Stacked monolithic upright metamorphic multijunction solar cell

Patent metadata

Field	Value
Publication number	US-12484313-B2
Application number	US-201916715388-A
Country	US
Kind code	B2
Filing date	Dec 16, 2019
Priority date	Dec 14, 2018
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

A stacked monolithic upright metamorphic multijunction solar cell, comprising at least one first subcell having a first band gap, a first lattice constant and being made up of germanium by more than 50%, a second subcell, which is disposed above the first subcell and has a second band gap and a second lattice constant, a metamorphic buffer disposed between the first subcell and the second subcell, including a sequence of at least three layers having lattice constants which increase from layer to layer in the direction of the second subcell, and a first tunnel diode, which is situated between the metamorphic buffer and the second subcell and which has an n + layer and a p + layer, the second band gap being larger than the first band gap, the n + layer of the first tunnel diode comprising InAlP, the p + layer of the first tunnel diode comprising an As-containing III-V material.

First claim

What is claimed is:

1 . A stacked monolithic upright metamorphic multijunction solar cell comprising:
at least one first subcell having a first band gap, a first lattice constant, and is made of germanium by more than 50%; a second subcell, which is disposed above the first subcell, has a second band gap and a second lattice constant, and is made of AlInGaP; a metamorphic buffer disposed between the first subcell and the second subcell; and a first tunnel diode that includes an n+ layer and a p+ layer, the first tunnel diode being arranged between the metamorphic buffer and the second subcell, the p + layer of the first tunnel diode comprising an As-containing III-V material, wherein the second band gap is larger than the first band gap, wherein the second lattice constant is larger than the first lattice constant, wherein the n + layer of the first tunnel diode comprises In x Al 1-x P, where x>0.6, wherein an intermediate layer is disposed between the n + layer and the p + layer, wherein the intermediate layer is thinner than the n + layer and the p + layer, wherein the intermediate layer has a thickness of less than 6 nm or less than 4 nm, wherein the intermediate layer comprises GaAs or AlGaAs or AlInAs or InGaAs or AlInGaAs, wherein the intermediate layer is doped with silicon having a dopant concentration of at least 10 18 N/cm 3 , wherein an As content of the intermediate layer is higher than an As content of the n + layer, and wherein the intermediate layer suppresses cross contamination of dopants between the n + layer and the p + layer of the tunnel diode.

2 . The multijunction solar cell according to claim 1 , wherein the intermediate layer has an energy gap of ≥1.08 eV.

3 . The multijunction solar cell according to claim 1 , wherein the n + layer of the first tunnel diode is doped with silicon and/or with tellurium and/or with selenium and/or with sulfur having a dopant concentration of ≥10 19 N/cm 3 .

4 . The multijunction solar cell according to claim 1 , wherein the p + layer of the first tunnel diode comprises AlInAs.

5 . The multijunction solar cell according to claim 1 , wherein the p + layer of the first tunnel diode comprises Al x Ga y In 1-x-y As, where x>0.4.

6 . The multijunction solar cell according to claim 1 , wherein the p + layer of the first tunnel diode is doped with carbon.

7 . The multijunction solar cell according to claim 1 , wherein a lattice constant of the n + layer of the first tunnel diode corresponds to the second lattice constant of the second subcell, and
wherein a lattice constant of the p + layer of the first tunnel diode is equal to or less than the second lattice constant of the second subcell.

8 . The multijunction solar cell according to claim 1 , wherein the multijunction solar cell comprises additional subcells, each having a band gap, the additional subcells being disposed between the first tunnel diode and the first subcell, and the band gaps of the additional subcells each being larger than the first band gap of the first subcell and each being smaller than the second band gap of the second subcell.

9 . The multijunction solar cell according to claim 8 , wherein the multijunction solar cell comprises at least one additional tunnel diode.

10 . The multijunction solar cell according to claim 9 , wherein the at least one additional tunnel diode comprises an additional intermediate layer, an n + layer of the additional tunnel diode comprising InAlP or InGaP, a p + layer of the additional tunnel diode comprising an As-containing III-V material, the additional intermediate layer being disposed between the n + layer and the p + layer of the additional tunnel diode, and the additional intermediate layer being thinner than the n + layer and the p + layer of the additional tunnel diode.

11 . The multijunction solar cell according to claim 1 , wherein the multijunction solar cell is a 4-junction Ge/InGaAs/AlInGaAs/AlInGaP cell.

12 . The multijunction solar cell according to claim 1 , wherein the multijunction solar cell is a 5-junction Ge/InGaAs/AlInGaAs/InGaP/AlInGaP cell.

13 . The multijunction solar cell according to claim 1 , wherein the intermediate layer operates to counteract a reduction in a tunnel current of the first tunnel diode due to the n+ layer.

14 . A stacked monolithic upright metamorphic multijunction solar cell comprising:
at least one first subcell having a first band gap, a first lattice constant and is made of germanium by more than 50%; a second subcell, which is disposed above the first subcell, has a second band gap and a second lattice constant, and is made of AlInGaP; a metamorphic buffer disposed between the first subcell and the second subcell; and a first tunnel diode that includes an n+ layer and a p+ layer, the first tunnel diode being arranged between the metamorphic buffer and the second subcell, the p + layer of the first tunnel diode comprising an As-containing III-V material, wherein the second band gap is larger than the first band gap, wherein the second lattice constant is larger than first lattice constant, wherein the n + layer of the first tunnel diode comprises In x Al 1-x P, where x>0.6, wherein an intermediate layer is disposed between the n + layer and the p + layer, wherein the intermediate layer is thinner than the n + layer and the p + layer, wherein the intermediate layer has a thickness of less than 6 nm or less than 4 nm, wherein the intermediate layer comprises GaAs or AlGaAs or AlInAs or InGaAs or AlInGaAs such that the intermediate layer counteracts a reduction in a tunnel current of the first tunnel diode due to the n+ layer, and wherein the intermediate layer suppresses cross contamination of dopants between the n + layer and the p + layer of the tunnel diode.

15 . The multijunction solar cell according to claim 1 , wherein the second subcell is a topmost subcell.

16 . The multijunction solar cell according to claim 14 , wherein the second subcell is a topmost subcell.

17 . The multijunction solar cell according to claim 1 , wherein the second subcell is made entirely of AlInGaP.

18 . The multijunction solar cell according to claim 1 , wherein the intermediate layer has a one-part design and is made by metalorganic vapor phase epitaxy.

19 . The multijunction solar cell according to claim 1 , wherein the metamorphic buffer layer comprises a sequence of three layers, each of the three layers having a lattice constant, and
wherein the lattice constant of the three layers increases layers to layer in a direction of the second subcell.

Assignees

• Azur Space Solar Power Gmbh

Inventors

• Fuhrmann Daniel
• Van Leest Rosalinda
• Meusel Matthias

Classifications

• H10F77/1248

  having three or more elements, e.g. GaAlAs, InGaAs or InGaAsP · CPC title

• H10F71/1272

  comprising at least three elements, e.g. GaAlAs or InGaAsP · CPC title

• H10F10/163

  comprising only Group III-V materials, e.g. GaAs/AlGaAs or InP/GaInAs photovoltaic cells · CPC title

• H10F10/144

  comprising only Group III-V materials, e.g. GaAs,AlGaAs, or InP photovoltaic cells · CPC title

• H10F10/142 Primary

  comprising multiple PN homojunctions, e.g. tandem cells · CPC title