Thermoplastic moulding composition with improved weathering resistance

Patent metadata

Field	Value
Publication number	US-12503528-B2
Application number	US-202118001085-A
Country	US
Kind code	B2
Filing date	Jun 9, 2021
Priority date	Jun 10, 2020
Publication date	Dec 23, 2025
Grant date	Dec 23, 2025

Abstract

A thermoplastic moulding composition has improved weathering resistance. A process for producing the thermoplastic moulding composition involves providing a thermoplastic polymer and adding at least one colouring preparation. Injection moulded parts and extruded parts can be composed of the thermoplastic moulding composition.

First claim

The invention claimed is:

1 . A thermoplastic moulding composition, comprising:
from 90.0 to 99.99989 wt.-% of a thermoplastic polymer; from 0.0001 to 5.0 wt.-% of carbon black; and from 0.00001 to 5.0 wt.-% of a monoazo dye, wherein the thermoplastic polymer is polymethyl methacrylate having a weight average molecular weight Mw of from 80,000 g/mol to 180,000 g/mol and is obtained by polymerization of a polymerizable composition whose polymerizable constituents comprise, based on a weight of the polymerizable composition: (i) from 50.0 to 99.9 wt.-% of methyl methacrylate, (ii) from 0.1 to 50.0 wt.-% of an acrylic acid ester of a C 1 -C 4 alcohol, and (iii) from 0.0 to 35.0 wt.-% of at least one further monomer copolymerizable with monomers (i) and (ii); and wherein the monoazo dye is at least one selected from the group consisting of 5-[(3,4-dichlorophenyl)azo]-1,2-dihydro-6-hydroxy-1,4-dimethyl-2-oxonicotinonitrile, 2,3-dihydro-2,2-dimethyl-6-((4-(phenylazo)-1-naphthyl)azo)-1H-perimidin, cyano-5-[[5-cyano-2,6-bis[(3-methoxypropyl)amino]-4-methylpyridin-3-yl]azo]-3-methyl-2-thiophenecarboxylic acid methyl ester, 5-methyl-2-phenyl-4-phenylazo-4H-pyrazol-3-one, 4-[(2,4-dimethylphenyl)azo]-2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-one, 3-[(1-oxonaphthalen-2-ylidene)methylhydrazinylidene]-1-prop-2-enylindol-2-one, 4-((o-methoxyphenyl)azo)-3-methyl-1-phenyl-2-pyrazolin-5-one, and 5-methyl-2-phenyl-4-phenylazo-4H-pyrazol-3-one.

2 . The thermoplastic moulding composition according to claim 1 , wherein the carbon black has a weight average particle size of from 5.0 to 100.0 nm, and a specific surface area, determined by BET method, of from 50 to 500 m 2 /g.

3 . The thermoplastic moulding composition according to claim 1 , further comprising:
at least one further dye selected from perinone dye, quinophthalone dye, and anthraquinone dye; at least one phthalocyanine pigment; or any mixture of the above.

4 . The thermoplastic moulding composition according to claim 1 , wherein the thermoplastic polymer comprises a polymer matrix and scattering particles dispersed in said polymer matrix, wherein the scattering particles have a weight average particle diameter of from 0.01 μm to 100.0 μm, and a refractive index of the scattering particles differs from that of the polymer matrix by at least 0.01.

5 . The thermoplastic moulding composition according to claim 1 , wherein the thermoplastic polymer is polymethyl methacrylate and the thermoplastic moulding composition has a melt flow rate from 0.5 to 10.0 g/10 min, measured at 230° C. with a load of 3.8 kg.

6 . A process for the manufacturing of the thermoplastic moulding composition according to claim 1 , the process comprising:
a) providing the thermoplastic polymer; and b) adding to the thermoplastic polymer from a) at least one colouring composition, comprising the carbon black and the monoazo dye.

7 . The process according to claim 6 , wherein the colouring composition is a liquid composition comprising:
from 1.0 to 30.0 wt.-% of a dispersing additive, from 0.05 to 10.0 wt.-% of the carbon black, from 0.5 to 50.0 wt.-% of the monoazo dye, from 0.0 to 50.0 wt.-% of an auxiliary additive, and a liquid, wherein portions by weight of components add up to 100 wt.-%.

8 . The process according to claim 6 , wherein the colouring composition is a masterbatch comprising:
from 0.01 to 40.0 wt.-% by weight of the monoazo dye, from 0.01 to 10.0 wt.-% by weight of the carbon black, from 50.0 to 99.98 wt.-% by weight of thermoplastic polymer, and from 0.0 to 10.0 wt.-% of an auxiliary additive.

9 . The process according to claim 6 , wherein the colouring composition comprises less than 100 ppm of aluminium or a compound thereof and less than 300 ppm of silicon or a compound thereof; and/or
the colouring composition has a mass loss in dried form of not more than 15 wt.-% in isothermal thermogravimetric analysis at 260° C. for 60 min.

10 . The process according to claim 6 , wherein the b) is carried out in an extruder.

11 . A process for the manufacturing of a moulded part, the process comprising:
injection moulding the thermoplastic moulding composition according to claim 1 , at a temperature ranging from 200° C. to 320° C., into a mould which can produce the moulded part.

12 . A process for the manufacturing of an extruded part, the process comprising:
extruding the thermoplastic moulding composition according to claim 1 , at a temperature ranging from 200° C. to 320° C., wherein the thermoplastic moulding composition is melted and die-casted to the extruded part.

13 . The process according to claim 11 , wherein the moulded part has different wall thicknesses, one or more perforations, at least one non-planar surface, or a combination of these features.

14 . A moulded part, obtained by the process according to claim 11 .

15 . A process for the manufacturing of the thermoplastic moulding composition according to claim 1 ,
the process comprising: a) providing the thermoplastic polymer; and b) adding to the thermoplastic polymer from a) at least one colouring composition, comprising the carbon black and the monoazo dye, wherein said colouring composition is a liquid composition comprising: from 1.0 to 30.0 wt.-% of a dispersing additive, from 0.05 to 10.0 wt.-% of the carbon black, from 0.5 to 50.0 wt.-% of the monoazo dye, from 0.0 to 50.0 wt.-% of an auxiliary additive, and a liquid, wherein portions by weight of components add up to 100 wt.-%.

16 . The process according to claim 7 , wherein the liquid is demineralized water or an organic solvent.

17 . The process according to claim 9 , wherein the colouring composition comprises less than 50 ppm of the aluminium or compound thereof and less than 200 ppm of the silicon or compound thereof; and/or
wherein the colouring composition has a mass loss in dried form of from 0.0 to 10 wt.-% in isothermal thermogravimetric analysis at 260° C. for 60 min.

18 . An extruded part, obtained by the process according to claim 12 .

Assignees

• Roehm Gmbh

Inventors

• Golchert Ursula
• Nau Stefan
• Becker Ernst

Classifications

• C08K5/3417

  condensed with carbocyclic rings · CPC title

• C08K5/23 Primary

  Azo-compounds · CPC title

• C08K3/04

  Carbon · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• C08K2201/006

  Additives being defined by their surface area · CPC title