Carbon-capture sorbent regeneration by magnetic heating of nanoparticles

Patent metadata

Field	Value
Publication number	US-12521668-B2
Application number	US-202318370980-A
Country	US
Kind code	B2
Filing date	Sep 21, 2023
Priority date	Sep 21, 2023
Publication date	Jan 13, 2026
Grant date	Jan 13, 2026

Abstract

A method of carbon-capture sorbent regeneration is provided. The method includes obtaining a sorbent that includes adsorbed carbon dioxide. Magnetic nanoparticles are introduced to the sorbent and adsorbed carbon dioxide to form a mixture. A magnetic field is applied to the mixture. The magnetic nanoparticles generate heat which releases carbon dioxide from the sorbent, thereby regenerating the sorbent. The magnetic nanoparticles include iron oxides, doped ferrites, functionalized iron oxides, functionalized ferrites, and composite materials that are combinations of these. The sorbent includes liquid and solid sorbents, and the regenerated sorbent may be utilized for further carbon capture.

First claim

What is claimed is:

1 . A method of carbon-capture sorbent regeneration, the method comprising:
obtaining a sorbent that includes adsorbed carbon dioxide; introducing magnetic nanoparticles to the sorbent and adsorbed carbon dioxide to form a mixture; and applying a magnetic field to the mixture; wherein the magnetic nanoparticles generate heat which releases carbon dioxide from the sorbent, thereby regenerating the sorbent.

2 . The method of claim 1 , wherein the magnetic nanoparticles include one or more of: (i) an iron oxide; (ii) a doped ferrite; (iii) a functionalized iron oxide; (iv) a functionalized ferrite; and (v) a composite material that is a combination of two or more of (i) through (iv).

3 . The method of claim 1 , wherein the magnetic nanoparticles include an iron oxide selected from a group consisting of: (i) Fe 3 O 4 ; (ii) FeO; (iii) α-Fe 2 O 3 ; and (iv) γ-Fe 2 O 3 .

4 . The method of claim 1 , wherein the sorbent is a liquid or a solid material.

5 . The method of claim 4 , wherein the sorbent is a liquid that includes one of: (i) diethanolamine (DEA); (ii) monoethanolamine (MEA); (iii) methyldiethanolamine (MDEA); (iv) diisopropanolamine (DIPA); (v) aminoethoxyethanol (diglycolamine) (DGA); (vi) an amino acid; (vii) an ionic liquid; and (viii) any combination of two or more of (i) through (vii).

6 . The method of claim 1 , wherein the sorbent is a solid material that includes one of: (i) a covalent organic framework; (ii) a metal-organic framework; (iii) an activated carbon; (iv) an amine functionalized material; (v) a membrane material; and (vi) any combination of two or more of (i) through (v).

7 . The method of claim 1 , wherein the sorbent is a liquid, and the mixture includes the magnetic nanoparticles suspended in the liquid.

8 . The method of claim 1 , wherein the sorbent is a porous solid material, and the magnetic particles are mixed into the pores of the solid material.

9 . The method of claim 1 , wherein the magnetic field is an alternating current magnetic field.

10 . The method of claim 1 , further including the step of applying a static magnetic field to the mixture to coagulate the magnetic nanoparticles.

11 . The method of claim 1 , further including the step of collecting the carbon dioxide released from the sorbent.

12 . The method of claim 1 , wherein the regenerated sorbent is utilized for carbon capture.

13 . The method of claim 1 , wherein in conjunction with the step of applying a magnetic field to the mixture, further including one or both of: (i) applying additional heat from an external source to the mixture; and (ii) applying a vacuum to the mixture.

14 . A method of carbon capture including sorbent regeneration, the method including:
(a) providing a sorbent; (b) introducing a flow of gas to the sorbent, the gas including carbon dioxide, wherein the sorbent adsorbs the carbon dioxide; (c) subsequent to the sorbent adsorbing carbon dioxide, introducing magnetic nanoparticles to the sorbent and adsorbed carbon dioxide to form a mixture; and (d) applying a magnetic field to the mixture; wherein the magnetic nanoparticles generate heat which releases the carbon dioxide from the sorbent, thereby regenerating the sorbent.

15 . The method of claim 14 , including repeating steps (a) through (c) subsequent to step (d), wherein the sorbent in repeated step (1) is the regenerated sorbent.

16 . The method of claim 14 , further including the step of: (e) collecting the carbon dioxide released from the sorbent.

17 . The method of claim 14 , wherein the magnetic nanoparticles include one or more of: (i) an iron oxide; (ii) a doped ferrite; (iii) a functionalized iron oxide; (iv) a functionalized ferrite; and (v) a composite material that is a combination of two or more of (i) through (iv).

18 . The method of claim 14 , wherein the sorbent is a liquid that includes one of: (i) diethanolamine (DEA); (ii) monoethanolamine (MEA); (iii) methyldiethanolamine (MDEA); (iv) diisopropanolamine (DIPA); (v) aminoethoxyethanol (diglycolamine) (DGA); (vi) an amino acid; (vii) an ionic liquid; and (viii) any combination of two or more of (i) through (vii).

19 . The method of claim 14 , wherein the sorbent is a solid material that includes one of: (i) a covalent organic framework; (ii) a metal-organic framework; (iii) activated carbon; (iv) an amine functionalized material; (v) a membrane material; and (vi) any combination of two or more of (i) through (v).

20 . The method of claim 14 , wherein the magnetic field in step (d) is an alternating current magnetic field, and subsequent to regenerating the sorbent in step (d), further including the step of: (f) applying a static magnetic field to the mixture to coagulate the magnetic nanoparticles.

Assignees

• Ut Battelle Llc

Inventors

• Li Kai
• Nawaz Kashif
• Aytug Tolga
• Kesler Michael S
• Lara-Curzio Edgar
• Mcguire Michael A
• Tener Zack
• Sholl David S
• Zhang Mingkan

Classifications

• B01D2253/102

  Carbon · CPC title

• B01D2253/204

  Metal organic frameworks (MOF's) · CPC title

• B01D2259/40098

  with other heating means · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• B01D2259/814

  Magnetic fields · CPC title