Carbon-supported NiO electrode

Patent metadata

Field	Value
Publication number	US-12516429-B2
Application number	US-202318473377-A
Country	US
Kind code	B2
Filing date	Sep 25, 2023
Priority date	Feb 23, 2018
Publication date	Jan 6, 2026
Grant date	Jan 6, 2026

Abstract

A method of making NiO nanoparticles is described, as well as a method of using NiO nanoparticles as an electrocatalyst component to a porous carbon electrode. The carbon electrode may be made of carbonized filter paper. Together, this carbon-supported NiO electrode may be used for water electrolysis. Using a pamoic acid salt in the NiO nanoparticle synthesis leads to smaller and monodisperse nanoparticles, which support higher current densities.

First claim

The invention claimed is:

1 . A carbon-supported NiO electrode, comprising:
carbonized paper and NiO nanoparticles having an average particle size of 5-40 nm, deposited on the carbonized paper, wherein the carbon-supported NiO electrode is substantially free of Ni 0 , wherein the NiO nanoparticles have an aspect ratio of 1:1-1.5:1, wherein a density of the NiO nanoparticles on the carbonized paper is 100-200 μg/cm 2 , wherein the NiO nanoparticles are aggregated into clusters having diameters of 1-15 μm, and wherein the clusters have a nearest neighbor distance of 500 nm-5 μm.

2 . The carbon-supported NiO electrode of claim 1 , wherein the NiO nanoparticles are made by a method comprising:
mixing a nickel salt, pamoic acid or a pamoic acid salt, and an alcohol to form a dispersed mixture; drying the dispersed mixture to produce a dried mass; and heating the dried mass in air at a temperature of 420-700° C. for 1-6 h to produce the NiO nanoparticles.

3 . The carbon-supported NiO electrode of claim 1 , wherein the NiO nanoparticles are monodisperse.

4 . The carbon-supported NiO electrode of claim 1 , wherein the NiO nanoparticles have a crystalline bunsenite morphology.

5 . The carbon-supported NiO electrode of claim 1 , wherein at least 70% of the NiO nanoparticles have a particle size of 10-40 nm.

6 . The carbon-supported NiO electrode of claim 2 , wherein in the method of making the NiO nanoparticles a molar ratio of the pamoic acid or the pamoic acid salt to the nickel salt is 5:10-8:10.

7 . The carbon-supported NIO electrode of claim 2 , wherein in the method of making the NiO nanoparticles the nickel salt is Ni(NO 3 ) 2 or Ni(NO 3 ) 2 ·6H 2 O.

8 . The carbon-supported NiO electrode of claim 2 , wherein in the method of making the NiO nanoparticles the pamoic acid salt is present, and the pamoic acid salt is disodium pamoate.

9 . The carbon-supported NiO electrode of claim 1 , wherein the NiO nanoparticles have an average particle size that is substantially smaller than an average particle size of NiO nanoparticles produced by an otherwise identical method having no pamoic acid and no pamoic acid salt.

10 . The carbon-supported NiO electrode of claim 2 , wherein in the method of making the NiO nanoparticles the nickel salt and the pamoic acid or the pamoic acid salt have a combined weight percentage of 0.8-2.5 wt % relative to a total weight of the dispersed mixture.

11 . The carbon-supported NiO electrode of claim 1 , wherein the NiO nanoparticles have an average particle size of 15-25 nm.

12 . The carbon-supported NiO electrode of claim 1 , wherein the NiO nanoparticles have an aspect ratio of 1.1:1-1.35:1.

13 . The carbon-supported NiO electrode of claim 1 , wherein the density of the NiO nanoparticles on the carbonized paper is 130-170 μg/cm 2 .

14 . The carbon-supported NiO electrode of claim 1 , wherein the NiO nanoparticles are aggregated into clusters having diameters of 3-12 μm.

15 . The carbon-supported NiO electrode of claim 1 , wherein the clusters have a nearest neighbor distance of 1 μm-3 μm.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Aziz Md Abdul
• Qasem Mohammed Ameeh Ahmed

Classifications

• C25B11/043

  Carbon, e.g. diamond or graphene · CPC title

• C25B11/00

  Electrodes; Manufacture thereof not otherwise provided for · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• B01J23/755

  Nickel · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title