Nickel catalysts with single alkali ions for homopolymerization and copolymerization

Patent metadata

Field	Value
Publication number	US-12503526-B2
Application number	US-202418734299-A
Country	US
Kind code	B2
Filing date	Jun 5, 2024
Priority date	Jul 27, 2022
Publication date	Dec 23, 2025
Grant date	Dec 23, 2025

Abstract

This invention relates to nickel catalysts with alkali ions for homopolymerization and copolymerization.

First claim

What is claimed is:

1 . A catalyst having a structure selected from Formula (1) and Formula (2):

wherein in Formula (1) and Formula (2):
Ar is 2,6-dimethoxyphenyl;
L is an optionally substituted phenyl group;
X is selected from hydrogen, an electron donating group, and an electron withdrawing group,
Y and Z are each independently selected from hydrogen, an electron donating group, and an electron withdrawing group, provided that Y and Z are not both hydrogen; and
R 1 , R 2 , and R 3 are each independently selected from optionally substituted aryl, optionally substituted alkyl, and optionally substituted cycloalkyl.

2 . The catalyst of claim 1 , wherein the electron donating group is selected from the group consisting of: alkoxy, phenoxy, amino, alkylamino, dialkylamino, hydroxy, alkyl, and cycloalkyl; and the electron withdrawing group is selected from the group consisting of: —NO 2 , —CN, —C(O)-alkyl, —C(O)Oalkyl, —C(O)Nalkyl, —SO 3 H, —SO 2 alkyl, —PO 3 H, —PO 3 alkyl, —CF 3 , and -halo.

3 . The catalyst of claim 1 , wherein
Ar is 2,6-dimethoxyphenyl; L is a phenyl group; X is methyl; Y and Z are each independently selected from hydrogen, an electron donating group, and an electron withdrawing group, provided that Y and Z are not both hydrogen; and R 1 , R 2 , and R 3 are each methyl.

4 . A method for catalyzing copolymerization of a first optionally substituted olefin and at least one other optionally substituted olefin, comprising:
contacting a first optionally substituted olefin and at least one other optionally substituted olefin with at least one catalyst of claim 1 and at least one alkali salt, whereby the first optionally substituted olefin and the at least one other optionally substituted olefin undergoes copolymerization, and wherein the first optionally substituted olefin and the at least one other optionally substituted olefin are different from one another.

5 . The method of claim 4 , wherein the at least one alkali salt comprises an alkali cation and a weakly coordinating anion.

6 . The method of claim 5 , wherein the alkali cation is Li + , Na + , K + , or Cs + .

7 . The method of claim 5 , wherein the weakly coordinating anion is tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, tetrakis(pentafluorophenyl)borate, tetraphenylborate, trifluoromethylsulfonate, hexafluorophosphate, hexafluoroantimonate, or tetrafluoroborate.

8 . The method of claim 4 , wherein the at least one alkali salt is lithium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, sodium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, potassium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, or cesium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, or any combination thereof.

9 . The method of claim 4 , wherein the step of contacting the first optionally substituted olefin and the at least one other optionally substituted olefin with the at least one catalyst and the at least one alkali salt is performed in the presence of at least one solvent.

10 . The method of claim 2 , wherein the at least one solvent is a non-polar solvent, a polar solvent, or combination thereof.

11 . The method of claim 4 , further comprising contacting at least one activator with the at least one catalyst, the at least one alkali salt, the first optionally substituted olefin, and the at least one other optionally substituted olefin.

12 . The method of claim 11 , wherein the at least one activator is selected from the group consisting of Ni(COD) 2 , triarylborane, methylaluminoxane, and trialkylaluminum.

13 . The method of claim 4 , wherein the first optionally substituted olefin and the at least one other optionally substituted olefin are each independently an optionally substituted terminal olefin or an optionally substituted internal olefin.

14 . The method of claim 4 , wherein the first optionally substituted olefin is ethylene.

15 . The method of claim 14 , wherein the at least one other optionally substituted olefin is selected from the group consisting of propene, butene, 1-hexene, 1-heptene, 1-octene, styrene, acrylamide, acrylic acid, acrylic ester, vinyl halide, vinyl alcohol, allyl alcohol, allylbenzene, 2-hexene, 3-hexene, 2-heptene, 3-heptene, 2-octene, 3-octene, and 4-octene.

16 . The method of claim 4 , wherein the at least one other optionally substituted olefin is selected from the group consisting of ethylene, propene, butene, 1-hexene, 1-heptene, 1-octene, styrene, acrylamide, acrylic acid, acrylic ester, vinyl halide, vinyl alcohol, allyl alcohol, allylbenzene, 2-hexene, 3-hexene, 2-heptene, 3-heptene, 2-octene, 3-octene, and 4-octene.

17 . The method of claim 14 , wherein the at least one other optionally substituted olefin is a polar olefin.

18 . The method of claim 4 , wherein the at least one other optionally substituted olefin is a polar olefin.

19 . A method for catalyzing homopolymerization of an optionally substituted olefin, comprising:
contacting an optionally substituted olefin with at least one catalyst of claim 1 and at least one alkali salt, whereby the optionally substituted olefin undergoes homopolymerization.

20 . The method of claim 19 , wherein the at least one alkali salt comprises an alkali cation and a weakly coordinating anion.

21 . The method of claim 20 , wherein the alkali cation is Li + , Na + , K + , or Cs + .

22 . The method of claim 20 , wherein the weakly coordinating anion is tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, tetrakis(pentafluorophenyl)borate, tetraphenylborate, trifluoromethylsulfonate, hexafluorophosphate, hexafluoroantimonate, or tetrafluoroborate.

23 . The method of claim 19 , wherein the at least one alkali salt is lithium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, sodium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, potassium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, or cesium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, or any combination thereof.

24 . The method of claim 19 , wherein the step of contacting the optionally substituted olefin with the at least one catalyst and the at least one alkali salt is performed in the presence of at least one solvent.

25 . The method of claim 24 , wherein the at least one solvent is a non-polar solvent, a polar solvent, or combination thereof.

26 . The method of claim 19 , further comprising contacting at least one activator with the at least one catalyst, the at least one alkali salt, and the optionally substituted olefin.

27 . The method of claim 26 , wherein the at least one activator is selected from the group consisting of Ni(COD) 2 , triarylborane, methylaluminoxane, and trialkylaluminum.

28 . The method of claim 19 , wherein the optionally substituted olefin is an optionally substituted terminal olefin or an optionally substituted internal olefin.

29 . The method of claim 19 , wherein the optionally substituted olefin is selected from the group consisting of ethylene, propene, butene, 1-hexene, 1-heptene, 1-octene, styrene, acrylamide, acrylic acid, acrylic ester, vinyl halide, vinyl alcohol, allyl alcohol, allylbenzene, 2-hexene, 3-hexene, 2-heptene, 3-heptene, 2-octene 3-octene, and 4-octene.

30 . The method of c

Assignees

• Univ Houston System

Inventors

• Do Loi H
• Tran Thi V

Classifications

• C08F10/02

  Ethene · CPC title

• C08F210/02

  Ethene · CPC title

• C08F2/06

  Organic solvent · CPC title

• B01J2531/0291

  Ligands adapted to form modular catalysts, e.g. self-associating building blocks as exemplified in the patent document EP-A-1 479 439 · CPC title

• B01J2531/15

  Caesium · CPC title