Production method for precarbonized fiber bundle, production method for carbon fiber bundle, and precarbonization furnace

Patent metadata

Field	Value
Publication number	US-12516451-B2
Application number	US-202117908578-A
Country	US
Kind code	B2
Filing date	Mar 22, 2021
Priority date	Mar 24, 2020
Publication date	Jan 6, 2026
Grant date	Jan 6, 2026

Abstract

An object is to provide a production method for a precarbonized fiber bundle and a precarbonization furnace capable of continuously producing the precarbonized fiber bundle for a long period of time by efficiently discharging a decomposition gas containing a tar component generated when performing a precarbonization treatment at the time of carbon fiber production and retained in a heat treatment chamber throughout the heat treatment chamber. The production method for a precarbonized fiber bundle includes allowing an aligned stabilized fiber bundle vertically arranged in one or two or more tiers to travel horizontally in a heat treatment chamber and heat-treating and precarbonizing the stabilized fiber bundle at a maximum temperature of 300 to 1,000° C. using an inert gas supplied from an inlet side and an outlet side of the heat treatment chamber, in which a flow rate ratio Q2/Q1 satisfies Formula (1) below, where Q1 represents a volume flow rate of gas in a first exhaust discharged out of the heat treatment chamber from a position higher than a position of an uppermost tier of the traveling stabilized fiber bundle, and Q2 represents a volume flow rate of gas in a second exhaust discharged out of the heat treatment chamber from a position lower than the position of the uppermost tier of the traveling stabilized fiber bundle:

0.01≤ Q 2 /Q 1≤0.5  Formula (1).

First claim

The invention claimed is:

1 . A production method for a precarbonized fiber bundle, comprising:
allowing a stabilized fiber bundle aligned along a horizontal plane and vertically arranged in one or two or more tiers to travel horizontally in a heat treatment chamber; and heat-treating and precarbonizing the stabilized fiber bundle at a maximum temperature of 300 to 1,000° C. using an inert gas supplied from an inlet side and an outlet side of the heat treatment chamber, wherein a flow rate ratio Q2/Q1 satisfies Formula (1) below, where Q1 represents a volume flow rate of gas in a first exhaust discharged out of the heat treatment chamber from a position higher than a position of an uppermost tier of the traveling stabilized fiber bundle, and Q2 represents a volume flow rate of gas in a second exhaust discharged out of the heat treatment chamber from a position lower than the uppermost tier of the traveling stabilized fiber bundle:
0.01≤ Q 2/ Q 1≤0.5  Formula (1).

2 . The production method for a precarbonized fiber bundle according to claim 1 , wherein the flow rate ratio Q2/Q1 between the volume flow rate Q1 of the gas in the first exhaust and the volume flow rate Q2 of the gas in the second exhaust satisfies Formula (2) below in precarbonization:
0.01≤ Q 2/ Q 1≤0.3  Formula (2).

3 . The production method for a precarbonized fiber bundle according to claim 1 , wherein the first exhaust and the second exhaust are performed at a position where a temperature in the heat treatment chamber is 350 to 550° C.

4 . The production method for a precarbonized fiber bundle according to claim 1 , wherein the first exhaust is performed in a non-traveling region of the stabilized fiber bundle.

5 . The production method for a precarbonized fiber bundle according to claim 1 , wherein when viewed in a longitudinal direction of the heat treatment chamber, an additional inert gas is supplied from a position between a position where the inert gas is supplied from the inlet side and a position closest to the inlet side selected from a position where the first exhaust is performed and a position where the second exhaust is performed, the position being on a bottom surface or a side surface of the heat treatment chamber.

6 . The production method for a precarbonized fiber bundle according to claim 5 ,
wherein Formula (3) below is satisfied, where S represents a cross-sectional area of the heat treatment chamber in a traveling direction of the stabilized fiber bundle, and V represents a supply volume flow rate of the additional inert gas:
0.1≤ V/S≤ 0.4[ m/s]   Formula (3).

7 . A production method for a carbon fiber bundle, comprising subjecting a precarbonized fiber bundle obtained by the production method for a precarbonized fiber bundle according to claim 1 to a carbonization treatment at a maximum temperature of 1,000 to 2,000° C. in an inert gas.

Assignees

• Toray Industries

Inventors

• Hosotani Naoto
• Hirose Takamitsu
• Kataoka Takuya

Classifications

• D01F9/225

  from stabilised polyacrylonitriles · CPC title

• D01D10/0463

  the filaments being maintained parallel · CPC title

• D01D10/0436

  while in continuous movement (forwarding filamentary material B65H51/00) · CPC title

• D02J13/008

  with elimination of fumes · CPC title

• D02J13/001

  in a tube or vessel · CPC title