Three-dimensional printing

Patent metadata

Field	Value
Publication number	US-12472687-B2
Application number	US-202018009913-A
Country	US
Kind code	B2
Filing date	Jul 20, 2020
Priority date	Jul 20, 2020
Publication date	Nov 18, 2025
Grant date	Nov 18, 2025

Abstract

An example of a three-dimensional (3D) build material composition includes from about 70 wt % to about 95 wt % of polyamide particles, based upon a total weight of the build material composition; and from about 5 wt % to about 30 wt % of biodegradable polyester filler particles, based upon the total weight of the build material composition. The biodegradable polyester filler particles are present in the build material composition without any additional filler particles.

First claim

What is claimed is:

1 . A three-dimensional (3D) build material composition, consisting of:
from about 70 wt % to about 95 wt % of polyamide particles, based upon a total weight of the build material composition; and from about 5 wt % to about 30 wt % of biodegradable polyester filler particles, based upon the total weight of the build material composition, wherein the 3D build material composition is dry.

2 . The 3D build material composition as defined in claim 1 wherein the biodegradable polyester filler particles are selected from the group consisting of polylactic acid, polyglycolide, poly(DL-lactide-co-glycolide), polyethylene succinate, polybutylene succinate, polybutylene adipate, polybutylene succinate/adipate copolymer, polycaprolactone, and combinations thereof.

3 . The 3D build material composition as defined in claim 1 wherein the polyamide particles are selected from the group consisting of polyamide-11, polyamide-12, polyamide-6, polyamide-8, polyamide-9, polyamide-66, polyamide-612, polyamide-812, polyamide-912, a thermoplastic polyamide, and combinations thereof.

4 . A three-dimensional (3D) printing kit, comprising:
a build material composition consisting of from about 70 wt % to about 95 wt % of polyamide particles and from about 5 wt % to about 30 wt % of biodegradable polyester filler particles, each based on a total weight of the build material composition, wherein the build material composition is dry; and a fusing agent including an energy absorber dissolved or dispersed in a liquid vehicle, wherein the energy absorber is selected from the group consisting of a near-infrared light absorbing colorant, an inorganic pigment, glass fibers, titanium dioxide, clay, mica, talc, barium sulfate, calcium carbonate, nitrocellulose, and combinations thereof.

5 . The 3D printing kit as defined in claim 4 wherein:
the polyamide particles are selected from the group consisting of polyamide-11, polyamide-12, polyamide-6, polyamide-8, polyamide-9, polyamide-66, polyamide-612, polyamide-812, polyamide-912, a thermoplastic polyamide, and combinations thereof; and
the biodegradable polyester filler particles are selected from the group consisting of polylactic acid, polyglycolide, poly(DL-lactide-co-glycolide), polyethylene succinate, polybutylene succinate, polybutylene adipate, polybutylene succinate/adipate copolymer, polycaprolactone, and combinations thereof.

6 . A three-dimensional printing method, comprising:
spreading the build material composition of claim 1 to form a build material layer; based on a 3D object model, selectively applying a fusing agent on at least a portion of the build material layer, wherein the fusing agent includes an energy absorber selected from the group consisting of a near-infrared light absorbing colorant, an inorganic pigment, glass fibers, titanium dioxide, clay, mica, talc, barium sulfate, calcium carbonate, nitrocellulose, and combinations thereof; and exposing the build material layer to electromagnetic radiation to coalesce the build material composition in the at least the portion, thereby forming a layer of a 3D object.

7 . The method as defined in claim 6 , further comprising:
iteratively applying individual build material layers of the build material composition; based on the 3D object model, selectively applying the fusing agent to at least some of the individual build material layers to define individually patterned layers; and iteratively exposing the individually patterned layers to the electromagnetic radiation to form individual object layers.

