Method of inspecting lubricating oil composition and method of producing lubricating oil composition

Patent metadata

Field	Value
Publication number	US-12517027-B2
Application number	US-202117526346-A
Country	US
Kind code	B2
Filing date	Nov 15, 2021
Priority date	May 16, 2019
Publication date	Jan 6, 2026
Grant date	Jan 6, 2026

Abstract

The invention provides a method of inspecting a lubricating oil composition and a method of producing a lubricating oil composition. The inspecting method is capable of stably reproducing wear resistance characteristics by using a relatively easy measuring method even in the case where the lubricating oil composition contains a fullerene. In the method of inspecting the lubricating oil composition, the particle size (r) of particles present in the lubricating oil composition containing a base oil and fullerene is measured, and the lubricating oil composition is sorted on the basis of a predetermined range of the particle size (r) set by the relationship between the measured value of the particle size (r) and the measured value of the wear coefficient of the lubricating oil composition.

First claim

The invention claimed is:

1 . A method of inspecting a lubricating oil composition, the method comprising:
measuring a particle size (r) of particles present in the lubricating oil composition containing a base oil and a fullerene, thereby obtaining a measured particle size (r), and determining wear resistance characteristics of the lubricating oil composition based on the measured particle size (r) according to a defined relationship between the measured particle size (r) and a measured wear coefficient of the lubricating oil composition, wherein the particles include at least one kind selected from the group consisting of (i) aggregates of fullerenes and (ii) complexes of fullerenes and base oil molecules and the particle size (r) of particles present in the lubricating oil composition is an average particle size (R) of the particles present in the lubricating oil composition.

2 . The method according to claim 1 ,
wherein the particle size (r) of the particles is measured by a dynamic light scattering method, a laser diffraction method, or a small-angle X-ray scattering (SAXS) method.

3 . The method according to claim 1 ,
wherein the average particle size (R) of the particles is measured by a small-angle X-ray scattering (SAXS) method.

4 . The method according to claim 3 ,
wherein the average particle size (R) of the particles is calculated from a slope of a Guinier plot.

5 . The method according to claim 3 ,
wherein the average particle size (R) of the particles is calculated from a value of a scattering vector at which the scattering intensity ratio between the lubricating oil composition and the base oil is the maximum value with respect to the scattering vector.

6 . A method of producing a lubricating oil composition, the method comprising a step of sorting the lubricating oil composition by using the method according to claim 1 .

7 . The method according to claim 1 ,
wherein the particles include aggregates of fullerenes.

8 . The method according to claim 1 ,
wherein the particles include complexes of fullerenes and base oil molecules.

9 . The method according to claim 1 ,
wherein the particles include (i) aggregates of fullerenes and (ii) complexes of fullerenes and base oil molecules.

10 . The method according to claim 1 , wherein there is a negative correlation between the measured particle size (r) and a measured wear coefficient of the lubricating oil composition.

11 . A method of inspecting a lubricating oil composition, the method comprising:
measuring a particle size (r) of particles present in the lubricating oil composition containing a base oil and a fullerene, thereby obtaining a measured particle size (r), and estimating a wear coefficient of the lubricating oil composition based on the measured particle size (r) according to a defined relationship between the measured particle size (r) and a measured wear coefficient of the lubricating oil composition, wherein the particles include at least one kind selected from the group consisting of (i) aggregates of fullerenes and (ii) complexes of fullerenes and base oil molecules and the particle size (r) of particles present in the lubricating oil composition is an average particle size (R) of the particles present in the lubricating oil composition.

12 . The method according to claim 11 ,
wherein the particle size (r) of the particles is measured by a dynamic light scattering method, a laser diffraction method, or a small-angle X-ray scattering (SAXS) method.

13 . The method according to claim 11 ,
wherein the average particle size (R) of the particles is measured by a small-angle X-ray scattering (SAXS) method.

14 . The method according to claim 13 ,
wherein the average particle size (R) of the particles is calculated from a slope of a Guinier plot.

15 . The method according to claim 13 ,
wherein the average particle size (R) of the particles is calculated from a value of a scattering vector at which the scattering intensity ratio between the lubricating oil composition and the base oil is the maximum value with respect to the scattering vector.

16 . A method of producing a lubricating oil composition, the method comprising a step of sorting the lubricating oil composition by using the method according to claim 11 .

17 . The method according to claim 11 ,
wherein the particles include aggregates of fullerenes.

18 . The method according to claim 11 ,
wherein the particles include complexes of fullerenes and base oil molecules.

19 . The method according to claim 11 ,
wherein the particles include (i) aggregates of fullerenes and (ii) complexes of fullerenes and base oil molecules.

20 . The method according to claim 11 , wherein there is a negative correlation between the measured particle size (r) and a measured wear coefficient of the lubricating oil composition.

Assignees

• Showa Denko Kk
• Mitsubishi Corp

Inventors

• Monden Ryuji
• Sakaguchi Yasuyuki
• KANE Hitomi
• Kondo Kunio

Classifications

• G01N33/2888

  Lubricating oil characteristics, e.g. deterioration (lubricating properties G01N33/30) · CPC title

• G01N33/2835

  Specific substances contained in the oils or fuels · CPC title

• C10M125/02

  Carbon; Graphite · CPC title

• G01N2015/0053

  in liquids, e.g. trouble · CPC title

• G01N2015/0222

  from dynamic light scattering, e.g. photon correlation spectroscopy · CPC title