Ware washing solution containing oxidized starch

Patent metadata

Field	Value
Publication number	US-12486476-B2
Application number	US-201917753752-A
Country	US
Kind code	B2
Filing date	Sep 30, 2019
Priority date	Sep 30, 2019
Publication date	Dec 2, 2025
Grant date	Dec 2, 2025

Abstract

Consumer and industrial 2-in-1 alkaline ware washing compositions providing both detergency and rinseability in a single cleaning composition are disclosed. Further benefits can be achieved with low levels of rinse aid surfactants in a rinse additive following the alkaline ware washing composition, including levels of rinse additive surfactant of about 500 ppm surfactant or less. Alkaline ware washing compositions and methods of using the same provide user-friendly, solid, ware washing compositions without the need for using a separate rinse aid composition.

First claim

What is claimed is:

1 . A solid alkaline ware washing composition comprising:
about 50 wt-% to about 80 wt-% of an alkalinity source, wherein the alkalinity source comprises an alkali metal hydroxide; an oxidized starch; about 1 wt-% to about 10 wt-% of at least one builder, wherein the builder comprises an alkali metal gluconate; about 1 wt-% to about 10 wt-% of a water conditioning polymer, wherein the water conditioning polymer comprises a polycarboxylate; and a nonionic surfactant; wherein the composition provides at least substantially similar cleaning, sheeting and drying as separate detergent and rinse aid compositions that do not include the oxidized starch.

2 . The composition of claim 1 , wherein the builder is sodium gluconate.

3 . The composition of claim 1 , wherein the alkalinity source is sodium hydroxide.

4 . The composition of claim 1 , wherein the oxidized starch is present from about 0.1 wt-% to about 30 wt-%.

5 . The composition of claim 4 , wherein the oxidized starch has starch glucoside units oxidized to carboxyl groups or carbonyl groups.

6 . The composition of claim 4 , wherein the oxidized starch has a molecular weight between about 500 and about 60,000 g/mol.

7 . The composition of claim 1 , wherein the water conditioning polymer is a polyacrylate.

8 . The composition of claim 1 , wherein the nonionic surfactant is present from about 0.1 wt-% to about 30 wt-%.

9 . The composition of claim 8 , wherein the nonionic surfactant is a block polyoxypropylene-polyoxyethylene polymer surfactant.

10 . The composition of claim 1 , further comprising at least one additional functional ingredient comprising an enzyme, neutralizing agent, anti-etch agent, anti-corrosion agent, solidification agent, antiredeposition agent, antimicrobial agent, foam inhibiting surfactant, or combinations thereof.

11 . The composition of claim 10 , wherein the additional functional ingredient is an enzyme, and wherein the enzyme is an amylase.

12 . A method of cleaning and rinsing ware comprising:
forming a wash solution comprising water and a solid alkaline ware washing composition comprising an oxidized starch, about 50 wt-% to about 80 wt-% of an alkalinity source, wherein the alkalinity source comprises an alkali metal hydroxide, about 1 wt-% to about 10 wt-% of at least one builder, wherein the builder comprises an alkali metal gluconate, about 1 wt-% to about 10 wt-% of a water conditioning polymer, wherein the water conditioning polymer comprises a polycarboxylate, and a nonionic surfactant; contacting ware with said wash solution; rinsing said ware with water; wherein said wash solution provides at least substantially similar cleaning, sheeting and drying as separate detergent and rinse aid compositions that do not include the oxidized starch; and optionally wherein the ware comprises melamine, glass and/or ceramic.

13 . The method of claim 12 , wherein the nonionic surfactant is present from about 1 wt-% to about 20 wt-% of the solid alkaline ware washing composition.

14 . The method of claim 12 , wherein the alkalinity source comprises sodium hydroxide, wherein the builder comprises sodium gluconate, wherein the water conditioning polymer comprises a polyacrylate, and wherein the nonionic surfactant comprises a block polyoxypropylene-polyoxyethylene polymer surfactant.

15 . The method of claim 12 , wherein the wash solution comprising water and a solid alkaline ware washing composition has an active concentration between about 500 ppm to about 1500 ppm, and/or wherein the method does not include a separate rinse additive or rinse aid composition or includes a rinse additive or rinse aid composition providing no more than about 1000 ppm surfactant, or no more than about 500 ppm surfactant.

16 . The method of claim 12 , wherein the wash solution does not impart a visible layer, filming and/or spotting on the treated ware.

17 . The method of claim 12 , wherein the wash solution provides substantially similar cleaning performance to a two-part detergent and rinse aid composition that does not contain the oxidized starch, and/or wherein the solid alkaline ware washing composition is a single use or a multi-use solid composition, and wherein the solid alkaline ware washing composition is a pressed solid, cast solid, or extruded solid.

Assignees

• Ecolab Usa Inc

Inventors

• Lu Xin
• Li Chunyang
• Zhang Jinming

Classifications

• C11D2111/14

  Hard surfaces · CPC title

• C11D3/38609

  Protease or amylase in solid compositions only · CPC title

• C11D3/1213

  Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2 · CPC title

• C11D1/72

  Ethers of polyoxyalkylene glycols · CPC title

• C11D1/722

  Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; {Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups (C11D1/721 takes precedence)} · CPC title