Heat treatment system, saggar and method of heat-treating

Patent metadata

Field	Value
Publication number	US-12482804-B2
Application number	US-202218046558-A
Country	US
Kind code	B2
Filing date	Oct 14, 2022
Priority date	Nov 18, 2021
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

A heat treatment system disclosed herein may include: one or more saggars, each of which is configured to accommodate powder of a lithium positive electrode material; and a heat treatment furnace configured to heat-treat the powder accommodated in the one or more saggars. Each of the one or more saggars may include a contact surface which is to make contact with the powder, wherein at least the contact surface of each saggar is constituted of a nickel-based alloy. The heat treatment furnace may be configured to heat-treat the powder accommodated in the one or more saggars at a temperature of 300° C. or more and 1000° C. or less for a duration of 10 hours or more and 30 hours or less.

First claim

What is claimed is:

1 . A heat treatment system comprising:
one or more saggars, each of which is configured to accommodate powder of a lithium positive electrode material, and each of which comprises a contact surface which is to make contact with the powder; a supply device configured to supply the powder into each of the one or more saggars; a heat treatment furnace configured to heat-treat the powder accommodated in each of the one or more saggars; a recovery device configured to recover the powder heat-treated by the heat treatment furnace from each of the one or more saggars; and a cleaning device configured to clean the contact surface of each of the one or more saggars after the heat-treated powder has been recovered by the recovery device, wherein at least the contact surface of each of the one or more saggars is constituted of a nickel-based alloy, the heat treatment furnace is configured to heat-treat the powder accommodated in each of the one or more saggars at a temperature of 300° C. or more and 1000° C. or less for a duration of 10 hours or more and 30 hours or less, the cleaning device is configured to remove the heat-treated powder having remained on the contact surface of each of the one or more saggars and a reaction product generated by heat-treating the powder from the contact surface of each of the one or more saggars after the heat-treated powder has been recovered by the recovery device, and the one or more saggars are used such that each of the one or more saggars circulates between the supply device, the heat treatment furnace, the recovery device, and the cleaning device.

2 . The heat treatment system according to claim 1 , wherein
the nickel-based alloy contains aluminum, and an aluminum content of the nickel-based alloy is 1 wt % or more and 10 wt % or less.

3 . The heat treatment system according to claim 2 , wherein
the one or more saggars are each configured such that a film thickness of an Al 2 O 3 film formed on the contact surface when the one or more saggars are exposed to an oxygen-containing atmosphere at the temperature of 800° C. for 10 hours is within a range of 1 μm to 1 mm.

4 . The heat treatment system according to claim 1 , wherein
the heat treatment furnace is configured to heat-treat the powder accommodated in the one or more saggars in an oxygen-containing atmosphere.

5 . The heat treatment system according to claim 1 , wherein
the heat treatment furnace comprises a heat treatment unit configured to heat-treat the powder accommodated in the one or more saggars and a cooling unit configured to cool the powder that has been heat-treated by the heat treatment unit.

6 . The heat treatment system according to claim 1 , wherein
the one or more saggars comprise a plurality of saggars, and the plurality of saggars is configured to be arranged in the heat treatment furnace in a state of being stacked in an up-down direction.

7 . A saggar for heat-treating powder of a lithium positive electrode material, the saggar being configured to accommodate the powder and to be disposed in a heat treatment furnace for heat treatment of the powder, wherein
the saggar comprises a contact surface which is to make contact with the powder, wherein at least the contact surface of the saggar is constituted of a nickel-based alloy, the nickel-based alloy contains aluminum, and an aluminum content of the nickel-based alloy is 1 wt % or more and 10 wt % or less, and the saggar is configured such that a film thickness of an Al 2 O 3 film formed on the contact surface when the nickel-based alloy is exposed to an oxygen-containing atmosphere at a temperature of 800° C. for 10 hours is within a range of 1 μm to 1 mm.

8 . A method of heat-treating powder of a lithium positive electrode material, the method comprising:
supplying the powder into one or more saggars, each of which comprises a contact surface which is to make contact with the powder; heat-treating the powder supplied in each of the one or more saggars, recovering the heat-treated powder from each of the one or more saggars, removing the heat-treated powder having remained on the contact surface of each of the one or more saggars and a reaction product generated by heat-treating the powder from the contact surface of each of the one or more saggars after recovering the heat-treated powder, and circulating the one or more saggars between supplying the powder into each of the one or more saggars, heat-treating the powder supplied in each of the one or more saggars, recovering the heat-treated powder from each of the one or more saggars, and removing the heat-treated powder having remained on the contact surface of each of the one or more saggars and a reaction product generated by heat-treating the powder from the contact surface of each of the one or more saggars after recovering the heat-treated powder, wherein at least the contact surface of each of the one or more saggars is constituted of a nickel-based alloy, and the heat-treating comprises heat-treating the powder supplied in each of the one or more saggars at a temperature of 300° C. or more and 1000° C. or less for a duration of 10 hours or more and 30 hours or less.

Assignees

• Ngk Insulators Ltd

Inventors

• Hirano Masatoshi
• Komaki Takeshi

Classifications

• F27D25/00

  Devices {or methods} for removing incrustations {, e.g. slag, metal deposits, dust; Devices or methods for preventing the adherence of slag} · CPC title

• F27D3/0033

  charging of particulate material · CPC title

• F27D5/0068 Primary

  Containers · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title