Composite films for mobile electronic device components

Patent metadata

Field	Value
Publication number	US-12490377-B2
Application number	US-202218681799-A
Country	US
Kind code	B2
Filing date	Aug 5, 2022
Priority date	Aug 6, 2021
Publication date	Dec 2, 2025
Grant date	Dec 2, 2025

Abstract

The present disclosure relates to a composite film made of at least LCP and a fiber fabric, for example presenting a thickness of less than 0.10 mm, as well as articles comprising such composite films, exhibiting low dielectric constant and dissipation factors and being suitable for mobile electronic device components, for example flexible printed circuit board (FPC).

First claim

The invention claimed is:

1 . A composite film comprising:
at least one Liquid Crystalline Polyester (LCP), and at least one fiber fabric (F), wherein the LCP comprises: a) repeat units of formula (IV):

b) repeat units of formula (V):

c) repeat units of formula (VI):

and
d) repeat units of formula (VII):

wherein the proportions of these repeat units are the following:
repeat units (IV): from 10.0 mol % to 25.0 mol %;
repeat units (V): from 10.0 mol % to 30.0 mol %;
repeat units (VI): from 30.0 mol % to 80.0 mol %;
repeat units (VII): from 1.0 mol % to 10.0 mol %;

these proportions in mol % being based on the total number of moles in the LCP.

2 . The composite film of claim 1 , wherein the total proportion of repeat units (IV) to (VII) is at least 95.0 mol %.

3 . The composite film of claim 1 , wherein the repeat units of the LCP consist essentially of the repeat units (IV)-(VII).

4 . The composite film of claim 1 , wherein the proportions of repeat units (IV)-(VII) are the following:
repeat units (IV): from 10.0 mol % to 20.0 mol %; repeat units (V): from 15.0 mol % to 25.0 mol %; repeat units (VI): from 30.0 mol % to 80.0 mol %; repeat units (VII): from 1.0 mol % to 10.0 mol %.

5 . The composite film of claim 1 , wherein the proportions of repeat units (IV)-(VII) are the following:
repeat units (IV): from 13.0 mol % to 17.0 mol %; repeat units (V): from 18.0 mol % to 22.0 mol %; repeat units (VI): from 58.0 mol % to 62.0 mol %; repeat units (VII): from 2.0 mol % to 7.0 mol %.

6 . The composite film according to claim 1 wherein the molar ratio (VII)/[(VII)+(IV)] is lower than 0.45.

7 . The composite film according to claim 1 , wherein the LCP includes at least one additive blended with the LCP and selected from the group consisting of plasticizers, light and weathering stabilizers, antistatic agents, ultraviolet absorbing agents, dyes, pigments, viscosity agents and lubricants.

8 . The composite film according to claim 1 , wherein the LCP includes at least one filler blended with the LCP and selected from the group consisting of glass fibers, silica, alumina, aluminium borate, silicon carbide, mica, talc, clay, titanium oxide, zirconia, kaolin, calcium carbonate, magnesium carbonate, calcium sulfate, barium sulfate, magnesium hydroxide, quartz, graphite, carbon fibers, bentonite, and calcium phosphate.

9 . The composite film of claim 1 , wherein the fiber fabric (F) is an aramid fabric, a glass fiber fabric or a quartz fabric.

10 . The composite film of claim 1 , wherein the fiber fabric (F) is a woven fabric.

11 . The composite film of claim 1 , wherein the fiber fabric (F) is such that it has an average area weight comprised between 10 gsm and 100 gsm.

12 . The composite film of claim 1 , presenting a thickness of less than 0.10 mm.

13 . The composite film of claim 1 , wherein the fiber fabric (F) is impregnated with the Liquid Crystalline Polyester (LCP) on both faces of the fiber fabric.

14 . The composite film of claim 1 , wherein the volume fiber Vf is between 10.0 and 60.0 vol. %, Vf being calculated according to the following equation:

V
f

=

Volume
⁢

of
⁢

fiber

Volume
⁢

of
⁢

fiber

+

Volume
⁢

of
⁢

polymer

×
100.

15 . The composite film of claim 1 , wherein the LCP exhibits a melting point Tm of:
at least 305° C.; Tm being measured by Differential Scanning calorimetry (“DSC”).

16 . The composite film of claim 1 , wherein the film has:
dielectric constant Dk at 20 GHz of less than 3.9, as measured by Split Cylinder Resonator, IPC TM-650 2.5.5.13 after drying 1 h at 100° C., and/or a dissipation factor Df at 20 GHz of less than 0.002, as measured by Split Cylinder Resonator, IPC TM-650 2.5.5.13 after drying 1 h at 100° C.

17 . The composite film of claim 1 , wherein the film has:
dielectric constant Dk at 20 GHz of less than 3.7, as measured by Split Cylinder Resonator, IPC TM-650 2.5.5.13 after immersion in water for 24 hours, and/or a dissipation factor Df at 20 GHz of less than 0.002, as measured by Split Cylinder Resonator, IPC TM-650 2.5.5.13 after immersion in water for 24 hours.

18 . The composite film according to claim 1 , exhibiting a dissipation factor Df at 20 GHz which is less than 0.0020, as measured by Split Cylinder Resonator, IPC TM-650 2.5.5.13 after drying 1 h at 100° C.

19 . The composite film according to claim 1 , exhibiting a dissipation factor Df at 20 GHz which is be less than 0.0020, as measured by Split Cylinder Resonator, IPC TM-650 2.5.5.13 after immersion in water for 24 hours.

20 . An article or component article, comprising at least one composite film according to claim 1 , and a metal layer, the composite film being in contact with the metal layer.

21 . A method comprising preparing a mobile electronic device article or component with at least one composite film of claim 1 .

Assignees

• Syensqo Specialty Polymers Usa Llc
• Cytec Ind Inc

Inventors

• Chen Nan
• Williams Lewis Karl
• Gunther Val Glade
• Apostolo Marco
• Khariwala Devang

Classifications

• H05K2201/0145

  Polyester, e.g. polyethylene terephthalate [PET], polyethylene naphthalate [PEN] · CPC title

• H05K2201/0141

  Liquid crystal polymer [LCP] · CPC title

• H05K1/038

  Textiles (used as reinforcing materials for organic insulating substrates H05K1/0366) · CPC title

• H05K1/0373

  containing additives, e.g. fillers (H05K1/036 takes precedence) · CPC title

• C09K2219/03

  in the form of films, e.g. films after polymerisation of LC precursor · CPC title