Syndiotactic polybutadiene in non-tire applications

Patent metadata

Field	Value
Publication number	US-12503578-B2
Application number	US-202017753333-A
Country	US
Kind code	B2
Filing date	Aug 28, 2020
Priority date	Aug 28, 2019
Publication date	Dec 23, 2025
Grant date	Dec 23, 2025

Abstract

An air spring bellow formed from a rubber composition including a rubber component that contains a polyisoprene rubber and syndiotactic 1,2-polybutadiene. The syndiotactic 1,2-polybutadiene has a low crystallinity of 40 percent or less and the rubber composition includes a filler.

First claim

The invention claimed is:

1 . An air spring bellow comprising a rubber composition, the rubber composition comprising a rubber component comprising:
a. a rubber selected from the group consisting of a polyisoprene rubber and a neoprene rubber, b. 2 to 50 parts by mass of syndiotactic 1,2-polybutadiene per 100 parts by mass of the rubber component, the syndiotactic 1,2-polybutadiene having a crystallinity in the range of 3 to 40 percent, wherein the rubber composition is obtained by vulcanizing the rubber composition at a temperature of at least 140° C. and at least 1° to 30° C. above the melting point of the syndiotactic 1,2-polybutadiene, the syndiotactic 1,2-polybutadiene comprising a melting point in the range of 140° to 160° C.

2 . The air spring bellow of claim 1 , wherein the crystallinity of the syndiotactic 1,2-polybutadiene is in the range of −5 to 30 percent.

3 . The air spring bellow of claim 1 , wherein the syndiotactic 1,2-polybutadiene comprises a weight average molecular weight in the range of 100,000 to 850,000.

4 . The air spring bellow of claim 1 , wherein the syndiotactic 1,2-polybutadiene comprises a 1,2-bond content of 70 percent or more.

5 . The air spring bellow of claim 1 , wherein the syndiotactic 1,2-polybutadiene is present at 30 parts or less by mass per 100 parts by mass of the rubber component.

6 . The air spring bellow of claim 1 , wherein the neoprene rubber is polychloroprene.

7 . The air spring bellow of claim 1 , wherein the polyisoprene rubber, neoprene rubber or a combination thereof comprises 20 to 80 parts by mass per 100 parts by mass of the rubber component.

8 . The air spring bellow of claim 1 , wherein the rubber composition comprises a filler selected from the group consisting of carbon black, clay, silica and a combination thereof.

9 . The air spring bellow of claim 1 , wherein the rubber composition comprises 5 to 50 parts by mass of clay per 100 parts by mass of the rubber component.

10 . The air spring bellow of claim 9 , wherein the clay is a hydrated aluminum silicate.

11 . The air spring bellow of claim 1 , wherein the rubber composition comprises-10 to 85 parts by mass of carbon black per 100 parts by mass of the rubber component.

12 . The air spring bellow of claim 1 , wherein the rubber component further comprises polybutadiene rubber.

13 . A method of preparing the air spring bellow of claim 1 , the method comprising forming a vulcanizable composition comprising the polyisoprene rubber or the neoprene rubber, the syndiotactic 1,2-polybutadiene, a sulfur-based curative, zinc oxide, and an eutectic composition; and
heating the vulcanizable composition to thereby effect vulcanization to form the rubber composition.

14 . The method of claim 13 , wherein the vulcanizable composition comprises less than about 2 parts by mass of the zinc oxide per 100 parts by mass of the rubber component.

15 . The method of claim 13 , wherein the vulcanizable composition comprises less than about 1 parts by mass of the zinc oxide per 100 parts by mass of the rubber component.

16 . The method of claim 13 , wherein the vulcanizable composition comprises from about 0.005 to about 3 parts by mass of the eutectic composition per 100 parts by mass of the rubber component.

17 . The method of claim 13 , wherein the vulcanizable composition comprises from about 0.01 to about 1 parts by mass of the eutectic composition per 100 parts by mass of the rubber component.

18 . An air spring bellow comprising a rubber composition, the rubber composition comprising a rubber component comprising:
a. a rubber selected from the group consisting of a polyisoprene rubber and a neoprene rubber, b. 2 to 50 parts by mass of syndiotactic 1,2-polybutadiene per 100 parts by mass of the rubber component, the syndiotactic 1,2-polybutadiene having a crystallinity in the range of 3 to 40 percent, c. 5 to 50 parts by mass of clay per 100 parts by mass of the rubber component, and d. 10 to 85 parts by mass of carbon black per 100 parts by mass of the rubber component, wherein the rubber composition is obtained by vulcanizing the rubber composition at a temperature of at least 140° C. and at least 1° to 30° C. above the melting point of the syndiotactic 1,2-polybutadiene, the syndiotactic 1,2-polybutadiene comprising a melting point in the range of 140° to 160° C.

19 . The air spring bellow of claim 18 , wherein the crystallinity of the syndiotactic 1,2-polybutadiene is in the range of −5 to 30 percent.

Assignees

• Bridgestone Americas Tire Operations Llc

Inventors

• Ahmed Shammi
• Huang Yingyi

Classifications

• B29D22/023 Primary

  Air springs; Air bellows (construction of fluid springs F16F9/00) · CPC title

• C08K2003/2296

  of zinc · CPC title

• C08L11/00

  Compositions of homopolymers or copolymers of chloroprene · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title

• C08L9/00 Primary

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title