Total organic carbon measurement method and total organic carbon measurement device

Patent metadata

Field	Value
Publication number	US-12480928-B2
Application number	US-202017777417-A
Country	US
Kind code	B2
Filing date	Jun 17, 2020
Priority date	Nov 18, 2019
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

Provided are a total organic carbon measurement method and a total organic carbon measurement device capable of determining whether or not an acid has been added to a sample. An acid is introduced into a reaction unit in which the sample is placed from a reservoir in which the acid is reserved (step S103). The conductivity of the sample into which the acid has been introduced is measured (step S105). The introduction of the acid from the reservoir into the reaction unit is detected on the basis of a change in the conductivity of the sample (step S107).

First claim

The invention claimed is:

1 . A total organic-carbon measurement method comprising:
introducing an acid from a reservoir in which the acid is reserved into a reaction unit in which a sample is placed; measuring conductivity of the sample before the acid is introduced: measuring conductivity of the sample into which the acid is introduced; calculating a difference in the conductivity of the sample before and after the introduction of the acid; detecting the introduction of the acid from the reservoir into the reaction unit on a basis of the difference in the conductivity of the sample; and combusting the sample after the introduction of the acid and after aeration treatment, and measuring an amount of a generated carbon-based substance in a gas phase to obtain the total organic carbon in the sample.

2 . The total organic-carbon measurement method according to claim 1 , wherein
in the step of measuring conductivity of the sample into which the acid is introduced, a part of the sample into which the acid is introduced is supplied to a conductivity measurement unit, and conductivity of the sample supplied to the conductivity measurement unit is measured, and in the step of measuring an amount of a carbon-based substance in the gas phase, an amount of a carbon-based substance in a gas phase generated from at least a part of a remaining sample after the supply of a part of the sample to the conductivity measurement unit is measured.

3 . A total organic carbon measurement comprising:
introducing an acid from a reservoir in which the acid is reserved into a reaction unit in which a sample is placed; measuring conductivity of the sample before the acid is introduced; measuring conductivity of the sample into which the acid is introduced; calculating a difference in the conductivity of the sample before and after the introduction of the acid; detecting the introduction of the acid from the reservoir into the reaction unit on a basis of the difference in the conductivity of the sample; measuring an amount of total carbon contained in the sample by combusting the sample before the introduction of the acid and measuring an amount of a generated carbon-based substance in a gas phase; measuring an amount of a carbon-based substance in a gas phase generated by performing aeration treatment on the sample after the introduction of the acid; and subtracting the amount of the carbon-based substance in the gas phase after aeration treatment from the amount of the total carbon to obtain the total organic carbon in the sample.

4 . The total organic-carbon measurement method according to claim 3 , wherein in the step of measuring an amount of a carbon-based substance in a gas phase after aeration treatment, a part of the sample into which the acid is introduced is supplied to a carbon-based substance measurement unit, and an amount of a carbon-based substance in a gas phase generated from the sample supplied to the carbon-based substance measurement unit is measured, and
in the step of measuring conductivity of the sample into which the acid is introduced, conductivity of at least a part of a remaining sample after the supply of a part of the sample to the carbon-based substance measurement unit is measured.

5 . A total organic-carbon measurement device, comprising:
a reaction unit in which a sample is placed; an addition unit configured to introduce an acid into the reaction unit from a reservoir in which the acid is reserved; a first conductivity measurement unit that measures conductivity of the sample into which the acid is introduced; a second conductivity measurement unit that measures conductivity of the sample before the introduction of the acid; and an arithmetic unit that calculates a difference in the conductivity of the sample before and after the introduction of the acid; and a determination unit that determines the introduction of the acid from the reservoir into the reaction unit on a basis of the difference in the conductivity of the sample; and a carbon-based substance measurement unit that combusts the sample after the introduction of the acid and after aeration treatment, and measures an amount of a generated carbon-based substance in a gas phase to obtain the total organic carbon in the sample.

6 . The total organic-carbon measurement device according to claim 5 , wherein
a part of the sample into which the acid is introduced is supplied to the first conductivity measurement unit, and the carbon-based substance measurement unit measures an amount of a carbon-based substance in a gas phase generated from at least a part of a remaining sample after the supply of a part of the sample to the first conductivity measurement unit.

7 . The total organic-carbon measurement device according to claim 5 , wherein
a part of the sample into which the acid is introduced is supplied to the carbon-based substance measurement unit, and the first conductivity measurement unit measures conductivity of at least a part of a remaining sample after the supply of a part of the sample to the carbon-based substance measurement unit.

8 . A total organic carbon measurement device, comprising:
a reaction unit in which a sample is placed; an addition unit configured to introduce an acid into the reaction unit from a reservoir in which the acid is reserved; a first conductivity measurement unit that measures conductivity of the sample into which the acid is introduced; a second conductivity measurement unit that measures conductivity of the sample before the introduction of the acid; and an arithmetic unit that calculates a difference in the conductivity of the sample before and after the introduction of the acid; characterized in that the total organic carbon measurement device further comprises: a determination unit that determines the introduction of the acid from the reservoir into the reaction unit on a basis of the difference in the conductivity of the sample; a total carbon measurement unit that measures an amount of total carbon contained in the sample by combusting the sample before the introduction of the acid and measuring an amount of a generated carbon-based substance in a gas phase; and a carbon-based substance measurement unit that measures an amount of a carbon-based substance in a gas phase generated by performing aeration treatment on the sample after the introduction of the acid; wherein the arithmetic unit subtracts the amount of the carbon-based substance in the gas phase after aeration treatment from the amount of the total carbon to obtain the total organic carbon in the sample.

Assignees

• Shimadzu Corp

Inventors

• Yahata Masahito
• Nieda Yoshiaki

Classifications

• G01N31/005

  investigating the presence of an element by oxidation (G01N31/12 takes precedence) · CPC title

• G01N27/06

  of a liquid (involving electrolysis G01N27/26) · CPC title

• Y10T436/235

  In an aqueous solution [e.g., TOC, etc.] · CPC title

• G01N31/12

  using combustion (G01N25/20 takes precedence) · CPC title

• G01N33/004

  CO or CO2 · CPC title