Long-chain branched ethylene-based polymers

Patent metadata

Field	Value
Publication number	US-12497472-B2
Application number	US-202117907363-A
Country	US
Kind code	B2
Filing date	Mar 26, 2021
Priority date	Mar 27, 2020
Publication date	Dec 16, 2025
Grant date	Dec 16, 2025

Abstract

Embodiments of this disclosure are directed to ethylene-based polymers. The ethylene-based polymers are polymerized units derived from ethylene, diene, and optionally one or more C 3 -C 12 α-olefins. The ethylene-based polymer includes a melt strength greater than negative 17 times the log base 10 of the melt index plus 25 ((MS)>−17*log (MI)+25). In the equation, MS is the melt strength in cN and MI is the melt index in g/10 min according to ASTM D1238. The ethylene-based polymer also includes an average g′ that is greater than 0.70. The average g′ is an intrinsic viscosity ratio determined by gel permeation chromatography using a triple detector.

First claim

The invention claimed is:

1 . An ethylene-based polymer comprising polymerized units derived from ethylene, diene, and optionally one or more C 3 -C 12 α-olefins, wherein the ethylene-based polymer comprises:
a melt strength (MS)>−17*log (MI)+25, wherein MS is the melt strength in cN (Rheotens device, 190° C., 2.4 mm/s 2 , 120 mm from the die exit to the center of the wheels, extrusion rate of 38.2 s-1, capillary die of 30 mm length, 2 mm diameter and 180° entrance angle) and MI is the melt index in g/10 min according to ASTM D1238; and
an average g′ is greater than 0.70, where the average g′ is an intrinsic viscosity ratio determined by gel permeation chromatography using a triple detector.

2 . The ethylene-based polymer of claim 1 , wherein the diene is unconjugated and acyclic.

3 . The ethylene-based polymer of claim 2 , wherein the diene comprises 1,4-pentadiene, 1,5-hexadiene, 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, dimethyldivinylsilane, dimethyldiallylsilane, dimethylallylvinylsilane.

4 . The ethylene-based polymer of claim 1 , wherein the ethylene-based polymer comprises a low molecular weight polymer fraction and a high molecular weight polymer fraction, wherein the low molecular weight polymer fraction and the high molecular weight polymer fraction each comprise polymerized units derived from ethylene, diene, and one or more C 3 -C 12 α-olefins.

5 . The ethylene-based polymer of claim 4 , wherein the high molecular weight polymer fraction comprises 0.5 to 30% by weight of the polymer.

6 . The ethylene-based polymer of claim 5 , wherein the high molecular weight polymer fraction comprises between 1 and 15% by weight of the polymer.

7 . The ethylene-based polymer of claim 1 , wherein the MI is greater than 0.1, wherein MI is the melt index in g/10 min according to ASTM D1238.

8 . The ethylene-based polymer of claim 7 , wherein the MI is from 0.1 to 5.0, wherein MI is the melt index in g/10 min according to ASTM D1238.

9 . The ethylene-based polymer of claim 1 , wherein the MS is greater than 45 cN.

10 . The ethylene-based polymer of claim 7 , wherein the MI is greater than 1, wherein MI is the melt index in g/10 min according to ASTM D1238.

11 . The ethylene-based polymer of claim 10 , wherein the MI is greater than 2, wherein MI is the melt index in g/10 min according to ASTM D1238.

12 . The ethylene-based polymer of claim 1 , wherein MS>−17*log (MI)+30.

13 . The ethylene-based polymer of claim 12 , wherein MS>−17*log (MI)+35.

14 . The ethylene-based polymer of claim 1 , wherein the ethylene-based polymer has an average g′ is greater than 0.86, where the average g′ is an intrinsic viscosity ratio determined by gel permeation chromatography using a triple detector.

15 . The ethylene-based polymer of claim 14 , wherein the average g′ is greater than 0.88.

16 . The ethylene-based polymer of claim 15 , wherein the average g′ is greater than 0.90.

17 . The ethylene-based polymer of claim 1 , wherein the ethylene-based polymer has a weight averaged molecular weight (M w ) of less than or equal to 250,000 Daltons, as determined by absolute gel permeation chromatography.

18 . The ethylene-based polymer of claim 17 , wherein the ethylene-based polymer has a weight averaged molecular weight (M w ) of less than or equal to 150,000 Daltons, as determined by absolute gel permeation chromatography.

19 . The ethylene-based polymer of claim 1 , wherein the ethylene-based polymer has a molecular weight tail quantified by an MWD area metric, A TAIL , and A TAIL is greater than 0.08 as determined by gel permeation chromatography using a triple detector.

20 . The ethylene-based polymer of claim 19 , wherein the A TAIL is greater than 0.10.

Assignees

• Dow Global Technologies Llc

Inventors

• Froese Robert D J
• Lu Keran
• Sammler Robert L
• Den Doelder Cornelis F J
• Kashyap Teresita
• Martinetti Luca

Classifications

• C08L2207/07

  Long chain branching · CPC title

• C08L23/0892

  with monomers containing atoms other than carbon, hydrogen or oxygen · CPC title

• C08F4/76

  selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum · CPC title

• C08F4/6592

  containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring · CPC title

• C08F4/64044

  NN · CPC title