Artificial tanzanite and its manufacturing method

Patent metadata

Field	Value
Publication number	US-12497300-B2
Application number	US-202217985282-A
Country	US
Kind code	B2
Filing date	Nov 11, 2022
Priority date	Nov 11, 2022
Publication date	Dec 16, 2025
Grant date	Dec 16, 2025

Abstract

An artificial tanzanite comprises aluminosilicate and vanadium, wherein the content of the aluminosilicate is in a range from 1 mass % to 30 mass % and the content of the vanadium is in a range from 1000 ppm to 40000 ppm. The artificial tanzanite is prepared by a method comprising: providing a synthetic raw material, wherein the synthetic raw material comprises the aluminosilicate, silicon-containing oxide, vanadium-containing oxide, and calcium-containing salt; and heating the synthetic raw material to a synthetic temperature, and keeping the synthetic raw material under a synthetic pressure to carry out synthetic reaction to form the artificial tanzanite after a period of synthetic time.

First claim

What is claimed is:

1 . An artificial tanzanite comprising aluminosilicate, calcium, aluminum, silicon and vanadium, wherein the content of the aluminosilicate is in a range from 1 mass % to 30 mass %, and the content of the vanadium is in a range from 1,000 ppm to 40,000 ppm.

2 . The artificial tanzanite as claimed in claim 1 , wherein the artificial tanzanite is prepared by a method comprising:
step S 1 : providing a synthetic raw material, wherein the synthetic raw material comprises the aluminosilicate, silicon-containing oxide, vanadium-containing oxide, and calcium-containing salt; and step S 2 : heating the synthetic raw material to a synthetic temperature, and keeping the synthetic raw material under a synthetic pressure to carry out synthetic reaction to form the artificial tanzanite after a period of synthetic time.

3 . The artificial tanzanite as claimed in claim 2 , wherein the synthetic raw material further comprises an organic acid for mixing the aluminosilicate, the silicon-containing oxide, the vanadium-containing oxide and the calcium-containing salt so as to make the synthetic raw material in an acidic state.

4 . The artificial tanzanite as claimed in claim 3 , wherein the organic acid is selected from the group consisting of aconitic acid, glyceric acid, malic acid, tartaric acid, glycolic acid, 1,2,3,4-butanetetracarboxylic acid, tricarballylic acid, malonic acid, propionic acid, acrylic acid, oxalic acid, lactic acid, citric acid, acetic acid, thioglycolic acid, ethylenediaminetetraacetic acid, iminodiacetic acid, formic acid, phthalic acid, butyric acid, maleic acid, isocitric acid, gluconic acid, adipic acid, glutamic acid, p-toluenesulfonic acid, methanesulfonic acid and benzenesulfonic acid.

5 . The artificial tanzanite as claimed in claim 3 , wherein the pH of the organic acid is less than 4.

6 . The artificial tanzanite as claimed in claim 2 , wherein the calcium-containing salt is selected from the group consisting of calcium oxalate, calcium gluconate, calcium lactate, calcium acetate, calcium chlorate, calcium carbonate, calcium phosphate, calcium hydrogen phosphate, calcium sulfite, calcium sulfate, calcium nitrate, calcium oxide, calcium chloride, calcium bromide, calcium iodide, calcium fluoride, calcium hydroxide and calcium iodate.

7 . The artificial tanzanite as claimed in claim 2 , wherein the aluminosilicate is selected from the group consisting of kyanite, andalusite and sillimanite, and the silicon-containing oxide is selected from the group consisting of silica, sand, mullite, quartz and glass.

8 . The artificial tanzanite as claimed in claim 2 , wherein the vanadium-containing oxide is selected from the group consisting of vanadium monoxide, vanadium dioxide, vanadium trioxide, vanadium tetroxide and vanadium pentoxide.

9 . The artificial tanzanite as claimed in claim 2 , wherein the synthetic temperature is in a range from 160° C. to 430° C.

10 . The artificial tanzanite as claimed in claim 2 , wherein the synthetic pressure is in a range from 50 atm to 100 atm.

11 . The artificial tanzanite as claimed in claim 2 , wherein the calcium-containing salt is a calcium-containing hydroxide, the synthetic temperature is in a range from 500° C. to 700° C., and the synthetic pressure is in a range from 1.2 GPa to 1.7 GPa.

Assignees

• Univ Nat Cheng Kung

Inventors

• Chen Yen-Hua
• Ni Jia-Cheng

Classifications

• C01F11/00

  Compounds of calcium, strontium, or barium (C01F7/00 takes precedence) · CPC title

• C01G31/02

  Oxides · CPC title

• C01B33/26 Primary

  Aluminium-containing silicates {, i.e. silico-aluminates} · CPC title