Positive electrode active material for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery
US-2023071732-A1 · Mar 9, 2023 · US
US12512459B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12512459-B2 |
| Application number | US-202118028364-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 14, 2021 |
| Priority date | Sep 30, 2020 |
| Publication date | Dec 30, 2025 |
| Grant date | Dec 30, 2025 |
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This positive electrode active material for nonaqueous electrolyte secondary batteries contains a lithium transition metal composite oxide that is represented by composition formula Li x Mn y Ni z P a M b O 2-c F c (wherein M represents at least one element that is selected from among Ti, Co, Si, Sr, Nb, W, Mo, Ca, Mg, Sb, Na, B, V, Cr, Fe, Cu, Zn, Ge, Zr, Ru, K and Bi; 1.0<x≤1.2; 0.4≤y≤0.8; 0≤z≤0.4; 0<a<0.01; 0<b<0.05; 0<c<0.1; and (x+y+z+a+b)≤2).
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The invention claimed is: 1 . A positive electrode active material for a non-aqueous electrolyte secondary battery, including a lithium-transition metal composite oxide represented by the composition formula Li x Mn y Ni z P a M b O 2-c F c , wherein M represents at least one element selected from the group consisting of Ti, Co, Si, Sr, Nb, W, Mo, Ca, Mg, Sb, Na, B, V, Cr, Fe, Cu, Zn, Ge, Zr, Ru, K, Bi, and Al, 1.0<x≤1.2, 0.4≤y≤0.8, 0≤z≤0.4, 0.002≤a<0.01, 0<b<0.05, 0<c<0.1, and x+y+z+a+b≤2. 2 . The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein M represents two or more elements. 3 . The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 2 , wherein the two or more M are selected from Ti, Co, Nb, Sb, and Al, and a molar proportion of M (b) satisfies 0<b<0.035. 4 . The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein in the composition formula Li x Mn y Ni z P a M b O 2-c F c , a molar proportion of P (a) satisfies 0.002≤a≤0.005. 5 . The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein in the composition formula Li x Mn y Ni z P a M b O 2-c F c , a molar proportion of F (c) satisfies 0.05≤c≤0.085. 6 . The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein in the composition formula Li x Mn y Ni z P a M b O 2-c F c , a molar proportion of Ni (z) satisfies 0.05≤z<0.3. 7 . The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein M represents one or more elements selected from the group consisting of Ti, Co, Si, Sr, Nb, Mg, Sb, Ge, and Al. 8 . The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein M contains at least Ti. 9 . The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 8 , wherein the composition formula contains no Co. 10 . A non-aqueous electrolyte secondary battery, comprising: a positive electrode including the positive electrode active material according to claim 1 ; a negative electrode; a separator interposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte.
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Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
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of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title
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