Gas turbine plant with ammonia decomposition system

Patent metadata

Field	Value
Publication number	US-12510022-B2
Application number	US-202418677375-A
Country	US
Kind code	B2
Filing date	May 29, 2024
Priority date	May 30, 2023
Publication date	Dec 30, 2025
Grant date	Dec 30, 2025

Abstract

The present disclosure relates to a gas turbine plant which decomposes ammonia and supplies it as fuel to a combustor of a gas turbine. The gas turbine plant supplies sufficient heat to the ammonia in order to thermally decompose the ammonia effectively, and separates the residual ammonia present in the decomposition gas and supplies it to a combustor of the gas turbine.

First claim

What is claimed is:

1 . A gas turbine plant with an ammonia decomposition system, the gas turbine plant comprising:
a storage tank configured to store liquid ammonia; a supply pump configured to supply the liquid ammonia from the storage tank; a preheater configured to preheat the liquid ammonia supplied by the supply pump; a vaporizer configured to vaporize at least a portion of the liquid ammonia preheated by the preheater to form a gaseous ammonia; a first superheater configured to superheat the gaseous ammonia vaporized by the vaporizer; a first decomposition reactor of the ammonia decomposition system configured to thermally decompose at least a portion of the gaseous ammonia superheated by the first superheater to form a first decomposition gas; and a second superheater that superheats the first decomposition gas decomposed by the first decomposition reactor and supplies the superheated first decomposition gas to a second decomposition reactor; the second decomposition reactor thermally decomposed at least a portion of a residual ammonia contained in the superheated first decomposition gas to form a second decomposition gas; a separator configured to receive at least a portion of the second decomposition gas from the second decomposition reactor and separate a residual ammonia contained in the at least a portion of the second decomposition gas to form a synthesis gas consisting of hydrogen and nitrogen; wherein at least a portion of the synthesis gas exhausted from the separator is supplied to a first combustor of a gas turbine of the gas turbine plant to form an exhaust gas, wherein the exhaust gas discharged from the gas turbine is branched as a first portion of the exhaust gas supplying heat while passing through the first decomposition reactor and as a second portion of the exhaust gas supplied to a heat recovery steam generator, wherein the gas turbine plant further comprises a second combustor configured to generate a combustion gas that supplies heat while passing through the second decomposition reactor and the second superheater.

2 . The gas turbine plant with the ammonia decomposition system of claim 1 , wherein the residual ammonia contained in the at least a portion of the second decomposition gas and separated by the separator is mixed with the gaseous ammonia vaporized by the vaporizer and is supplied to the first superheater.

3 . The gas turbine plant with the ammonia decomposition system of claim 1 , wherein the first portion of the exhaust gas that has passed through the first decomposition reactor supplies heat while passing through the first superheater.

4 . The gas turbine plant with the ammonia decomposition system of claim 1 , wherein the second decomposition reactor is arranged in series downstream of the first decomposition reactor, and the first decomposition gas discharged from the first decomposition reactor is supplied to the second decomposition reactor through the second superheater.

5 . The gas turbine plant with the ammonia decomposition system of claim 1 , wherein the second decomposition gas that is exhausted from the second decomposition reactor is branched as the portion of the second decomposition gas received by the separator and as a second portion of the second decomposition gas supplied to the second combustion and is combusted, or
wherein the synthesis gas that is exhausted from the separator is branched as the portion of the synthesis gas supplied to the first combustor and as a second portion of the synthesis gas supplied to the second combustor and is combusted.

6 . The gas turbine plant with the ammonia decomposition system of claim 5 , wherein the second portion of the second decomposition gas exhausted from the second decomposition reactor or the second portion of the synthesis gas exhausted from the separator is expanded by a gas expander before being supplied to the second combustor.

7 . The gas turbine plant with an ammonia decomposition system of claim 1 , wherein the liquid ammonia exhausted from the preheater is branched as the portion of the liquid ammonia received by the vaporizer and as a second portion of the liquid ammonia supplied to the second combustor and is combusted, or
wherein the gaseous ammonia exhausted from the first superheater is branched as the portion of the gaseous ammonia received by the first decomposition reactor and as a second portion of the gaseous ammonia supplied to the second combustor and is combusted.

8 . The gas turbine plant with an ammonia decomposition system of claim 7 , wherein the second portion of the gaseous ammonia exhausted from the first superheater is expanded by a gas expander before being supplied to the second combustor.

Assignees

• Doosan Enerbility Co Ltd

Inventors

• Bak Byoung Gu
• Kim Jin Il
• Kim Tae Woo
• Ha Hong Geun
• Bae Young Hoon
• Seon Chil Yeong
• Lee Ki Hyun
• Jeong Kwang Hun

Classifications

• F02C9/40

  specially adapted to the use of a special fuel or a plurality of fuels · CPC title

• F02C6/18 Primary

  using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants (using waste heat as source of energy for refrigeration plants F25B27/02; using the waste heat of a gasturbine for steam generation or in a steam cycle see F01K23/10) · CPC title

• F05D2220/62

  with energy recovery turbines · CPC title

• F05D2260/213

  by the provision of a heat exchanger within the cooling circuit · CPC title

• F02C7/224 Primary

  Heating fuel before feeding to the burner · CPC title