Organic solvent-soluble copolymer polyester, composition for forming ultrafiltration membrane comprising same, and high water permeability reverse osmosis membrane prepared therefrom

Patent metadata

Field	Value
Publication number	US-12516150-B2
Application number	US-202117797137-A
Country	US
Kind code	B2
Filing date	Apr 2, 2021
Priority date	Jun 1, 2020
Publication date	Jan 6, 2026
Grant date	Jan 6, 2026

Abstract

The present invention relates to an organic solvent-soluble copolymerized polyester, a composition for forming an ultrafiltration membrane including the same, and a high water-permeability reverse osmosis membrane prepared therefrom. More specifically, the present invention relates to a polyester that has a high solubility in organic solvents at room temperature and thus can be used to produce ultrafiltration membranes at low cost, a composition for forming an ultrafiltration membrane including the same, and a high water-permeability reverse osmosis membrane prepared therefrom, wherein the reverse osmosis membrane has a reduced production cost and high water permeability.

First claim

The invention claimed is:

1 . A composition for forming an ultrafiltration membrane, comprising:
an organic solvent; and a copolymerized polyester that is dissolved in the organic solvent, the copolymerized polyester being formed by an esterification reaction between an acid component comprising at least one C 8-12 aromatic dicarboxylic acid and a diol component consisting of ethylene glycol and neopentyl alcohol, wherein the molar ratio (N C /N O ) of the number of carbon atoms (N C ) and the number of oxygen atoms (N O ) in the copolymerized polyester is 2.8 to 3.2, and the solubility of the copolymerized polyester in dimethylformamide (DMF) at room temperature is 20% by weight or more, and wherein the viscosity of said composition is 10 to 600 cP.

2 . The composition of claim 1 , wherein the organic solvent comprises at least one solvent selected from the group consisting of diethylene glycol, triethylene glycol, methyl ethyl ketone, ethylene glycol diacetate, ethylene glycol dimethylether, toluene, dimethylformamide, dimethylacetamide (DMAc), N-methyl-2-pyrrolidone (NMP), dimethyl sulfoxide (DMSO), m-cresol, diglycolamine and tetrahydrofuran (THF).

3 . The composition of claim 1 , wherein the composition comprises the copolymerized polyester at a concentration of 10 to 30% by weight.

4 . A reverse osmosis membrane, comprising:
a porous support layer; and an ultrafiltration membrane formed on one surface of the porous support layer, wherein the ultrafiltration membrane comprises a copolymerized polyester that is dissolved in an organic solvent and that is formed by an esterification reaction between an acid component comprising at least one C 8-12 aromatic dicarboxylic acid and a diol component consisting of ethylene glycol and neopentyl alcohol, wherein the molar ratio (N C /N O ) of the number of carbon atoms (N C ) and the number of oxygen atoms (N O ) in the copolymerized polyester is 2.8 to 3.2, and the solubility of the copolymerized polyester in dimethylformamide (DMF) at room temperature is 20% by weight or more, and wherein the reverse osmosis membrane has a water permeability of 200 to 1,000 gfd as measured according to the measurement conditions below:
the reverse osmosis membrane when operated at a temperature of 25° C. and a pressure of 1 kgf/cm 2 using raw water, which is deionized water (DI), to measure the water permeability.

5 . The reverse osmosis membrane of claim 4 , wherein the ultrafiltration membrane has an asymmetric structure in which the average pore size gradually increases or decreases from a surface (lower surface) in contact with the porous support layer to the opposite surface (upper surface), and the average pore size (D 50 ) on the upper surface of the ultrafiltration membrane is 0.01 to 0.2 μm.

6 . The reverse osmosis membrane of claim 4 , further comprising a polyamide coating layer on the ultrafiltration membrane.

7 . The reverse osmosis membrane of claim 4 , wherein the porous support is a woven fabric or a nonwoven fabric.

8 . The composition of claim 1 , wherein the acid component comprises terephthalic acid and a C 8-12 aromatic dicarboxylic acid compound other than terephthalic acid.

9 . The composition of claim 8 , wherein the C 8-12 aromatic dicarboxylic acid compound other than terephthalic acid is at least one compound selected from the group consisting of isophthalic acid (IPA), naphthalendioic acid and a 5-sulfoisophthalic acid (SIA) sodium salt, and
wherein the acid component comprises 5 to 50 mol % of the C 8-12 aromatic dicarboxylic acid compound other than terephthalic acid based on the total amount of the acid component.

10 . The composition of claim 1 , wherein the diol component comprises 35 to 65 mol % of ethylene glycol based on the total amount of the diol component.

Assignees

• Toray Advanced Mat Korea Inc

Inventors

• Byun Gwang Su
• Lim Jae Won
• Lee Jeong Hwan

Classifications

• B01D69/106

  Membranes in the pores of a support, e.g. polymerized in the pores or voids · CPC title

• B01D2325/20

  Specific permeability or cut-off range · CPC title

• B01D2325/022

  Asymmetric membranes · CPC title

• B01D71/56

  Polyamides, e.g. polyester-amides · CPC title

• B01D71/48 Primary

  Polyesters · CPC title