Oligomerisation process comprising a step of recycling a pre-cooled solvent

Patent metadata

Field	Value
Publication number	US-12479780-B2
Application number	US-202218284606-A
Country	US
Kind code	B2
Filing date	Mar 25, 2022
Priority date	Mar 30, 2021
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

The present invention relates to a process for the oligomerization of an olefinic feedstock characterized in that a solvent fraction resulting from a downstream separation step is cooled and recycled.

First claim

The invention claimed is:

1 . A process for the oligomerization of an olefinic feedstock, said process comprising:
a) oligomerizing said olefinic feedstock in a reaction section at a temperature between 30° C. and 200° C., a pressure between 0.1 and 10 MPa, and in the presence of a homogeneous catalytic oligomerization system and a solvent, the reaction section comprising an oligomerization reactor and one or more recirculation loops enabling control of the temperature in said reactor via cooling of a liquid phase fraction, wherein said one or more recirculation loops is formed by withdrawing a liquid phase fraction from the oligomerization reactor, cooling at least a portion of the withdrawn liquid phase fraction, and introducing the cooled liquid phase fraction into the oligomerization reactor, b) separating, in a downstream separation section, a reaction effluent resulting from the oligomerization so as to obtain a solvent fraction, c) cooling the solvent fraction to a temperature below the temperature of the one or more recirculation loop(s), and d) introducing into the reaction section the cooled solvent fraction.

2 . The process as claimed in claim 1 , wherein the solvent fraction is cooled in c) to a temperature between 0° C. and 150° C.

3 . The process as claimed in claim 1 , wherein the solvent fraction is cooled in c) to a temperature at least 40° C. lower relative to the temperature of the cooled liquid phase fraction in the one or more recirculation loops.

4 . The process as claimed in claim 1 , wherein the cooling of the solvent fraction in c) is carried out by one or more thermal exchangers.

5 . The process as claimed in claim 4 , wherein the introducing of the cooled solvent fraction is carried out by introducing the cooled solvent fraction into a recirculation loop of said one or more recirculation loops, wherein the cooled solvent fraction is introduced upstream or downstream of a thermal exchanger of the recirculation loop.

6 . The process as claimed in claim 4 , wherein the introducing of the cooled solvent fraction is carried out by introducing the cooled solvent fraction into a recirculation loop of said one or more recirculation loops, wherein the cooled solvent fraction is introduced downstream of a thermal exchanger of the recirculation loop.

7 . The process as claimed in claim 1 , wherein the downstream separation section comprises at least two distillation columns.

8 . The process as claimed in claim 1 , wherein the introducing of the cooled solvent fraction into the reactor section is carried out by introducing the cooled solvent fraction into the reactor.

9 . The process as claimed in claim 1 , wherein the cooled solvent fraction has a flow rate, as a weight percentage relative to the flow rate of the liquid circulating in the one or more recirculation loop(s), of between 0.05% and 15.0%.

10 . The process according to claim 1 , wherein the olefinic feedstock comprises olefins having between 2 and 6 carbon atoms.

11 . The process as claimed in claim 10 , wherein the olefinic feedstock is chosen from butene, propylene and ethylene, alone or as a mixture.

12 . The process as claimed in claim 1 , wherein the cooling of at least a portion of the withdrawn liquid phase fraction is carried out by circulating said at least a portion of the liquid phase fraction through one or more thermal exchangers located in the one or more recirculation loops.

13 . The process as claimed in claim 12 , wherein the thermal exchanger(s) used in the one or more recirculation loops reduce(s) the temperature of said at least a portion of the liquid phase fraction by 1.0° C. to 30.0° C.

14 . The process as claimed in claim 12 , wherein the thermal exchanger(s) used in in the one or more recirculation loops reduce(s) the temperature of said at least a portion of the liquid phase fraction by 2.0° C. to 25.0° C.

15 . The process as claimed in claim 1 , wherein the reaction effluent is obtained by dividing the withdrawn liquid phase fraction from the oligomerization reactor into two streams.

16 . The process as claimed in claim 1 , wherein the oligomerization reactor is a a two-phase gas/liquid reactor or a single-phase liquid reactor.

17 . The process as claimed in claim 1 , wherein the cooling of the solvent fraction is carried out by one or more heat exchangers selected from process fluid/process fluid heat exchangers, air cooler heat exchangers, and cooling water heat exchangers.

18 . The process as claimed in claim 1 , wherein the downstream separation section comprises at least three distillation columns.

19 . The process as claimed in claim 1 , wherein the cooled solvent fraction has a flow rate, as a weight percentage relative to the flow rate of the liquid circulating in the one or more recirculation loop(s), of between 0.1% and 10.0%.

20 . The process according to claim 1 , wherein the olefinic feedstock comprises olefins having between 2 and 4 carbon atoms.

21 . The process as claimed in claim 1 , wherein the introducing of the cooled solvent fraction into the reactor section is carried out by introducing the cooled solvent fraction into the one or more of the recirculation loops.

22 . The process as claimed in claim 1 , wherein the oligomerization reactor is a two-phase gas/liquid reactor.

23 . The process as claimed in claim 1 , wherein the flow rate of the reaction effluent is from 5 to 200 times lower than the liquid flow rate sent to the cooling said at least a portion of the withdrawn liquid phase fraction.

Assignees

• Ifp Energies Now

Inventors

• Breuil Pierre-Alain
• Cotte Olivier

Classifications

• C07C11/08

  with four carbon atoms · CPC title

• C07C7/04

  by distillation · CPC title

• C07C11/107

  with six carbon atoms · CPC title

• C07C11/02

  Alkenes · CPC title

• C07C2/08 Primary

  Catalytic processes · CPC title