Light-emitting device and electronic apparatus including the same

Patent metadata

Field	Value
Publication number	US-12484372-B2
Application number	US-202217989910-A
Country	US
Kind code	B2
Filing date	Nov 18, 2022
Priority date	Nov 23, 2021
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

A light-emitting device includes a first electrode, a second electrode, and an interlayer between the first electrode and the second electrode. The interlayer includes an emission layer, a third layer between the emission layer and the second electrode, a first layer between the third layer and the second electrode, and a second layer between the first layer and the third layer. The first layer includes a first metal-free material and a first metal-containing material, the second layer includes a second metal-free material and a second metal-containing material, the first metal-free material and the second metal-free material are different from each other, the first metal-containing material and the second metal-containing material are different from each other, and the third layer consists of a third metal-free material. Embodiments include an electronic apparatus including the light-emitting device.

First claim

What is claimed is:

1 . A light-emitting device comprising:
a first electrode; a second electrode; and an interlayer between the first electrode and the second electrode, wherein the interlayer comprises:
an emission layer;
a third layer between the emission layer and the second electrode;
a first layer between the third layer and the second electrode; and
a second layer between the first layer and the third layer,
the first layer comprises a first metal-free material and a first metal-containing material, the second layer comprises a second metal-free material and a second metal-containing material, the first metal-free material and the second metal-free material are different from each other, the first metal-free material comprises a phosphine oxide-based compound, a phenanthroline-based compound, or a combination thereof, the first metal-containing material and the second metal-containing material are different from each other, and the third layer consists of a third metal-free material.

2 . The light-emitting device of claim 1 , wherein
the interlayer comprises:
m emitting units; and
m−1 charge generation unit(s) between neighboring emitting units among the m emitting units,
m is an integer of 2 or more, and one of the m emitting units comprises the emission layer, the first layer, the second layer, and the third layer.

3 . The light-emitting device of claim 2 , wherein a maximum emission wavelength of light emitted from at least one of the m emitting units is different from a maximum emission wavelength of light emitted from at least one of the remainder of the m emitting units.

4 . The light-emitting device of claim 2 , wherein an emitting unit neighboring the second electrode among the m emitting units includes the emission layer, the first layer, the second layer, and the third layer.

5 . The light-emitting device of claim 2 , wherein m is 4.

6 . The light-emitting device of claim 5 , wherein
the m emitting units comprise a first emitting unit, a second emitting unit, a third emitting unit, and a fourth emitting unit, the m−1 charge generation units comprise a first charge generation unit, a second charge generation unit, and a third charge generation unit, the first charge generation unit is between the first emitting unit and the second emitting unit, the second charge generation unit is between the second emitting unit and the third emitting unit, the third charge generation unit is between the third emitting unit and the fourth emitting unit, the first emitting unit is between the first electrode and the first charge generation unit, the second emitting unit is between the first charge generation unit and the second charge generation unit, the third emitting unit is between the second charge generation unit and the third charge generation unit, the fourth emitting unit is between the third charge generation unit and the second electrode, and one of the first emitting unit, the second emitting unit, the third emitting unit, and the fourth emitting unit includes the emission layer, the first layer, the second layer, and the third layer.

7 . The light-emitting device of claim 6 , wherein the fourth emitting unit comprises the emission layer, the first layer, the second layer, and the third layer.

8 . The light-emitting device of claim 6 , wherein the fourth emitting unit emits green light.

9 . The light-emitting device of claim 1 , wherein the first metal-containing material comprises an alkali metal, an alkaline earth metal, a lanthanide metal, or a combination thereof.

10 . The light-emitting device of claim 1 , wherein the first metal-containing material is Yb, Li, Cu, Ag, Au, Al, Mg, or a combination thereof.

11 . The light-emitting device of claim 1 , wherein the second metal-free material comprises a compound including at least one of:
groups of Group 2A; a condensed cyclic group in which two or more groups of Group 2A are condensed with each other; or a condensed cyclic group in which at least one group of Group 2A and at least one of Group 2B are condensed with each other: [Group 2A] a pyridine group, a diazine group, a triazine group, a tetrazine group, [Group 2B] a benzene group.

12 . The light-emitting device of claim 1 , wherein the second metal-containing material comprises an alkali metal complex.

13 . The light-emitting device of claim 1 , wherein the third metal-free material comprises a compound comprising at least one of:
groups of Group 3A; a condensed cyclic group in which two or more groups of Group 3A are condensed with each other; or a condensed cyclic group in which at least one group of Group 3A and at least one of Group 3B are condensed with each other: [Group 3A] a pyridine group, a diazine group, a triazine group, a tetrazine group, [Group 3B] a benzene group.

14 . The light-emitting device of claim 1 , wherein the second metal-free material and the third metal-free material are identical to each other.

15 . The light-emitting device of claim 1 , wherein an amount of the second metal-free material is in a range of about 10 parts by weight to about 90 parts by weight, based on 100 parts by weight of the second metal-free material and the second metal-containing material.

16 . The light-emitting device of claim 1 , wherein the first layer directly contacts the second layer.

17 . The light-emitting device of claim 1 , wherein a thickness of the first layer is equal to or less than a thickness of the second layer.

18 . An electronic apparatus comprising:
the light-emitting device of claim 1 ; and a thin-film transistor, wherein the thin-film transistor comprises a source electrode and a drain electrode, and the first electrode of the light-emitting device is electrically connected to the source electrode or the drain electrode.

19 . The electronic apparatus of claim 18 , further comprising a color filter, a color conversion layer, a touch screen layer, a polarizing layer, or a combination thereof.

Assignees

• Samsung Display Co Ltd

Inventors

• Kang Namsu
• Park Heungsu
• Han Wonsuk
• Park Huiju
• Lee Hyunshik

Classifications

• H10K59/123

  Connection of the pixel electrodes to the thin film transistors [TFT] · CPC title

• H10K85/342

  comprising iridium · CPC title

• H10K85/654

  comprising only nitrogen as heteroatom (H10K85/652 takes precedence) · CPC title

• H10K85/631

  Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine · CPC title

• H10K85/6572

  comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole · CPC title