Weather stable pearlescent pigments

Patent metadata

Field	Value
Publication number	US-12479999-B2
Application number	US-202319101363-A
Country	US
Kind code	B2
Filing date	Dec 7, 2023
Priority date	Dec 22, 2022
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

Weather stable pearlescent pigment having a basic pearlescent with an interference color which comprises a transparent platelet-shaped substrate and at least one metal oxide layer with a refractive index >1.8 and on top of this basic pearlescent pigment a weather stabilizing top coating comprising at least one metal oxide and an organofunctional surface modification, wherein a) for a basic pearlescent pigment with silvery interference color the weather stabilizing top coating consists of a first metal oxide of a rare earth metal M1 from the group consisting of Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and mixtures thereof, or b) for a basic pearlescent pigment with a colored interference color or a silvery interference color the weather stabilizing top coating comprises a first metal oxide of a rare earth metal M1 from the group consisting of Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and mixtures thereof, and a second metal oxide from a second metal M2 from the group consisting of Si, Al, Zn, Mg, Zr, Sn and mixtures or combinations thereof, and in each case a) or b) the organofunctional surface modification comprises organofunctional silanes or water-based pre-condensated organofunctional silanes.

First claim

The invention claimed is:

1 . Weather stable pearlescent pigment having a basic pearlescent pigment with an interference color which comprises a transparent platelet-shaped substrate and at least one metal oxide layer with a refractive index >1.8 and on top of this basic pearlescent pigment, a weather stabilizing top coating comprising at least one metal oxide and an organofunctional surface modification, wherein
a) for a basic pearlescent pigment with silvery interference color, the weather stabilizing top coating comprises a first metal oxide of a rare earth metal M 1 from the group consisting of Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and mixtures thereof, or b) for a basic pearlescent pigment with a colored interference color or a silvery interference color, the weather stabilizing top coating comprises a first metal oxide of a rare earth metal M 1 and a second metal oxide from a second metal M 2 wherein M 1 is selected from the group consisting of Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and mixtures thereof, and M 2 is selected from the group consisting of Si, Al, Zn, Mg, Zr, Sn and mixtures or combinations thereof, and in each case a) or b) the organofunctional surface modification comprises organofunctional silanes or water-based pre-condensated organofunctional silanes.

2 . Weather stable pearlescent pigment according to claim 1 , wherein the weather stabilizing top coating comprises a metal oxide of a rare earth metal from the group consisting of Pr, Nd, Sm, Eu, Gd, Ho, Yb, and mixtures thereof.

3 . Weather stable pearlescent pigment according to claims 1 , wherein the weather stabilizing top coating comprises a metal oxide of a rare earth metal from the group consisting of Nd, Sm, Yb, Eu, Gd and mixtures thereof.

4 . Weather stable pearlescent pigment according to claim 1 , wherein the second metal oxide of metal M 2 is selected from the group consisting of SiO 2 , Al 2 O 3 , ZnO, MgO, ZrO 2 , SnO 2 and mixtures or combinations thereof.

5 . Weather stable pearlescent pigment according to claim 1 , wherein 50 to 100 atomic-% of the rare earth metal M 1 metal oxide are based on a M 1 (III) oxidation state, based on the total amount of M 1 ions.

6 . Weather stable pearlescent pigment according to claim 1 , wherein the amount of the first metal oxide of a rare earth metal M 1 is in a range of 0.3 to 3.0 wt. %, based on the total weight of the pearlescent pigment.

7 . Weather stable pearlescent pigment according to claim 1 , wherein the weather stabilizing top coating further comprises a cerium metal oxide in an amount of 0.0 to 30 wt %, calculated as Ce 2 O 3 and referred to the total amount of rare earth weather stable top coating and calculated as M 1 2 O 3 .

8 . Weather stable pearlescent pigment according to claim 1 , wherein the amount of the second metal oxide of a metal M 2 is in a range of 1.0 to 4.0 wt. %, based on the total pearlescent pigment.

9 . Weather stable pearlescent pigment according to claim 1 , wherein the weather stabilizing top coating b) has a structure characterized that a first coating located on the high-index metal oxide coating is the first rare earth metal oxide coating which is followed by the second metal oxide coating.

10 . Weather stable pearlescent pigment according to claim 1 , wherein the weather stabilizing top coating b) has a structure characterized that the first rare earth metal oxide and the second metal oxide have been manufactured by co-precipitation of both metal oxide precursors.

11 . Weather stable pearlescent pigment according to claim 1 , wherein the transparent platelet-shaped substrate is selected from the group consisting of natural mica, synthetic mica platelets, glass platelets, SiO 2 platelets, Al 2 O 3 platelets, synthetic boehmite platelets, BiOCI platelets and mixtures thereof.

12 . A formulation comprising the weather stable pearlescent pigments of claim 1 .

13 . The formulation of claim 12 wherein the formulation is an automotive base coat formulation.

Assignees

• Eckart Gmbh

Inventors

• Grüner Michael
• Kaupp Günter
• Schneider Thomas

Classifications

• C09C2220/10

  Wet methods, e.g. co-precipitation · CPC title

• C09C2200/407

  Organosilicon materials, e.g. silanes, silicones · CPC title

• C09C2200/401

  Inorganic protective coating · CPC title

• C09C2200/102

  the core consisting of glass or silicate material like mica or clays, e.g. kaolin · CPC title

• C09C1/0027 Primary

  One layer consisting of at least one sub-stoichiometric inorganic compound · CPC title