8 . The method as defined in claim 6 wherein:
the polyamide particles are selected from the group consisting of polyamide-11, polyamide-12, polyamide-6, polyamide-8, polyamide-9, polyamide-66, polyamide-612, polyamide-812, polyamide-912, a thermoplastic polyamide, and combinations thereof; and
the biodegradable polyester filler particles are selected from the group consisting of polylactic acid, polyglycolide, poly(DL-lactide-co-glycolide), polyethylene succinate, polybutylene succinate, polybutylene adipate, polybutylene succinate/adipate copolymer, polycaprolactone, and combinations thereof.

9 . The 3D build material composition as defined in claim 1 wherein the biodegradable polyester filler particles have an average particle size ranging from about 25 μm to about 245 μm.

10 . The 3D build material composition as defined in claim 1 wherein the polyamide particles are polyamide-12 particles.

11 . A three-dimensional (3D) build material composition, consisting of:
polyamide build material particles; biodegradable polyester filler particles; and an additive selected from the group consisting of a flow aid, an antioxidant, an antistatic agent, a whitener, and combinations thereof, wherein:
the flow aid is selected from the group consisting of aluminum oxide, powdered cellulose, magnesium stearate, sodium bicarbonate, sodium ferrocyanide, potassium ferrocyanide, calcium ferrocyanide, bone phosphate, sodium silicate, silicon dioxide, fused metal oxide, calcium silicate, magnesium trisilicate, talcum powder, sodium aluminosilicate, potassium aluminum silicate, calcium aluminosilicate, bentonite, aluminum silicate, stearic acid, and polydimethylsiloxane;
the antioxidant is selected from the group consisting of a hindered phenol, a phosphite, and an organic sulfite;
the antistatic agent is selected from the group consisting of an aliphatic amine, a quaternary ammonium salt, an ester of phosphoric acid, a polyethylene glycol ester, and a polyol; and
the whitener is selected from the group consisting of titanium dioxide, zinc oxide, calcium carbonate, zirconium dioxide, aluminum oxide silicon dioxide, boron nitride, and combinations thereof.

12 . A three-dimensional (3D) build material composition, consisting of:
polyamide build material particles present in an amount ranging from about 70 wt % to about 90 wt %, based on a total weight of the 3D build material composition; biodegradable polyester filler particles present in an amount ranging from about 10 wt % to about 30 wt %, based on the total weight of the 3D build material composition; and an additive selected from the group consisting of a flow aid, an antioxidant, an antistatic agent, a whitener, and combinations thereof, wherein:
the flow aid is selected from the group consisting of aluminum oxide, tricalcium phosphate, powdered cellulose, magnesium stearate, sodium bicarbonate, sodium ferrocyanide, potassium ferrocyanide, calcium ferrocyanide, bone phosphate, sodium silicate, silicon dioxide, fused metal oxide, calcium silicate, magnesium trisilicate, talcum powder, sodium aluminosilicate, potassium aluminum silicate, calcium aluminosilicate, bentonite, aluminum silicate, stearic acid, and polydimethylsiloxane;
the antioxidant is selected from the group consisting of a hindered phenol, a phosphite, and an organic sulfite;
the antistatic agent is selected from the group consisting of an aliphatic amine, a quaternary ammonium salt, an ester of phosphoric acid, a polyethlene glycol ester, and a polyol; and
the whitener is selected from the group consisting of titanium dioxide, zinc oxide, calcium carbonate, zirconium dioxide, aluminum oxide silicon dioxide, boron nitride, and combinations thereof.

13 . The 3D build material composition as defined in claim 11 wherein the polyamide build material particles are polyamide-12 particles.

14 . The 3D build material composition as defined in claim 11 wherein the biodegradable polyester filler particles are selected from the group consisting of polylactic acid, polyglycolide, poly(DL

Assignees

• Peridot Print Llc

Inventors

• Discekici Emre Hiro
• Fleischmann Carolin
• Woodruff Shannon Reuben
• Yemane Alay

Classifications

• C08K2003/2227

  of aluminium · CPC title

• B29K2067/043

  PGA, i.e. polyglycolic acid or polyglycolide · CPC title

• C08K2003/325

  Calcium, strontium or barium phosphate · CPC title

• C08K2003/262

  Alkali metal carbonates · CPC title

• C08K2003/2241

  Titanium dioxide · CPC title