Catalyst composition for the production of hydrogen

Patent metadata

Field	Value
Publication number	US-12465906-B2
Application number	US-202117641775-A
Country	US
Kind code	B2
Filing date	Jun 3, 2021
Priority date	Aug 26, 2020
Publication date	Nov 11, 2025
Grant date	Nov 11, 2025

Abstract

The present disclosure relates to a catalyst composition comprising: (a) nickel; (b) at least one promoter selected from Cu Zn, Mo, Co, Mg, Ce, Ti, Zr, Fe, Pd, Ag, Pt, or combinations thereof; and (c) a support material, wherein, the nickel loading is in the range of 6-19 wt % and the at least one promoter loading is in the range of 0.2-5 wt % with respect to the support material. The present disclosure further discloses a process for preparing a catalyst composition and a process each for the production of hydrogen gas and carbon nanotubes. Also disclosed herein, is use of a catalyst composition for obtaining hydrogen gas and carbon nanotubes.

First claim

We claim:

1 . A catalyst composition for production of a methane off-gas and a carbon nanotube by a conversion of methane, wherein the methane off-gas includes 10-30 vol % of hydrogen and the carbon nanotube has purity in the range of 90-99%, said composition comprising:
nickel; promoter comprising of Cu and Zn; and a support material selected from steamed biochar and spent FCC equilibrium catalyst;
wherein the nickel loading is in the range of 6-10 wt % and the promoter loading is in the range of 0.2-5 wt % with respect to the support material;
wherein the steamed biochar has a surface area of 860 m 2 /g.

2 . The composition of claim 1 , wherein the at least one promoter loading is in the range of 1-5 wt % with respect to the support material.

3 . The composition of claim 1 , wherein the Cu loading is in the range of 0.5-4 wt % and Zn loading is in the range of 0.5-4 wt % with respect to the support material.

4 . The composition of claim 1 , wherein the steamed biochar has a pore volume in the range of 0.60-0.70 cc/g.

5 . The catalyst composition of claim 1 , wherein the steamed biochar is obtained from heating a raw support material selected from the group consisting of raw biochar sawdust, raw biochar rice straw, raw biochar rice husk, raw biochar bagasse, other agricultural wastes, and combinations thereof.

6 . A process for preparing the catalyst composition of claim 1 , the process comprising:
(a) contacting a salt of nickel and a salt of the promoter, a combination of Cu and Zn to obtain a mixture; (b) impregnating the mixture on to the support material to obtain an impregnated catalyst material; and (c) calcining the impregnated catalyst material to obtain the catalyst composition.

7 . The process of claim 6 , wherein the support material is steamed biochar obtained by steaming of raw support material selected from the group consisting of raw biochar sawdust, raw biochar rice straw, raw biochar rice husk, raw biochar bagasse, other agricultural wastes, and combinations thereof at a temperature in the range of 700 to 900° C. for a time period in the range of 5-10 hours.

8 . A process for the production of hydrogen gas from light hydrocarbon, comprising:
(a) adding the catalyst composition of claim 1 in a reactor; (b) passing the light hydrocarbon over a catalyst bed at a temperature in the range of 300-750° C. at atmospheric pressure for 20-50 hours; and (c) obtaining a product stream comprising hydrogen gas.

9 . The process of claim 8 , wherein the product stream is free of carbon monoxide and carbon dioxide.

10 . The process of claim 8 , wherein the process produces 10-30% of hydrogen gas of the total content of the light hydrocarbon.

11 . The process of claim 8 , wherein the product stream is processed to obtain carbon nanotubes.

12 . A process for the production of carbon nanotubes from a light hydrocarbon, comprising:
(a) adding the catalyst composition of claim 1 in a reactor; (b) passing the light hydrocarbon over a catalyst bed at a temperature in the range of 300-750° C. at atmospheric pressure for 20-50 hours; and (c) obtaining a product stream comprising hydrogen gas and a mixture; (d) processing the mixture to obtain carbon nanotubes.

13 . The process of claim 12 , wherein the product stream is free of carbon monoxide and carbon dioxide.

14 . The process of claim 12 , wherein the carbon nanotubes have purity in the range of 90-99%.

15 . The process of claim 8 , wherein the light hydrocarbon is selected from methane, ethane, propane, butane, ethylene, acetylene, or combinations thereof.

16 . The process of claim 8 , wherein the reactor is selected from fluidized bed reactor, moving bed reactor, fixed bed reactor, or rotating bed reactor.

Assignees

• Hindustan Petroleum Corp Ltd

Inventors

• Meesala Lavanya
• Kumar Pramod

Classifications

• C01B3/28

  using moving solid particles, e.g. fluidised bed technique · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J35/635

  0.5-1.0 ml/g · CPC title

• B01J35/617

  500-1000 m2/g · CPC title