Process for manufacturing alkanesulfonic acids

Patent metadata

Field	Value
Publication number	US-12479795-B2
Application number	US-202017766084-A
Country	US
Kind code	B2
Filing date	Sep 23, 2020
Priority date	Oct 2, 2019
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

The present invention relates to an improved process for the production of alkanesulfonic acids.

First claim

The invention claimed is:

1 . A process for the production of alkanesulfonic acid from an alkane and SO 3 with an initiator comprising a distillation step, the distillation step comprising providing a feed comprising unpurified alkanesulfonic acid to at least one distillation column,
wherein total energy consumption of the process is reduced by heat integration, and wherein the feed is heated by heat integration with a stream of purified alkanesulfonic acid leaving the distillation step, and/or the feed is heated by heat integration with a distillation residue leaving the distillation step, and/or the feed is first heated by heat integration with the stream of purified alkanesulfonic acid leaving the distillation step and then by heat integration with the distillation residue leaving the distillation step, and/or the feed is heated by heat integration with a stream from mixing the purified alkanesulfonic acid leaving the distillation step with water to yield an aqueous solution.

2 . The process according to claim 1 , comprising:
a) synthesizing the initiator and reacting the alkane with the SO 3 in the presence of the initiator to form the unpurified alkanesulfonic acid, b) quenching a) to convert the SO 3 into a heavy boiler,
c) removing unreacted alkane from b) by decompression to provide the feed,
d) performing the distillation step on the feed, and
e) discarding waste streams.

3 . The process according to claim 1 , wherein the alkane is methane and the alkanesulfonic acid is methanesulfonic acid.

4 . The process according to claim 1 , wherein the feed is further heated at a feeding point after the heat integration.

5 . The process according to claim 1 , wherein heat exchangers are used for heat integration.

6 . The process according to claim 5 , wherein the heat exchangers are monoliths made of pressureless sintered silicon carbide (SSIC).

7 . The process according to claim 1 , wherein heat in the heat integration is transferred from the stream of purified alkanesulfonic acid leaving the distillation step and/or the distillation residue leaving the distillation step to the feed directly without a heat transfer fluid in one apparatus per stream.

8 . The process according to claim 1 , wherein heat in the heat integration is transferred from the stream of purified alkanesulfonic acid leaving the distillation step and/or the distillation residue leaving the distillation step to the feed using a heat transfer fluid.

9 . The process according to claim 1 , wherein aliphatic and/or cyclic hydrocarbons and/or as silicon oils are used as heat transfer fluids for heat integration.

10 . The process according to claim 2 , wherein the quenching step is operated adiabatically.

11 . The process according to claim 2 , further comprising incinerating remaining alkane from the synthesis of the unpurified alkanesulfonic acid to supply heat to the process.

12 . The process according to claim 11 , wherein the heat supplied by incinerating the remaining alkane generates steam or heats up heat transfer fluids.

13 . The process according to claim 11 , wherein the remaining alkane is methane and the heat supplied by incinerating the methane heats up the feed or powers one or more evaporators of the distillation step.

14 . The process according to claim 13 , wherein the evaporators of the distillation step are powered by steam, and steam condensate coming from the evaporators of the distillation step is used to heat the feed.

15 . The process according to claim 1 , wherein energy released in one or more condensers of the distillation step is used to heat up the feed.

16 . The process according to claim 5 , wherein the heat exchangers are made of silicon carbide.

Assignees

• Basf Se

Inventors

• Piepenbreier Frank
• Kempter Andreas
• Kaibel Bjoern
• Borgmeier Frieder

Classifications

• C07C303/06 Primary

  by reaction with sulfuric acid or sulfur trioxide · CPC title

• B01D5/006

  with evaporation or distillation · CPC title

• B01D5/0039

  Recuperation of heat, e.g. use of heat pump(s), compression · CPC title

• B01D3/007

  Energy recuperation; Heat pumps · CPC title

• B01D1/0041

  Use of fluids · CPC title