System for purifying argon by cryogenic distillation

Patent metadata

Field	Value
Publication number	US-12503365-B2
Application number	US-202217825032-A
Country	US
Kind code	B2
Filing date	May 26, 2022
Priority date	May 27, 2021
Publication date	Dec 23, 2025
Grant date	Dec 23, 2025

Abstract

System for purifying argon by cryogenic distillation, comprising a single column surmounted by a top-end condenser, a fluid inlet in the lower part of the column, a fluid outlet in the upper part of the column, and N distillation sections where N≥4, of which at least the two uppermost sections of the column are equipped respectively with a first liquid distributor and with a second liquid distributor, the second distributor being capable of performing a function of mixing together liquids that fall onto the distributor, each of the first and second distributors being positioned above the respective section and of which the two lowermost sections of the column are respectively equipped with a (N−1)th and an Nth liquid distributor capable of performing a function of mixing together liquids that fall onto the distributor, and which is arranged above the respective section, the first, second, (N−1)th and Nth distributors each being dimensioned to contain a maximum height of liquid head, that (those) of the first and second distributors being greater than that (those) of the (N−1)th and Nth distributors.

First claim

We claim:

1 . A system configured to purify argon by cryogenic distillation, the system comprising:
i. a single column surmounted by a top-end condenser, a fluid inlet in a lower part of the column, a fluid outlet in an upper part of the column, and N distillation sections where N≥4, each section being made up of a stack of units of structured packing, of a cross-corrugated type, each of said units of structured packing comprising a packet of rectangular corrugated sheets, of which at least the two uppermost sections of said N distillation sections of said single column are equipped respectively with a first liquid distributor and with a second liquid distributor, the second liquid distributor being configured to perform a function of mixing together liquids that fall onto the second liquid distributor, each of the first and second liquid distributors being positioned above a respective section among said two uppermost sections and of which at least two lowermost sections of the column are respectively equipped with a (N−1) th and an Nth liquid distributor configured to perform a function of mixing together liquids that fall onto the (N−1) th liquid distributor and the Nth liquid distributor, and which is arranged above the respective section; or ii. a first column and a second column surmounted by a top-end condenser, a fluid inlet in a lower part of the first column, a fluid outlet in an upper part of the second column, means for connecting a top end of the first column and a bottom end of the second column to allow a bottom liquid from the second column to be conveyed to the top end of the first column and allow a top-end gas from the first column to be conveyed to the second column, the first and second columns comprising in total N distillation sections where N≥4, each section being made up of a stack of units of structured packing, of a cross-corrugated type, each of said stack of units of structured packing comprising a packet of rectangular corrugated sheets, of which at least a two uppermost sections of the second column are equipped respectively with a first liquid distributor and with a second liquid distributor configured to perform a function of mixing together liquids that fall onto the first liquid distributor of the second liquid distributor respectively, each of the first and second liquid distributors being positioned above a respective section and of which at least two lowermost sections of the first column are respectively equipped with a (N−1)th and an Nth liquid distributor configured to perform a function of mixing together liquids that fall onto the (N−1)th liquid distributor and the Nth liquid distributor, and which is arranged above the respective section, wherein the first, second, (N−1)th and Nth liquid distributors are each dimensioned to contain a maximum height of liquid head, wherein the maximum height of liquid head for which the first and second liquid distributors are dimensioned is greater than the maximum height of liquid head for which the (N−1)th and Nth liquid distributors are dimensioned.

2 . The system according to claim 1 , comprising the single column comprising the N distillation sections where N≥8, each distillation section being made up of the stack of units of structured packing, of the cross-corrugated type, each stack of units of structured packing comprising a packet of rectangular corrugated sheets, of which at least a three uppermost sections of said N distillation sections of the single column are equipped respectively with a first liquid distributor and with a second liquid distributor configured to perform a function of mixing together liquids that fall onto the first liquid distributor or the second liquid distributor, respectively, and with a third liquid distributor configured to perform a function of mixing together liquids that fall onto the third liquid distributor, each of the first, second and third distributors being arranged above the respective distillation section; and
at least a five lowermost sections of said N distillation sections of the single column being respectively equipped with a liquid distributor configured to perform a function of mixing together liquids that fall onto the respective liquid distributor, and which is arranged above the respective distillation section, wherein the first, second, third, (N−4)th, (N−3)th, (N−2)th, (N−1)th and Nth liquid distributors are each dimensioned to contain a maximum height of liquid head, wherein the maximum height of liquid head of the first, second and third liquid distributors are dimensioned is greater than the maximum height of liquid head of the (N−4)th, (N−3)th, (N−2)th, (N−1)th and Nth liquid distributors are dimensioned.

3 . The system according to claim 1 , wherein the (N−1) th and Nth liquid distributors are dimensioned to contain the maximum height of liquid head that is at least 30% less than the maximum height of liquid head for which the first and second liquid distributors are dimensioned.

4 . The system according to claim 1 , wherein the maximum height of liquid head of the (N−1)th and Nth liquid distributors is greater than 50 mm.

5 . The system according to claim 1 , wherein the maximum height of liquid head of the first and second liquid distributors is between 150 and 300 mm.

6 . The system according to claim 1 , comprising the single column comprising the N distillation sections where N≥8, each distillation section being made up of a stack of units of structured packing, of the cross-corrugated type, each of said stack of units of structured packing comprising a packet of rectangular corrugated sheets, of which at least a three uppermost sections of said N distillation section of the single column are equipped respectively with a first liquid distributor, with a second liquid distributor configured to perform a function of mixing together liquids that fall onto the first or second liquid distributor, and with a third liquid distributor configured to perform a function of mixing together liquids that fall onto the third liquid distributor, each of the first, second and third liquid distributors being arranged above the respective distillation section, and
at least a five lowermost sections of said N distillation section of the single column being respectively equipped with a liquid distributor configured to perform a function of mixing together liquids that fall onto the respective liquid distributor, and which is arranged above the respective distillation section, the first, second and third, liquid distributors each comprising at least two rows of perforations configured to distribute liquid, one row being arranged above the other, and
the (N−4)th, (N−3)th, (N−2)th, (N−1) th and Nth liquid distributors comprising a single row of perforations configured to distribute liquid.

7 . The system according to claim 1 , wherein the first liquid distributor is configured to ensure a difference in liquid flow rate of less than 1% across various zones of a horizontal cross-section of the distillation section supplied by said first liquid distributor when a flow rate of a fluid entering the fluid inlet of the single column or the first column is between 25% and 45% of a nominal operation load for the single column or the first column.

8 . The system according to claim 1 , wherein each of the liquid distributors from the second liquid distributor to the (N−1) th liquid distributor, inclusive, is configured to mix liquids received thereon by directing at least 20% of a liquid flow falling onto one zone of said liquid distributor's horizontal cross-section to a zone diametrically opposite said one zone along at least one axis of said liquid distributor.

Assignees

• Air Liquide

Inventors

• Saulnier Bernard
• Trueba Antonio

Classifications

• F25J2250/40

  One fluid being air · CPC title

• F25J3/04412 Primary

  in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title

• F25J3/04096

  of argon or argon enriched stream · CPC title

• F25J3/0409

  of oxygen · CPC title

• F25J2290/20

  Particular dimensions; Small scale or microdevices · CPC title