Electrode for nitrate reduction

Patent metadata

Field	Value
Publication number	US-12509371-B2
Application number	US-202318870256-A
Country	US
Kind code	B2
Filing date	Jun 1, 2023
Priority date	Jun 1, 2022
Publication date	Dec 30, 2025
Grant date	Dec 30, 2025

Abstract

A nitrate-reducing electrode, and methods of making the nitrate-reducing electrode are disclosed. The nitrate reducing electrode includes catalyst particulates disposed on water permeable substrates with the use of electrodeposition, electroless deposition, electrospinning, or thermal treatment. The catalyst particles include metals and metal oxides. The water permeable substrates are preferably made of carbonaceous materials using electrospinning and thermal treatment.

First claim

What is claimed:

1 . A method comprising, heating a carbonaceous water permeable substrate having a titanium compound and a metal catalyst disposed thereon or therein to increase oxygen vacancies (OVs).

2 . The method of claim 1 , wherein the titanium compound comprises titanium dioxide.

3 . The method of claim 1 , wherein the carbonaceous water permeable substrate having a titanium compound and a metal catalyst disposed thereon or therein is heated to a temperature in the range of from about 400° C. to about 700° C.

4 . The method of claim 1 , wherein the carbonaceous water permeable substrate having a titanium compound and a metal catalyst disposed thereon or therein is heated in a reducing atmosphere that comprises H2.

5 . A method comprising:
preparing a water permeable substrate that comprises electro spun nanofibers and that has a titanium compound disposed thereon or therein by electrospinning polymer fibers from a sol-gel comprising the titanium compound, a polymer precursor, and a suspending solvent to provide the water permeable substrate that comprises electro spun nanofibers and that has the titanium compound disposed thereon or therein; oxidatively stabilizing the electro spun nanofibers by heating in air at about 250° C. to provide the water permeable substrate that comprises oxidatively stabilized electro spun nanofibers and that has the titanium compound disposed thereon or therein; heating the water permeable substrate that comprises oxidatively stabilized electro spun nanofibers and that has the titanium dioxide disposed thereon or therein to a temperature in a range of about 800° C. to about 1200° C. to carbonize the oxidatively stabilized nanofibers and to provide the carbonaceous water permeable substrate having the titanium compound disposed thereon or therein; depositing a metal catalyst onto the carbonaceous water permeable substrate having the titanium compound disposed thereon to provide the carbonaceous water permeable substrate having the titanium compound and the metal catalyst disposed thereon or therein; heating the carbonaceous water permeable substrate having the titanium compound and the metal catalyst disposed thereon or therein to increase oxygen vacancies to provide the carbonaceous water permeable substrate having increased oxygen vacancies and having the titanium compound and the metal catalyst disposed thereon or therein; and incorporating the carbonaceous water permeable substrate having increased oxygen vacancies and having the titanium compound and a metal catalyst disposed thereon or therein into an electrode.

6 . The method of claim 5 , wherein the polymer precursor comprises polyacrylonitrile.

7 . A method comprising:
forming a carbonaceous water permeable substrate having a titanium compound and a metal catalyst disposed thereon or therein; and introducing oxygen vacancies into the carbonaceous water permeable substrate.

8 . The method of claim 7 , comprising forming the carbonaceous water permeable substrate having the titanium compound and the metal catalyst disposed thereon or therein and heat treating the carbonaceous water permeable substrate having the titanium compound and the metal catalyst disposed thereon or therein.

Assignees

• Univ Iowa Res Found
• Univ Texas

Inventors

• Cwiertny David
• Hussaini Syed Mubeen Jawahar
• Butzlaff Ashley Hesterberg
• Werth Charles
• Yan Chenxu

Classifications

• C02F2103/34

  from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 · CPC title

• C02F2103/26

  from the processing of plants or parts thereof · CPC title

• C02F2101/163

  Nitrates · CPC title

• C02F2001/46157

  Perforated or foraminous electrodes · CPC title

• C02F2001/46142

  Catalytic coating · CPC title