Separation of elements using polyoxometalates and cations

Patent metadata

Field	Value
Publication number	US-12479735-B2
Application number	US-202217722248-A
Country	US
Kind code	B2
Filing date	Apr 15, 2022
Priority date	Apr 15, 2022
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

A method includes forming a solution comprising a solvent and at least two elements selected from: scandium (Sc), yttrium (Y), one or more lanthanides, and one or more actinides. The method includes adding an effective amount of at least one polyoxometalate for forming complexes with at least one of the elements and adding an effective amount of a cation for causing precipitation of at least some of the complexes of one of the elements. Substantially all of another of the elements remains in solution during the precipitation of the at least some of the complexes of the one of the elements. A kit includes a polyoxometalate, a cation, and instructions for adding effective amounts of the polyoxometalate and the cation for separating at least two elements selected from the group consisting of: scandium (Sc), yttrium (Y), one or more lanthanides, and one or more actinides via a precipitation reaction.

First claim

What is claimed is:

1 . A method, comprising:
forming a first solution comprising a solvent and at least two elements selected from the group consisting of: scandium (Sc), yttrium (Y), one or more lanthanides, and one or more actinides; forming a second solution by adding an effective amount of at least one polyoxometalate to the first solution for forming complexes with at least one of the elements; and adding an effective amount of a cation to the second solution for causing precipitation of at least some of the complexes of one of the elements, wherein substantially all of another of the elements remains in the second solution during the precipitation of the at least some of the complexes of the one of the elements.

2 . The method of claim 1 , wherein at least one of the elements in the first solution is an f-block element selected from the group consisting of: lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), actinium (Ac), thorium (Th), protactinium (Pa), uranium (U), neptunium (Np), plutonium (Pu), americium (Am), curium (Cm), berkelium (Bk), californium (Cf), einsteinium(Es), fermium (Fm), mendelevium (Md), nobelium (No), and lawrencium (Lr).

3 . The method of claim 1 , wherein the at least two elements include an actinide and a lanthanide.

4 . The method of claim 1 , wherein the at least two elements include two or more actinides.

5 . The method of claim 1 , wherein the at least two elements include two or more rare earth elements selected from the group consisting of: scandium (Sc), yttrium (Y), and one or more lanthanides.

6 . The method of claim 1 , wherein the at least two elements include a lanthanide and an element selected from the group consisting of: scandium and yttrium.

7 . The method of claim 1 , wherein the at least two elements include an actinide and an element selected from the group consisting of: scandium and yttrium.

8 . The method of claim 1 , wherein the first solution is aqueous.

9 . The method of claim 1 , wherein the solvent is water.

10 . The method of claim 1 , wherein the first solution is essentially inorganic.

11 . The method of claim 1 , wherein the at least one polyoxometalate has a charge of at least −5.

12 . The method of claim 1 , wherein the at least one polyoxometalate is selected from the group consisting of: a polyoxotungstate, a polyoxomolybate, a polyoxovanadate, a polyoxoniobate, and a polyoxotantalate.

13 . The method of claim 1 , wherein the cation is selected from the group consisting of: lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), francium (Fr), beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), radium (Ra), ammonium, and ethlyammonium.

14 . The method of claim 1 , wherein the cation is added in the form of a salt.

15 . The method of claim 1 , wherein the cation is cesium (Cs).

16 . The method of claim 1 , wherein at least two different cations are added to the second solution.

17 . The method of claim 1 , wherein the amount of the at least one polyoxometalate added to the first solution is at least two times the concentration of one of the at least two elements in the first solution.

18 . The method of claim 1 , wherein the amount of the cation added to the second solution is at least 20 times the concentration of one of the at least two elements in the second solution.

19 . The method of claim 1 , comprising removing the precipitated complex from the second solution.

20 . The method of claim 1 , comprising processing the precipitated complex for removing the element from the at least one polyoxometalate.

21 . The method of claim 1 , comprising recovering at least some of the complexes of the another of the elements from the second solution.

22 . The method of claim 21 , wherein the recovering includes adding additional cation for causing precipitation of the complexes of the another of the elements.

23 . The method of claim 21 , wherein the recovering includes evaporating the solvent from the second solution.

24 . The method of claim 1 , comprising performing a method using a kit, the kit comprising:
the at least one polyoxometalate; the cation; and instructions for adding the effective amounts of the at least one polyoxometalate and the cation for causing the precipitation.

Assignees

• L Livermore Nat Security Llc

Inventors

• Deblonde Gauthier

Classifications

• C22B59/00

  Obtaining rare earth metals · CPC title

• C22B34/00

  Obtaining refractory metals · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• C01B35/128 Primary

  containing plural metal or metal and ammonium · CPC title