)-based melt-extruded film and having pores controlled by biaxial stretching, and a manufacturing method therefore. The porous membrane is for water treatment and includes a fluoropolymer. The method includes forming a film by melt-extruding a fluoropolymer; and controlling the pore size of the formed film by biaxial stretching. The membrane for water treatment is based on a fluoropolymer and has physical properties that are resistant to high temperatures and strong acids, and it is able to be used for treatment of wastewater such as semiconductor wastewater.

First claim

What is claimed is:

1 . A method for manufacturing a membrane for water treatment, the method comprising steps of:
forming a film by melt-extruding a fluoropolymer represented by the following Formula 1; and controlling a pore size of the formed film by biaxial stretching:

wherein a ratio of x:y is 20 to 70:1, and Rf is a perfluorinated group selected from among —CF 3 , —CF 2 CF 3 , —CF 2 CF 2 CF 3 , and —CF(CF 3 ) 2 ,
wherein the step of controlling the pore size is performed by biaxially stretching the formed film at a stretching speed of 0.1 to 1 mm/s and a stretching ratio of 110 to 140% at a temperature of 240 to 260° C.

2 . The method of claim 1 , wherein the extruded film is passed through rolls at a speed of 200 to 1,200 mm/min to have an average thickness of 0.01 to 1 mm.

3 . The method of claim 1 , wherein the pores are controlled to have an average diameter of 10 to 100 nm.

4 . The method of claim 1 , wherein the step of controlling the pore size further comprises, after biaxially stretching the formed film, heat-treating the film at a temperature of 250 to 310° C. for 5 minutes or less.

Assignees

• Nat Univ Pukyong Ind Univ Coop Found

Inventors

• Cho Kie Yong
• Son Min Young
• Kwon Young Je
• Choi Gyeong Min
• Park Jae Won

Classifications

• C08F214/262

  with fluorinated vinyl ethers · CPC title

• B01D2323/60

  Co-casting; Co-extrusion · CPC title

• B01D2323/50

  Control of the membrane preparation process · CPC title

• B01D2323/081

  Heating · CPC title

• C08J2327/18

  Homopolymers or copolymers of tetrafluoroethylene · CPC title