Chiral induced spin selectivity enabling a room temperature spin polarized light emitting diode

Patent metadata

Field	Value
Publication number	US-12480045-B2
Application number	US-202217650582-A
Country	US
Kind code	B2
Filing date	Feb 10, 2022
Priority date	Feb 10, 2021
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

Described herein are spin polarized light emitting diodes (LEDs) and methods of making the same. Spin polarization is achieved via chiral induced spin selectivity where, for example, a stereochemically active cation is included in a perovskite to form the conductive layer of an LED device. Advantageously, the devices and methods described herein allow for spin polarization at room temperature and without application of a magnetic field or ferromagnetic contacts, in contrast to other described spin selective LEDs.

First claim

What is claimed is:

1 . A light emitting diode comprising:
a perovskite conductive layer comprising stereochemically-selected cations, wherein said stereochemically-selected cations enable a spin-polarized light emitting diode capable of generating a circularly-polarized electroluminescence; a perovskite nanocrystal emitting layer in electronic communication with said perovskite conductive layer; wherein said perovskite nanocrystal emitting layer comprises CsPbI nanocrystals, CsPbBr nanocrystals or a combination thereof.

2 . The light emitting diode of claim 1 further comprising an anode layer in electronic communication with said perovskite conductive layer.

3 . The light emitting diode of claim 1 further comprising a cathode layer in electronic communication with said perovskite nanocrystal emitting layer.

4 . The light emitting diode of claim 1 , wherein said perovskite conductive layer comprises a metal-halide perovskite.

5 . The light emitting diode of claim 1 , wherein said perovskite conductive layer comprises lead iodide.

6 . The light emitting diode of claim 1 , wherein said stereochemically-selected cations comprise R or S organic molecules.

7 . The light emitting diode of claim 1 , wherein said stereochemically-selected cations comprise R or S methylbenzylammonium.

8 . The light emitting diode of claim 1 , wherein at least 75% of said stereochemically-selected cations are the same enantiomer.

9 . The light emitting diode of claim 1 , wherein said perovskite conductive layer is solution processed.

10 . The light emitting diode of claim 1 , wherein said perovskite nanocrystal emitting layer comprises nanocrystals with an average diameter less than or equal to 25 nm.

11 . The light emitting diode of claim 1 , wherein said perovskite nanocrystal emitting layer is deposited on a surface of said perovskite conductive layer via spin coating.

12 . The light emitting diode of claim 2 , wherein said perovskite conductive layer is deposited on a surface of said anode layer via spin coating.

13 . The light emitting diode of claim 12 , wherein said perovskite conductive layer is deposited on a surface of said anode layer to form a horizontally oriented organic/inorganic multiple quantum well configuration.

14 . The light emitting diode of claim 1 , wherein said spin-polarized light emitting diode generates circularly-polarized electroluminescence at 25° C.

15 . The light emitting diode of claim 1 , wherein said spin-polarized light emitting diode generates circularly-polarized electroluminescence without application of a magnetic field or ferromagnetic contacts.

16 . The light emitting diode of claim 1 , wherein said spin polarized light emitting diode achieves a circularly-polarized electroluminescence having polarization greater than or equal to ±1.0%.

17 . A light emitting diode comprising:
a metal-halide perovskite conductive layer comprising stereochemically-selected cations; a perovskite nanocrystal emitting layer in electronic communication with said metal-halide perovskite layer; an anode layer in electronic communication with said metal-halide perovskite layer; and a cathode layer in electronic communication with said perovskite nanocrystal emitting layer; wherein said perovskite nanocrystal emitting layer comprises CsPbI nanocrystals, CsPbBr nanocrystals or a combination thereof.

18 . The light emitting diode of claim 17 , wherein said stereochemically-selected cations enable a spin-polarized light emitting diode capable of generating a circularly-polarized electroluminescence.

Assignees

• Alliance Sustainable Energy

Inventors

• Beard Matthew Craig
• Lu Haipeng
• Zhai Yaxin
• Kim Young-Hoon
• Berry Joseph Jonathan
• Luther Joseph Matthew

Classifications

• H10K85/50

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title

• H10K50/868

  Arrangements for polarized light emission (H10K50/86 takes precedence) · CPC title

• H10K2102/00

  Constructional details relating to the organic devices covered by this subclass · CPC title

• H10K71/00

  Manufacture or treatment specially adapted for the organic devices covered by this subclass · CPC title

• H10K50/115

  comprising active inorganic nanostructures, e.g. luminescent quantum dots · CPC title