Filter comprising a silicone carbide separator layer

Patent metadata

Field	Value
Publication number	US-12508552-B2
Application number	US-202017627441-A
Country	US
Kind code	B2
Filing date	Jul 10, 2020
Priority date	Jul 18, 2019
Publication date	Dec 30, 2025
Grant date	Dec 30, 2025

Abstract

A filter for the filtration of a fluid, such as a liquid, includes or is constituted by a support element made from a porous ceramic material, at least a portion of the surface of the support element being covered with a porous membrane separating layer, the membrane separating layer being constituted essentially of silicon carbide (SiC), its porosity being between 10% and 70% by volume, the median diameter of its pores being between 50 nanometers and 500 nanometers, its mean thickness being between 1 micrometer and 30 micrometers, and its tortuosity being less than 1.7.

First claim

The invention claimed is:

1 . A filter for the filtration of a fluid, comprising or constituted by a support element made from a porous ceramic material, at least a portion of a surface of said support element being covered with a membrane separating layer, wherein:
said membrane separating layer is constituted of at least 95% by weight of silicon carbide (SiC) in α crystallographic form, a porosity of the membrane separating layer is between 10% and 70% by volume, a median pore diameter in the membrane separating layer is between 50 nanometers and 500 nanometers, a mean thickness of the membrane separating layer is between 1 micrometer and 30 micrometers, a tortuosity of the membrane separating layer is less than 1.7.

2 . The filter as claimed in claim 1 , wherein a median size of the grains constituting the membrane separating layer is less than 400 nm and greater than 80 nm.

3 . The filter as claimed in claim 2 , wherein the median size of the grains constituting the membrane separating layer is less than 300 nm.

4 . The filter as claimed in claim 1 , wherein the mean thickness of the separating layer is between 4 and 15 micrometers.

5 . The filter as claimed in claim 1 , wherein the median pore diameter in the separating layer is between 100 and 300 nm.

6 . The filter as claimed in claim 1 , additionally comprising one or more intermediate layers positioned between the material constituting the support element and the material constituting the membrane separating layer.

7 . The filter as claimed in claim 1 , wherein the intermediate layer or layers are essentially constituted of SiC.

8 . The filter as claimed in claim 1 , wherein at least one intermediate layer exhibits a median pore diameter at least two times greater than that of the membrane separating layer.

9 . The filter as claimed in claim 1 , wherein the intermediate layer or layers exhibit(s) a mean thickness of between 5 and 100 micrometers.

10 . The filter as claimed in claim 1 , wherein said support element is provided in the form of a plate, of a disk, of a tube or of a parallelepiped.

11 . The filter as claimed in claim 1 , wherein the porous support element comprises or is constituted by a material chosen from silicon carbide, SiC recrystallized SiC, silicon nitride, silicon oxynitride, silicon aluminum oxynitride, or a combination thereof.

12 . The filter as claimed in claim 1 , wherein an open porosity of the material constituting the support element is between 20% and 70%.

13 . The filter as claimed in claim 1 , wherein the tortuosity of the support element is greater than 1 and/or less than 2.

14 . The filter as claimed in claim 1 , wherein the fluid is a liquid.

15 . The filter as claimed in claim 1 , wherein the tortuosity of the membrane separating layer is less than 1.5.

16 . The filter as claimed in claim 3 , wherein the median size of the grains constituting the membrane separating layer is less than 250 nm.

17 . A process for the manufacture of a filter as claimed in claim 1 , comprising:
preparing a slip starting from a powder of silicon carbide particles with a mean size of between 0.05 and 0.4 micrometers, applying said slip to a support element, under conditions making possible the formation of a layer of the slip on at least a part of an external surface of said support, drying then firing under a nonoxidizing atmosphere at a temperature of between 1400° C. and 1600° C., and in said temperature range for a time sufficient to obtain the membrane separating layer, said layer being constituted of at least 95% by weight of silicon carbide (SiC) in α crystallographic form.

18 . The process for the manufacture of a filter as claimed in claim 17 , additionally comprising, before applying said slip, depositing at least one intermediate layer starting from a slip comprising a powder of silicon carbide particles, at least a fraction of the grains of which exhibits a median diameter of less than 1 micrometer and greater than 0.1 micrometer.

19 . A method comprising filtrating a liquid with a filter as claimed in claim 1 .

Assignees

• Saint Gobain Ct Recherches

Inventors

• Coeuret Xavier
• Vincent Adrien

Classifications

• C04B2235/6027

  Slip casting · CPC title

• C04B2235/5445

  submicron sized, i.e. from 0,1 to 1 micron · CPC title

• C04B2235/5436

  micrometer sized, i.e. from 1 to 100 micron · CPC title

• C04B2235/3895

  Non-oxides with a defined oxygen content, e.g. SiOC, TiON · CPC title

• C04B2235/3873

  Silicon nitrides, e.g. silicon carbonitride, silicon oxynitride · CPC title