Film and method of producing the same

Patent metadata

Field	Value
Publication number	US-12479148-B2
Application number	US-202218047721-A
Country	US
Kind code	B2
Filing date	Oct 19, 2022
Priority date	Apr 22, 2020
Publication date	Nov 25, 2025
Grant date	Nov 25, 2025

Abstract

A film includes a copolymer having a tetrafluoroethylene-based unit and an ethylene-based unit, in which the film has a haze of from 1.2% to 8.0%, an ultraviolet reflectance of less than 17.0%, and a thickness of from 250 to 400 μm.

First claim

The invention claimed is:

1 . A method of producing a film comprising a copolymer having a tetrafluoroethylene-based unit and an ethylene-based unit, comprising:
melting a copolymer comprising a copolymer having a tetrafluoroethylene-based unit and an ethylene-based unit such that a melt comprising the copolymer is obtained; continuously extruding the melt through a die to form the melt into a sheet shape; and passing the melt extruded in the sheet shape between a pair of a rigid roll and an elastic roll or bringing the melt extruded in the sheet shape into contact with a rigid roll or an elastic roll, and a subsequent stage roll placed at a subsequent stage, for cooling such that a film comprising the copolymer is obtained, wherein the film has a haze in a range of 1.2% to 8.0%, an ultraviolet reflectance of less than 17.0%, and a thickness in a range of 250 to 400 μm, a surface temperature of each of the rigid roll, the elastic roll and the subsequent stage roll is controlled with a heating medium, a temperature of the melt immediately before passing between the rigid roll and the elastic roll or immediately before being in contact with the rigid roll or the elastic roll is in a range of from 200° C. to 330° C., a melting point M of the copolymer is 200° C. or more, and an average of a heating medium temperature of the rigid roll and a heating medium temperature of the elastic roll or an average of a heating medium temperature of the rigid roll or the elastic roll and a heating medium temperature of the subsequent stage roll is designated as T (° C.), T×M is 31,000 or less.

2 . The method of claim 1 , wherein the film has a thickness in a range of 250 to 300 μm.

3 . The method of claim 1 , wherein the film has a rate of dimensional change in each of a machine direction, MD, and a transverse direction, TD, of respectively in a range of −3.5% to −1.0% when heating is carried out at 150° C. for 10 minutes and then cooling is carried out to 23° C., based on dimensions of the film at 23° C., and the film has a stress at 10% extension in each of MD and TD at 80° C. of respectively 3.0 MPa or more.

4 . The method of claim 1 , wherein a content of the copolymer is 90% by mass or more with respect to a total mass of the film.

5 . The method of claim 1 , wherein the copolymer has another unit based on a different monomer other than tetrafluoroethylene and ethylene, and a total content of the other unit is in a range of 1 to 7 mol % with respect to a total of the tetrafluoroethylene-based unit and the ethylene-based unit.

6 . The method of claim 1 , wherein the film is a membrane structure film.

7 . The method of claim 1 , wherein the average of the heating medium temperature of the rigid roll or the elastic roll and the heating medium temperature of the subsequent stage roll is designated as T (° C.), T×M is 31,000 or less.

8 . The method of claim 1 , wherein the film is a single-layer film.

Assignees

• Agc Inc

Inventors

• Aruga Hiroshi
• Higuchi Yoshiaki
• Horiguchi Yuya
• Nakamura Junetsu

Classifications

• B29C48/9135

  of flat articles, e.g. using specially adapted supporting means · CPC title

• B29K2023/08

  Copolymers of ethylene (B29K2023/16 takes precedence) · CPC title

• B29K2027/18

  PTFE, i.e. polytetrafluoroethylene {, e.g. ePTFE, i.e. expanded polytetrafluoroethylene} · CPC title

• B29C48/911

  Cooling · CPC title

• C08J2327/18

  Homopolymers or copolymers of tetrafluoroethylene · CPC title