Air separation processes using zeolite ITQ-55

Patent metadata

Field	Value
Publication number	US-12472458-B2
Application number	US-202217814931-A
Country	US
Kind code	B2
Filing date	Jul 26, 2022
Priority date	Dec 10, 2021
Publication date	Nov 18, 2025
Grant date	Nov 18, 2025

Abstract

This disclosure relates to the adsorption and separation of fluid components, such as oxygen, in a feed stream, such as air, using zeolite ITQ-55 as the adsorbent. A process is disclosed for adsorbing oxygen from a feed stream containing oxygen, nitrogen and argon. The process comprises passing the feed stream through a bed of an adsorbent comprising zeolite ITQ-55 to adsorb oxygen from the feed stream, carrying out an equalization step to improve recovery, thereby producing a nitrogen product stream depleted in oxygen as well as a waste stream can be collected to have enriched oxygen. The feed stream is exposed to the zeolite ITQ-55 at effective conditions for performing a rapid cycle of kinetic separation, in which oxygen exhibits greater kinetic selectivity than nitrogen and argon.

First claim

What is claimed is:

1 . A process of adsorbing oxygen from a feed stream comprising oxygen, nitrogen, and water, comprising passing the feed stream through one or more beds of adsorbent comprising a first adsorbent selective for water so as to adsorb water from the feed stream and a second adsorbent selective for oxygen so as to adsorb oxygen from the feed stream, thereby producing a rejection product stream enriched in nitrogen and depleted in oxygen and water, wherein the first adsorbent comprises a dehydration adsorbent and the second adsorbent comprise ITQ-55; wherein the zeolite ITQ-55 has a mean crystal particle size within the range of from about 0.1 microns to about 40 microns; wherein the feed stream is exposed to the first adsorbent at effective conditions to remove water from the feed stream; and wherein the feed stream is exposed to the second adsorbent at effective conditions for performing a kinetic separation, in which the kinetic separation exhibits greater kinetic selectivity for oxygen than for nitrogen.

2 . The process of claim 1 , which is a swing adsorption process comprising an adsorption step performed at elevated pressure and/or reduced temperature in which the feed stream is passed through a bed of adsorbent comprising the zeolite ITQ-55 to adsorb oxygen from the feed stream, and a desorption step performed at reduced pressure and/or elevated temperature in which oxygen from the previous adsorption step is desorbed from the bed to regenerate the bed for the next adsorption step.

3 . The process of claim 1 further comprising tuning kinetic selectivity and mass transfer rates by varying the mean crystal particle size of zeolite ITQ-55 within the range of from about 0.1 microns to about 40 microns, or by varying the adsorption temperature within the range from about −195° C. to about 30° C., or by varying the adsorption pressure within the range from about 1 bar (˜14.7 psi) to about 30 bar (˜435 psi), or combinations thereof.

4 . The process of claim 2 , which is a rapid swing adsorption process, wherein the rapid swing adsorption process is selected from rapid cycle thermal swing adsorption (RCTSA), rapid cycle pressure swing adsorption (RCPSA), and rapid cycle vacuum pressure swing adsorption (RCVPSA), or combinations of these processes.

5 . The process of claim 2 , further comprising collecting the desorbed oxygen as an oxygen-enriched stream compared to the feed stream.

6 . The process of claim 1 , further comprising collecting unadsorbed N 2 as a nitrogen-enriched stream compared to the feed stream.

7 . The process of claim 5 , wherein the oxygen-enriched stream is used in a cryogenic air separation unit (ASU), a fluid catalytic cracking (FCC) unit, a natural gas combined cycle (NGCC) unit, a steam methane reformer (SMR) unit, or any combustion or gasification not limited to natural gas, coal, or bio-mass.

8 . The process of claim 2 , wherein oxygen purity for oxygen desorbed from the bed is greater than about 25%; and/or wherein nitrogen purity for the product stream depleted in oxygen is greater than about 90%.

9 . A process of adsorbing oxygen from a feed stream containing oxygen and nitrogen, comprising passing the feed stream through a bed of an adsorbent comprising zeolite ITQ-55 to adsorb oxygen from the feed stream, thereby producing a product stream depleted in oxygen; wherein the zeolite ITQ-55 has a mean crystal particle size within the range of from about 0.1 microns to about 40 microns; wherein the feed stream is exposed to the zeolite ITQ-55 at effective conditions for performing a kinetic separation, in which the kinetic separation exhibits greater kinetic selectivity for oxygen than for nitrogen,
wherein the process is a swing adsorption process comprising an adsorption step performed at elevated pressure and/or reduced temperature in which the feed stream is passed through a bed of adsorbent comprising the zeolite ITQ-55 to adsorb oxygen from the feed stream, and a desorption step performed at reduced pressure and/or elevated temperature in which oxygen from the previous adsorption step is desorbed from the bed to regenerate the bed for the next adsorption step, and wherein the swing adsorption process is pressure swing adsorption (PSA) which is configured into a cryogenic air separation unit (ASU), wherein the configuration is a PSA+ASU hybrid configuration in which the PSA pre-concentrates oxygen by rejection of at least a part of nitrogen, or an ASU+PSA hybrid configuration in which the PSA is installed in an O 2 -rich stream after a high pressure (HP) section of the ASU purifies a part of O 2 .

10 . The process of claim 9 , wherein the bed of adsorbent is configured as a monolith having a plurality of parallel channels.

11 . The process of claim 9 , wherein the kinetic separation exhibits greater kinetic selectivity for oxygen than for nitrogen, at a temperature from about −195° C. to about 30° C., and at a pressure of about 1 bar (˜14.7 psi) to about 30 bar (˜435 psi).

12 . The process of claim 9 , wherein the zeolite ITQ-55 has a mean crystal particle size within the range of from about 0.5 microns to about 10 microns, or a mean crystal particle size within the range of from about 1 microns to about 5 microns.

13 . The process of claim 9 , which is a swing adsorption process comprising a feed step, one or more down equalization steps, a co-current or counter-current blow down and depressurization, one or more up equalization steps, and feed repressurization to achieve coproduction of high purity nitrogen having a concentration >97% and enriched oxygen having a concentration >25%.

14 . The process of claim 9 further comprising tuning kinetic selectivity and mass transfer rates by varying the mean crystal particle size of zeolite ITQ-55 within the range of from about 0.1 microns to about 40 microns, or by varying the adsorption temperature within the range from about −195° C. to about 30° C., or by varying the adsorption pressure within the range from about 1 bar (˜14.7 psi) to about 30 bar (˜435 psi), or combinations thereof.

Assignees

• Exxonmobil Technology & Engineering Company

Inventors

• Wang Yu
• Corcoran Jr Edward W
• Kortunov Pavel
• Corma Canos Avelino

Classifications

• B01D2259/402

  using two beds · CPC title

• B01D2257/80

  Water · CPC title

• B01D2257/104

  Oxygen · CPC title

• B01D2253/342

  Monoliths · CPC title

• B01D2253/304

  Linear dimensions, e.g. particle shape, diameter · CPC title