Method for preparing wet master batch elastomer composition

Patent metadata

Field	Value
Publication number	US-12503573-B2
Application number	US-202318095828-A
Country	US
Kind code	B2
Filing date	Jan 11, 2023
Priority date	Oct 14, 2022
Publication date	Dec 23, 2025
Grant date	Dec 23, 2025

Abstract

Disclosed is a method for preparing a wet master batch elastomer composition, comprising a first step of feeding silica particles and an organic silane coupling agent into an SSBR polymer solution; and a second step of grinding the silica particles, while stirring the SSBR polymer solution into which the silica particles and the organic silane coupling agent are fed, wherein a ratio of an average particle size of the ground silica particles to an average particle size of the silica particles is less than or equal to 0.8, and wherein the wet master batch elastomer composition has a bound rubber content of 30 to 80 wt. %.

First claim

What is claimed is:

1 . A method for preparing a wet master batch elastomer composition, the method comprising:
a first step of feeding silica particles and an organic silane coupling agent into an SSBR polymer solution; and a second step of grinding the silica particles, while stirring the SSBR polymer solution into which the silica particles and the organic silane coupling agent are fed, wherein a ratio of an average particle size of the ground silica particles to an average particle size of the silica particles is less than or equal to 0.8, and wherein the wet master batch elastomer composition has a bound rubber content of 30 to 80 wt. %.

2 . The method of claim 1 , wherein a ratio of an average particle size of the ground silica particles to an average particle size of the silica particles is less than or equal to 0.5.

3 . The method of claim 2 , wherein a ratio of an average particle size of the ground silica particles to an average particle size of the silica particles is less than or equal to 0.2.

4 . The method of claim 1 , wherein the stirring is performed by a grinding stirrer.

5 . The method of claim 4 , wherein a stirring rate of the stirring is greater than or equal to 1,000 rpm.

6 . The method of claim 4 , wherein a stirring time of the stirring is 0.1 to 60 minutes.

7 . The method of claim 1 , wherein a content of the silica particles is 40 to 200 parts by weight based on 100 parts by weight of the SSBR polymer.

8 . The method of claim 1 , wherein the organic silane coupling agent comprises a first organic silane compound represented by Formula 1 and a second organic silane compound represented by Formula 2:
(R 1 O) 3 —Si—R 2 —S—R 3 OR 4   [Formula 1]
wherein R 1 and R 3 are an aliphatic hydrocarbon group having 1 to 4 carbon atoms, R 2 is an aliphatic hydrocarbon group having 3 to 8 carbon atoms, and R 4 is an aliphatic hydrocarbon group having 1 to 20 carbon atoms,
(R 5 O) 3 —Si—R 6 —(S) n —R 6 —Si—(OR 5 ) 3   [Formula 2]

wherein each R 5 is independently an aliphatic hydrocarbon group having 1 to 4 carbon atoms, each R 6 is independently an aliphatic hydrocarbon group having 3 to 8 carbon atoms, and n is an integer of 1 to 4.

9 . The method of claim 1 , wherein a content of the organic silane coupling agent is 0.1 to 20 parts by weight based on 100 parts by weight of the SSBR polymer.

Assignees

• Korea Kumho Petrochemical Co Ltd

Inventors

• Ko Jae Young
• Kim Eunjoo
• Kim Seung Hyun
• Cho Kyeongjun

Classifications

• C08K3/36 Primary

  Silica · CPC title

• C08F236/10

  with vinyl-aromatic monomers · CPC title

• C08K5/5419

  containing at least one Si—C bond · CPC title

• C08K5/548 Primary

  containing sulfur {(C08K5/5477 takes precedence)} · CPC title

• C08K9/06

  with silicon-containing compounds · CPC title