Nanodiamond counting
US-9897603-B1 · Feb 20, 2018 · US
US12480876B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12480876-B2 |
| Application number | US-202118245492-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 30, 2021 |
| Priority date | Sep 15, 2020 |
| Publication date | Nov 25, 2025 |
| Grant date | Nov 25, 2025 |
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A sensor apparatus for determining and/or monitoring a process variable of a medium in a containment includes: a crystal body including at least one defect; a magnetic field system for producing a magnetic field in the region of the crystal body and in the region of the medium within the containment, wherein the crystal body and the magnetic field system are arrangeable from the outside at a wall of the containment; a detection unit for detecting a magnetic field-dependent, fluorescent signal from the crystal body, wherein the detection unit has an excitation unit for optical exciting of the defect and a detector for detecting the fluorescent signal; and an evaluation unit for ascertaining at least one piece of information concerning the process variable based on the fluorescent signal.
Opening claim text (preview).
The invention claimed is: 1 . A sensor apparatus for determining and/or monitoring a process variable of a medium capable of filling a containment to a plurality of different fill levels, the sensor apparatus comprising: a crystal body including at least one defect; a magnetic field system configured to generate a magnetic field in a region of the crystal body, and in a region of the medium capable of filling the containment to the plurality of different fill levels, within the containment, wherein the crystal body and the magnetic field system are respectively configured as to be arranged at a wall of the containment from the outside; a detection unit configured to detect a magnetic field-dependent fluorescence signal emitted from the crystal body in a manner dependent upon the magnetic field, wherein the detection unit comprises an excitation unit configured to optical excite the at least one defect of the crystal and comprises a detector configured to detect the fluorescence signal; and an evaluation unit configured to determine at least one piece of information about the process variable of the medium capable of filling the containment to the plurality of different fill levels, based on the fluorescence signal; and wherein the process variable includes a fill level of the medium, and the magnetic field in the region of the medium is dependent on a change to the fill level. 2 . The sensor apparatus of claim 1 , wherein the crystal body is: diamond, wherein the at least one defect is at least one nitrogen defect; silicon carbide, wherein the at least one defect is at least one silicon defect; or hexagonal boron, wherein the at least one defect is at least one color center defect. 3 . The sensor apparatus of claim 1 , wherein the magnetic field system comprises at least one coil. 4 . The sensor apparatus of claim 3 , wherein the at least one coil surrounds the crystal body, at least partially, when the crystal body and the magnetic field system are arranged at the wall of the containment. 5 . The sensor apparatus of claim 1 , further comprising an optical fiber configured to guide the fluorescence signal from the crystal body to the detection unit. 6 . The sensor apparatus of claim 1 , further comprising a frame configured to enable introduction of at least one component of the sensor apparatus into the wall of the containment. 7 . A method for determining and/or monitoring a process variable of a medium in a containment using the sensor apparatus according to claim 1 , the method comprising: generating a magnetic field in the region of the crystal body and in the region of the medium within the containment using the magnetic field system; exciting the at least defect in the crystal body to fluoresce via the magnetic field; detecting the magnetic field-dependent fluorescence signal from the crystal body; and determining the at least one piece of information about the process variable based on the fluorescence signal. 8 . The method of claim 7 , wherein based on the fluorescence signal at least one variable characteristic for the magnetic field is determined. 9 . The method of claim 8 , wherein the at least one variable characteristic for the magnetic field is the magnetic susceptibility or the magnetic permeability. 10 . The method of claim 8 , wherein at least one physical and/or chemical, characteristic variable of the medium is determined based on the at least one variable characteristic for the magnetic field. 11 . The method of claim 8 , wherein based on the at least one variable characteristic for the magnetic field a state monitoring of a process running in the containment is performed. 12 . The method of claim 8 , wherein a predeterminable limit level of the medium in the containment is monitored. 13 . The method of claim 12 , wherein a limit value for the at least one variable characteristic for the magnetic field is predetermined, and wherein upon exceeding or falling below the limit value a crossing of the predeterminable limit level is signaled. 14 . The method of claim 8 , wherein the magnetic field generated in the region of the crystal body and in the region of the medium within the containment is generated as an alternating field, wherein the frequency of the alternating field is varied. 15 . A sensor apparatus for determining a process variable of a medium in a containment, the sensor apparatus comprising: a crystal body including at least one defect; a magnetic field system configured to generate a magnetic field in a region of the crystal body and in a region of the medium within the containment, wherein the crystal body and the magnetic field system are respectively configured as to be arranged at a wall of the containment from the outside; a detection unit configured to detect a magnetic field-dependent fluorescence signal emitted from the crystal body, wherein the detection unit comprises an excitation unit configured to optical excite the at least one defect of the crystal and comprises a detector configured to detect the fluorescence signal; and an evaluation unit configured to: determine based on the fluorescence signal a variable characteristic for the magnetic field; and determine a process variable characteristic including at least one of a presence, an absence, a fill level, a change to a fill level, or a chemical property, of the medium in the containment, based on the variable characteristic for the magnetic field. 16 . The sensor apparatus of claim 15 wherein the variable characteristic of the magnetic field includes a magnetic susceptibility or a magnetic permeability. 17 . The sensor apparatus of claim 15 wherein the evaluation unit is further configured to monitor a predeterminable limit level of the medium in the containment as the process variable by signaling when the variable characteristic for the magnetic field exceeds or falls below a predetermined limit value for the variable characteristic for the magnetic field. 18 . The sensor apparatus of claim 15 wherein the process variable characteristic includes the chemical property of the medium. 19 . The senor apparatus of claim 15 wherein the process variable characteristic includes the fill level of the medium.
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