Process for anaerobic digestion of carbonaceous material

Patent metadata

Field	Value
Publication number	US-12515975-B2
Application number	US-202318153130-A
Country	US
Kind code	B2
Filing date	Jan 11, 2023
Priority date	Jan 11, 2023
Publication date	Jan 6, 2026
Grant date	Jan 6, 2026

Abstract

A process of treatment of carbonaceous material, such as wastewater sludge or organic waste, includes performing a thermal treatment of the carbonaceous material, thereby providing thermally treated carbonaceous material, cooling the thermally treated carbonaceous material, thereby providing cooled carbonaceous material, the cooling being performed using a vacuum cooling procedure, and performing a post-treatment of the cooled carbonaceous material, and at least one carbonaceous material degassing.

First claim

The invention claimed is:

1 . A process of treatment of carbonaceous material, comprising:
performing a thermal treatment of said carbonaceous material, thereby providing thermally treated carbonaceous material, cooling said thermally treated carbonaceous material, thereby providing cooled carbonaceous material, the cooling being performed using a vacuum cooling step, and performing a post-treatment of said cooled carbonaceous material, and at least one step of carbonaceous material degassing; wherein the carbonaceous material degassing operates at a vacuum pressure level above a pressure at which steam is produced from the hot and fresh carbonaceous material.

2 . The process of claim 1 , comprising a step of CO 2 capturing, upstream of the cooling.

3 . The process of claim 1 , comprising a step of pre-heating of the carbonaceous material before performing the thermal treatment of the carbonaceous material, the step of pre-heating being performed by direct steam contact of a recovered steam produced by the vacuum cooling step with the carbonaceous material.

4 . The process of claim 3 , wherein the carbonaceous material is directed first to a heat recovery vessel wherein said carbonaceous material is in contact with the recovered steam produced by the vacuum cooling step.

5 . The process of claim 3 , further comprising performing a step of CO 2 capturing on a steam in excess in a heat recovery vessel.

6 . The process of claim 1 , wherein
performing the thermal treatment includes performing a first thermal treatment of carbonaceous material, at a temperature T 1 between 50 and 90° C., thereby producing the thermally treated carbonaceous material, and cooling said thermally treated carbonaceous material includes cooling said thermally treated carbonaceous material downstream of performing the first thermal treatment to a temperature T 2 lower than T 1 of between 34-75° C., in a cooling unit operating under vacuum, thereby producing the cooled carbonaceous material.

7 . The process of claim 1 , wherein the cooling is performed in one or several sub-steps.

8 . The process of the claim 7 , wherein the cooling comprises:
cooling the resulting thermally treated carbonaceous material downstream of performing the thermal treatment to an intermediate temperature T 2 a lower than T 1 , of between 50° C. and 80° C. in a cooling unit operating under vacuum, thereby producing intermediate cooled carbonaceous material, and cooling said intermediate cooled carbonaceous material downstream of cooling the resulting thermally treated carbonaceous material downstream of performing the thermal treatment to a final temperature T 2 b lower than T 2 a of between 34° C. and 47° C. in a cooling unit operating under vacuum, thereby producing cooled carbonaceous material.

9 . The process of claim 1 , wherein the thermal treatment is a pasteurization, a thermophilic biological treatment, or a low temperature thermal hydrolysis.

10 . The process of claim 1 , wherein the post-treatment is:
a mechanical treatment step, or a temporary storage step, or an anaerobic treatment step, an anaerobic digestion, or a mesophilic digestion step.

11 . The process of claim 1 , wherein the carbonaceous material is organic waste and/or sludge.

12 . An installation for implementing the process of claim 1 , comprising:
a thermal treatment unit for thermally treating carbonaceous material, a vacuum cooling unit downstream the thermal treatment unit for cooling the carbonaceous material, and a post-treatment unit, downstream the vacuum cooling unit, for post-treating the cooled carbonaceous material, and a degassing tank installed upstream of the vacuum cooling unit; said degassing tank being configured to operate at a vacuum pressure level above a pressure at which steam is produced from the hot and fresh carbonaceous material.

13 . The installation of claim 12 , comprising a carbon dioxide scrubbing unit, upstream of the vacuum cooling unit.

14 . The installation of claim 12 , comprising a first heat recovery vessel upstream of the thermal treatment unit for contacting the carbonaceous material with the recovered steam.

15 . The installation of claim 14 , comprising a carbon dioxide scrubbing unit connected to the first heat recovery vessel.

16 . The installation of claim 14 , wherein a degassing tank is installed upstream the first heat recovery vessel and/or between the thermal treatment unit and the vacuum cooling unit.

17 . The installation of claim 14 , further comprising a second heat recovery vessel downstream the first heat recovery vessel and upstream the thermal treatment unit.

18 . The installation of claim 12 , wherein the vacuum cooling unit comprises a booster centrifugal fan and a vacuum pump.

19 . The installation of claim 12 , wherein each line of the installation comprises an independent vacuum pump.

20 . The installation of claim 12 , wherein the vacuum cooling unit comprises two vacuum cooling units installed in series, the treated carbonaceous material from the thermal treatment unit by a treatment line being cooled in a first cooling unit of the two vacuum cooling units, then the cooled carbonaceous material being cooled in a second time in a second cooling unit of the two vacuum cooling units and directed through a treatment line towards the post-treatment unit for post-treatment.

21 . The installation of claim 20 , wherein a recovered steam produced in the first and second cooling units is condensed in one or more condensers.

22 . The installation of claim 21 , wherein the recovered steam produced in the second cooling unit is recoverable and directable to a heat recovery vessel wherein the steam is contacted with carbonaceous material, thereby producing a first pre-heated carbonaceous material, said first pre-heated carbonaceous material being then sent to another heat recovery unit, wherein the first pre-heated carbonaceous material is contacted with the recovered steam from the first cooling unit.

23 . The installation of claim 20 , wherein the recovered steam produced in the first cooling unit is recovered and sent to a heat recovery vessel wherein the steam is contacted with carbonaceous material.

24 . The installation of claim 12 , wherein the degassing tank is installed between the thermal treatment unit and the vacuum cooling unit.

25 . The process of claim 1 , wherein the degassing without production of steam removes non-condensable gases from the hot and fresh carbonaceous material.

26 . The process of claim 25 , wherein the degassing without production of steam avoids cooling of the hot and fresh carbonaceous material as the non-condensable gases are removed.

27 . The process of claim 26 , wherein at least one of the carbonaceous material degassing steps is performed after said thermal treatment and prior to said cooling.

28 . The process of claim 1 , wherein at least one of the carbonaceous material degassing steps is performed after said thermal treatment and prior to said cooling.

Assignees

• Suez Int

Inventors

• Haddad Mathieu
• Pardo Pierre-Emmanuel

Classifications

• C02F1/20

  by degassing, i.e. liberation of dissolved gases (degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D) · CPC title

• C02F1/16

  using waste heat from other processes · CPC title

• C02F1/025

  Thermal hydrolysis · CPC title

• C02F11/20

  by freezing · CPC title

• C02F11/185 Primary

  by pasteurisation · CPC title