Sensor system and method for gamma radiation dose measurement

Patent metadata

Field	Value
Publication number	US-12474489-B2
Application number	US-202418612922-A
Country	US
Kind code	B2
Filing date	Mar 21, 2024
Priority date	Jan 6, 2021
Publication date	Nov 18, 2025
Grant date	Nov 18, 2025

Abstract

A printed radiation sensor that includes a substrate, an interdigitated electrode, and a conductive polymeric film. The interdigitated electrode including a first electrode with a plurality of first electrode digits and a second electrode with a plurality of second electrode digits. The interdigitated electrode disposed on the substrate. The conductive polymeric film including a blend of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) and polyvinyl alcohol (PVA). The PEDOT:PSS is configured to provide an electrically conductive medium. The PVA is configured to provide ductility and stability of the printed radiation sensor. Upon radiation exposure, the PVA is further configured to crosslink within a material matrix of the printed radiation sensor militating against the recombination of chain scission by forming a semi-interpenetrating polymer network (SIPN) with the PEDOT:PSS to provide an enhanced and stable impedance reading.

First claim

What is claimed is:

1 . A sensor, wherein the sensor comprises:
a substrate; an electrode disposed on the substrate; and a conductive polymeric film disposed on the electrode, wherein the conductive polymeric film includes a blend of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) and polyvinyl alcohol (PVA), wherein the sensor is a gamma radiation sensor.

2 . The sensor of claim 1 , wherein the electrode is an interdigitated electrode.

3 . The sensor of claim 1 , wherein the substrate is a flexible substrate.

4 . The sensor of claim 2 , wherein the interdigitated electrode includes first electrode with a plurality of first electrode digits and a second electrode with a plurality of second electrode digits.

5 . The sensor of claim 1 , wherein the blend includes about 5-50 wt % of polyvinyl alcohol (PVA), and about 50-95 wt % of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS).

6 . The sensor of claim 1 , wherein the blend includes about 7.5-12.5 wt % of polyvinyl alcohol (PVA), and about 87.5-92.5 wt % of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS).

7 . The sensor of claim 1 , wherein the blend includes about 10 wt % of polyvinyl alcohol (PVA), and about 90 wt % of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS).

8 . The sensor of claim 1 , wherein the sensor is plasma treated.

9 . The sensor of claim 1 , wherein the conductive polymeric film has a contact angle that is less than sixty degrees.

10 . The sensor of claim 1 , wherein the sensor is substantially insoluble after radiation exposure.

11 . The sensor of claim 4 , wherein the conductive polymeric film is disposed on and between the plurality of digits of the first electrode and the plurality of digits of the second electrode.

12 . The sensor of claim 1 , wherein the sensor is configured to form a semi-interpenetrating polymer network.

13 . The sensor of claim 1 , wherein the sensor has an average impedance change within fifteen percent over an eighteen-day period after radiation exposure.

14 . A method of measuring gamma radiation dose comprising:
providing a sample to be treated with radiation; providing a sensor including:
a substrate;
an electrode disposed on the substrate; and
a conductive polymeric film disposed on the electrode, wherein the conductive polymeric film includes a blend of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) and polyvinyl alcohol (PVA);
disposing the sensor within a predetermined proximity to the sample; applying radiation to the sample; and monitoring a dose range of the radiation applied to the sample with the sensor, wherein the radiation is gamma radiation.

15 . The method of claim 14 , wherein the sensor is configured to provide a substantially linear relative change in resistance with a gamma radiation dose range of greater than zero kilogray to about fifty-three kilogray.

16 . The method of claim 14 , further comprising a step of plasma-treating the sensor.

Assignees

• Purdue Research Foundation

Inventors

• Rahimi Rahim
• Rivera Ulisses Heredia

Classifications

• H10K77/111

  Flexible substrates · CPC title

• H10K39/32

  Organic image sensors · CPC title

• H10K85/1135

  Polyethylene dioxythiophene [PEDOT]; Derivatives thereof · CPC title

• H10K71/60

  Forming conductive regions or layers, e.g. electrodes · CPC title

• G01T1/026 Primary

  Semiconductor dose-rate meters · CPC title