Cationic uv-led radiation curable protective varnishes for security documents
US-2024209223-A1 · Jun 27, 2024 · US
US12466965B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12466965-B2 |
| Application number | US-202217856650-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 1, 2022 |
| Priority date | Jul 2, 2021 |
| Publication date | Nov 11, 2025 |
| Grant date | Nov 11, 2025 |
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Described herein are compositions useful for infusing color into nonwoven polyester containing product and methods to do so. Such compositions and methods comprise use of a color infusion composition comprising an antimigrant polymer; pigment; ammonium polyphosphate; and an anionic surfactant comprising phosphate. In certain embodiments, thermoplastic polymer having a glass transition temperature (Tg) of 93.0° C. or less is used to enhance color infusion.
Opening claim text (preview).
What is claimed is: 1 . A composition comprising: an antimigrant polymer comprising sodium polyacrylate; pigment; ammonium polyphosphate; and an anionic surfactant comprising polyoxyethylene branched tridecyl phosphate. 2 . The composition of claim 1 , wherein the antimigrant polymer has a viscosity of about 900 cps to about 5000 cps. 3 . The composition of claim 2 , wherein the antimigrant polymer has a pH of between 4.5 to 8.0. 4 . The composition of claim 1 , wherein the pigment is present in an amount from about 0.05% to about 20.0%, based on the weight of the composition. 5 . The composition of claim 1 , wherein the ammonium polyphosphate has a pH of about 6.5. 6 . The composition of claim 1 , wherein the ammonium polyphosphate has a viscosity of about 100 mPa·s at 25° C. 7 . A composition comprising: an antimigrant polymer; pigment; ammonium polyphosphate; a thermoplastic polymer having a glass transition temperature (Tg) of 93.0° C. or less; and an anionic surfactant comprising polyoxyethylene branched tridecyl phosphate. 8 . The composition of claim 7 , wherein the antimigrant polymer has a viscosity of about 900 cps to about 5000 cps. 9 . The composition of claim 8 , wherein the antimigrant polymer has a pH of between 5.5 to 8.0. 10 . The composition of claim 7 , wherein the pigment is present in an amount from about 0.05% to about 20.0%, based on the weight of the composition. 11 . The composition of claim 7 , wherein the thermoplastic polymer is selected from sulfonated polyester, poly(vinyl acetate), acrylic, and vinyl-acrylic. 12 . The composition of claim 7 , wherein the thermoplastic polymer is present in an amount from about 0.001% to about 60.0%, based on the dry weight of the product. 13 . The composition of claim 7 , wherein the ammonium polyphosphate is present in an amount ranging from about 25% to about 35% based on the total dry weight of the composition and wherein the thermoplastic polymer is present in an amount ranging from about 10.5% to about 36% based on the total dry weight of the composition. 14 . A nonwoven polyester product comprising a composition comprising: an antimigrant polymer comprising an acrylic copolymer; pigment; ammonium polyphosphate; and an anionic surfactant comprising polyoxyethylene branched tridecyl phosphate. 15 . The nonwoven polyester product of claim 14 , wherein the antimigrant polymer has a viscosity of about 900 cps to about 5000 cps; and wherein the antimigrant polymer has a pH of between 5.5 to 8.0. 16 . The nonwoven polyester product of claim 14 , wherein the antimigrant polymer is present in an amount of about 0.1 to about 3.0%, based on the dry weight of the product. 17 . The nonwoven polyester product of claim 14 , wherein the pigment is selected from phthalocyanines, naphthols, arylides, inorganics, inorganic oxides, carbon black, chromium oxide, or combinations thereof. 18 . The nonwoven polyester product of claim 14 , wherein the pigment is present in an amount from about 0.05% to about 20.0%, based on the dry weight of the product. 19 . The nonwoven polyester product of claim 14 , wherein the ammonium polyphosphate has a pH of about 6.5. 20 . The composition of claim 7 , wherein the antimigrant polymer comprises sodium polyacrylate.
organic · CPC title
Polyesters · CPC title
with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts · CPC title
Polyesters · CPC title
Homopolymers or copolymers of esters {(C09D143/04 takes precedence)} · CPC title
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