Polyester film and method for producing same

Patent metadata

Field	Value
Publication number	US-12486368-B2
Application number	US-202117619613-A
Country	US
Kind code	B2
Filing date	Mar 8, 2021
Priority date	Mar 10, 2020
Publication date	Dec 2, 2025
Grant date	Dec 2, 2025

Abstract

A polyester film includes a polyester (A) composed mainly of polybutylene terephthalate and a polyester (B) composed mainly of polyethylene terephthalate, wherein a mass ratio (A/B) between the polyesters (A) and (B) is 70/30 to 55/45, a dry heat shrinkage rate (B) through heat treatment at 200° C. for 15 minutes is 35% or less in any of four directions (0°, 45° 90° and 135°) on the film surface, a difference between a maximum value and a minimum value of these dry heat shrinkage rates is 5% or less, a thickness variation in the four directions is 10% or less, and a crystallization index shown in DSC measurement is 25 to 55 J/g.

First claim

The invention claimed is:

1 . A polyester film having a layer (L1) and a layer (L2),
wherein the layer (L1) comprises a polyester (A) composed mainly of polybutylene terephthalate, a polyester (B) composed mainly of polyethylene terephthalate, and a low-molecular weight polymer having a weight average molecular weight (Mw) of 30,000 or less, and wherein the layer (L2) comprises the polyester (A) and the polyester (B), does not comprise the low-molecular weight polymer, wherein a mass ratio (A/B) between the polyesters (A) and (B) in the polyester film is 70/30 to 55/45, wherein the first dry heat shrinkage rate of the film through heat treatment of the film at 200° C. for 15 minutes is 35% or less in any of four directions on a film surface consisting of a 0° direction as an arbitrary direction, and a 45° direction, a 90° direction and a 135° direction clockwise from the 0° direction, and a difference between a maximum value and a minimum value of these dry heat shrinkage rates is 5% or less, wherein a thickness variation calculated from the following equation in the four directions is 10% or less:
Thickness variation (%)=( T max −T min )/ T ave ×100

T max : maximum thickness in four directions of polyester film T min : minimum thickness in four directions of polyester film T ave : average thickness in four directions of polyester film, and wherein a crystallization index shown in DSC measurement is 25 to 55 J/g.

2 . The polyester film according to claim 1 , wherein the polyester film has melting points in the range of 200 to 223° C. and in the range of 225 to 256° C.

3 . The polyester film according to claim 1 , wherein the first dry heat shrinkage rate through heat treatment at 200° C. for 15 minutes is 5% or more in any of four directions on a film surface consisting of a 0° direction as an arbitrary direction, and a 45° direction, a 90° direction and a 135° direction clockwise from the 0° direction.

4 . The polyester film according to claim 1 , wherein the film has the second dry heat shrinkage rate through heat treatment at 160° C. for 30 minutes of 3 to 20% in any of four directions on a film surface consisting of a 0° direction as an arbitrary direction, and a 45° direction, a 90° direction and a 135° direction clockwise from the 0° direction.

5 . A method for producing the polyester film of claim 1 , comprising stretching an unstretched sheet in a flow direction of the sheet (MD stretching) and then stretching the same in a width direction (TD stretching),
wherein the MD stretching is performed in two or more stages such that the MD stretching magnification (X) represented by a product of stretching magnifications in the respective stages in the MD stretching and the TD stretching magnification (Y) satisfy the following conditions: a stretching magnification ratio (X/Y) of 0.82 to 1.10, and an area magnification (XXY) of 12.00 to 16.00.

6 . The method for producing a polyester film according to claim 5 , wherein in the MD stretching, the stretching magnification (X n+1 ) in a (n+1)-th stage is higher than the stretching magnification (X n ) in an n-th stage.

7 . The method for producing a polyester film according to claim 5 , wherein at the temperature during extrusion into an unstretched sheet, the polyester (A) and the polyester (B) for use have a difference in melt viscosity of 65 Pa·s or less.

8 . A polyester film for lamination on a metal plate, comprising the polyester film of claim 1 .

9 . A polyester film for lamination on a metal can, comprising the polyester film of claim 1 .

10 . The polyester film for lamination on a metal can according to claim 9 , wherein the lamination is on an inner surface of the metal can.

11 . The polyester film for lamination on a metal can according to claim 9 , wherein the lamination is on an outer surface of the metal can.

12 . A laminated metal plate comprising the polyester film for lamination on a metal plate of claim 8 laminated on the metal plate.

13 . A metal container obtained by forming the laminated metal plate of claim 12 .

14 . The polyester film according to claim 1 , wherein the polyolefin comprises polyethylene or polypropylene.

Assignees

• Unitika Ltd

Inventors

• Ashihara Hiroshi
• Okuzu Takayoshi
• Akamatsu Ken
• Kurosawa Akiko
• Araki Goro
• KAJITA Akito

Classifications

• C08G63/183

  Terephthalic acids · CPC title

• B29L2031/717

  Cans, tins · CPC title

• B29K2995/0097

  Thickness · CPC title

• B29K2995/0053

  bi-axially · CPC title

• B29K2995/0049

  Heat shrinkable · CPC title