Process for controlling hydrogen sulfide and ammonia flow rates

Patent metadata

Field	Value
Publication number	US-12485384-B2
Application number	US-202217842592-A
Country	US
Kind code	B2
Filing date	Jun 16, 2022
Priority date	Aug 13, 2021
Publication date	Dec 2, 2025
Grant date	Dec 2, 2025

Abstract

A control process and apparatus provide feed forward control of stoichiometric proportions of hydrogen sulfide and ammonia to a thermal oxidizer and an ammonia scrubber, respectively. To account for unmeasured or uncalculated sulfur feed to the thermal oxidizer, a feed back measurement of sulfur dioxide and ammonia concentration is used to correct the flow rate of hydrogen sulfide to the thermal oxidizer and/or ammonia to the ammonia scrubber.

First claim

The invention claimed is:

1 . A process for controlling feed rates in a facility comprising:
determining the molar flow rate of hydrogen sulfide charged to a thermal oxidizer; determining the molar flow rate of ammonia charged to an ammonia scrubber; determining a concentration of sulfur oxide or ammonia in a stream exiting the ammonia scrubber and adjusting the flow rate of hydrogen sulfide in a sour gaseous stream and/or a solvent gaseous stream to the thermal oxidizer in response to the determination of the concentration of sulfur oxide in a flue gas stream; increasing the flow rate of the sour gaseous stream before increasing the flow rate of the solvent gaseous stream in response to the determination of the concentration of sulfur oxide in the flue gas stream; and controlling the flow rate of hydrogen sulfide to the thermal oxidizer and the flow rate of ammonia to the ammonia scrubber to provide stoichiometric molar proportions for a chemical reaction between ammonia and sulfur dioxide.

2 . The process of claim 1 wherein the sulfur charged to the thermal oxidizer is provided by said sour gaseous stream.

3 . The process of claim 1 further comprising determining the concentration of sulfur oxide or ammonia in a stream exiting the ammonia scrubber and adjusting the flow rate of ammonia to said ammonia scrubber in response to the determination of the concentration of sulfur oxide in the flue gas stream.

4 . The process of claim 3 wherein the ammonia charged to said ammonia scrubber is provided by an ammonia stripper off-gas stream and/or an ammonia storage stream.

5 . The process of claim 4 further comprising adjusting the flow rate of ammonia to the ammonia scrubber comprises decreasing the flow rate of the ammonia storage stream to the ammonia scrubber.

6 . The process of claim 5 further comprising diverting the ammonia stripper off-gas stream to an ammonia storage tank and/or to the thermal oxidizer to decrease the flow rate of ammonia to the ammonia scrubber.

7 . The process of claim 1 wherein said solvent gaseous stream and/or said sour gaseous stream is charged to a sulfur recovery unit, tail gas from said sulfur recovery unit is charged to said thermal oxidizer and flue gas from said thermal oxidizer is charged to said ammonia scrubber.

8 . The process of claim 1 wherein determining the molar flow rate of sulfur charged to a thermal oxidizer comprises determining the concentration of hydrogen sulfide in the sour gaseous stream and determining the concentration of hydrogen sulfide in the solvent gaseous stream.

9 . The process of claim 1 wherein determining the flow rate of ammonia charged to the ammonia scrubber comprises determining the concentration of ammonia in the ammonia stripper off-gas stream.

Assignees

• Uop Llc

Inventors

• Kardel Cameron
• Eizenga Donald
• Harris James W
• De Ren Jan
• Wisecarver Zudtky
• Green Alexander
• Whyman William J
• Clarke Ian

Classifications

• B01D53/58 Primary

  Ammonia · CPC title

• C01C1/245

  Preparation from compounds containing nitrogen and sulfur · CPC title

• G05D11/08

  by sensing concentration of mixture, e.g. measuring pH value · CPC title

• B01D53/346

  Controlling the process · CPC title

• C01C1/242

  Preparation from ammonia and sulfuric acid or sulfur trioxide · CPC title