Mxene layers as substrates for growth of highly oriented perovskite thin films
US-2020240000-A1 · Jul 30, 2020 · US
US12467664B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12467664-B2 |
| Application number | US-202217831471-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 3, 2022 |
| Priority date | Dec 23, 2019 |
| Publication date | Nov 11, 2025 |
| Grant date | Nov 11, 2025 |
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An electrocaloric effect element includes a laminate including an electrode layer mainly including Pt and a ceramic layer that are stacked, in which the ceramic layer has a perovskite structure and mainly includes a ceramic including Pb, Sc, and Ta, where a content ratio of Sc is y, a content ratio of Ta is 1−y, and a range of the y is about 0.450≤y≤about 0.495.
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What is claimed is: 1 . An electrocaloric effect element comprising: a laminate including an electrode layer mainly including Pt and a ceramic layer that are stacked; wherein the electrode layer mainly includes Pt such that Pt has a largest % by mass in the electrode layer; the ceramic layer has a perovskite structure and mainly includes a ceramic including Pb, Sc, and Ta, a content ratio of Sc is y, a content ratio of Ta is 1-y, and a range of the y is about 0.450≤y≤about 0.495; and the ceramic layer mainly includes the ceramic such that the ceramic has a largest % by mass in the ceramic layer. 2 . The electrocaloric effect element according to claim 1 , wherein the ceramic layer in the laminate has a thickness of about 50 μm or less. 3 . An electronic component comprising the electrocaloric effect element according to claim 1 . 4 . The electronic component according to claim 3 , wherein the ceramic layer in the laminate has a thickness of about 50 μm or less. 5 . The electrocaloric effect element according to claim 1 , further comprising at least one external electrode connected to the electrode layer. 6 . The electrocaloric effect element according to claim 1 , wherein the electrode layer is an internal electrode layer provided in the laminate. 7 . The electrocaloric effect element according to claim 1 , wherein the Pt included in the electrode layer includes about 80% by mass or more of Pt. 8 . The electrocaloric effect element according to claim 1 , wherein the Pt included in the electrode layer includes about 95% by mass or more of Pt. 9 . The electrocaloric effect element according to claim 1 , wherein the Pt included in the electrode layer includes about 98% by mass or more of Pt. 10 . An electrocaloric effect element comprising: a laminate including an electrode layer mainly including Pt and a ceramic layer that are stacked; wherein the electrode layer mainly includes Pt such that Pt has a largest % by mass in the electrode layer; the ceramic layer has a perovskite structure and mainly includes a ceramic represented by a formula Pb x Sc y Ta 1-y O 3-σ , where x satisfies about 0.97≤x≤about 1.03, y satisfies about 0.450≤y≤about 0.495, and σsatisfies −0.1≤σ≤0.1; and the ceramic layer mainly includes the ceramic such that the ceramic has a largest % by mass in the ceramic layer. 11 . The electrocaloric effect element according to claim 10 , wherein x satisfies 0.985≤x≤1.015. 12 . The electrocaloric effect element according to claim 10 , wherein the ceramic layer in the laminate has a thickness of about 50 μm or less. 13 . An electronic component comprising the electrocaloric effect element according to claim 10 . 14 . The electronic component according to claim 13 , wherein x satisfies 0.985≤x≤1.015. 15 . The electronic component according to claim 13 , wherein the ceramic layer in the laminate has a thickness of about 50 μm or less. 16 . The electrocaloric effect element according to claim 10 , further comprising at least one external electrode connected to the electrode layer. 17 . The electrocaloric effect element according to claim 10 , wherein the electrode layer is an internal electrode layer provided in the laminate. 18 . The electrocaloric effect element according to claim 10 , wherein the Pt included in the electrode layer includes about 80% by mass or more of Pt. 19 . The electrocaloric effect element according to claim 10 , wherein the Pt included in the electrode layer includes about 95% by mass or more of Pt. 20 . The electrocaloric effect element according to claim 10 , wherein the Pt included in the electrode layer includes about 98% by mass or more of Pt.
by using electro-caloric effects · CPC title
Thermoelectric active materials · CPC title
Materials characterised by the absence of phases other than the main phase, i.e. single phase materials · CPC title
Phases present in the sintered or melt-cast ceramic products other than the main phase · CPC title
Products characterised by their size, e.g. microceramics · CPC title
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