Multimodal coatings for heat and fire resistance

Patent metadata

Field	Value
Publication number	US-12460092-B2
Application number	US-201917259475-A
Country	US
Kind code	B2
Filing date	Jul 10, 2019
Priority date	Jul 10, 2018
Publication date	Nov 4, 2025
Grant date	Nov 4, 2025

Abstract

A multimodal coating and method of coating a substrate are disclosed. The coating includes a structural framework; and a medium embedded in the structural framework forming an intumescent coating, the intumescent coating configured to undergo intumescent expansion of an outermost coating of the medium upon heating.

First claim

What is claimed is:

1 . A multimodal coating, the multimodal coating comprising:
a medium; a structural framework embedded in the medium forming an intumescent coating, the intumescent coating configured to undergo intumescent expansion of an outermost coating of the medium upon heating; and a metastable material, the metastable material including calcium oxalate, and wherein the metastable material is configured to absorb heat through endothermic reactions as the metastable material undergoes phase transitions.

2 . The coating according to claim 1 , wherein the structural framework is a one or more of a mechanical stiffening element, the mechanical stiffening element being selected from a ceramic and a structural biopolymer.

3 . The coating according to claim 2 , wherein the structural biopolymer is lignin.

4 . The coating according to claim 1 , wherein the medium is a thermally modifiable polymer matrix, the thermally modifiable polymer matrix being a wax or hydrolyzed polyvinyl alcohol (PVA).

5 . The coating according to claim 1 , further comprising:
a substrate configured to receive the multimodal coating; and an organic layer under the intumescent coating and on an upper surface of the substrate.

6 . The coating according to claim 5 , wherein the organic layer is polyvinyl alcohol (PVA), Polyacrylonitrile (PAN), a biopolymer, plant-based tannin-polysaccharides, and/or a biophenol, and wherein the organic layer is configured to graphitize in a reducing environment provided by intumescent bubbles.

7 . The coating according to claim 6 , further comprising:
a transition metal or an additive in the organic layer, wherein the transition metal is one or more of iron (Fe), nickel (Ni), and cobalt (Co), and the additive is one or more of metal salts, metal ions, and metal nanoparticles.

8 . The coating according to claim 6 , comprising:
a plurality of alternating layers of the organic layer and the intumescent coating.

9 . The coating according to claim 5 , further comprising:
a plurality of layers of anisotropic insulating and potentially porous materials configured to disrupt continuous phonon transport, the plurality of layers of the anisotropic insulating and potentially porous materials including a suspension of anisotropic ceramic nanowires or glass nanowires in an aqueous polymer matrix.

10 . The coating according to claim 1 , wherein the structural framework comprises one or more of metals, alloys, and ceramics, and the structural framework has a geometry comprising one or more of a particulate, columnar, a hollow shape, a solid shape, and a foamy geometry with preexisting interconnected voids.

11 . The coating according to claim 5 , wherein the substrate is a plurality of substrates, the plurality of substrates having different surface roughness, curvatures, and geometries.

12 . The coating according to claim 1 , where the metastable material further comprises:
one or more of a metastable phase of a metal oxide, a carbide, a nitride, a phosphide, a sulfide, an oxalate, an anatase phase TiO 2 , silicon carbide, and boron nitride.

13 . A method of coating a substrate with the multimodal coating of claim 1 , the method comprising:
generating the medium; embedding the structured framework in the medium forming the intumescent coating; adding the metastable material on the substrate; and adding waxes to assist with a reversible phase transitioning of the metastable material.

14 . The method according to claim 13 , wherein the structural framework is a mechanical stiffening element, the mechanical stiffening element being a ceramic or a structural biopolymer, and wherein the medium is a thermally modifiable polymer matrix, the polymer matrix being a wax or hydrolyzed polyvinyl alcohol (PVA), the method further comprising:
depositing the multimodal coating on the substrate; and depositing an organic layer under the intumescent layer and on an upper surface of the substrate, where the organic layer has the potential to graphitize in a reducing environment provided by the intumescent bubbles.

15 . The method according to claim 14 , wherein the organic layer is selected from one or more of the following: polyvinyl alcohol (PVA), polyacrylonitrile (PAN), a biopolymer, plant-based tannin-polysaccharides, and a biophenol, the method comprising:
graphitizing the organic layer in a reducing environment provided by intumescent bubbles; and adding a transition metal or an additive to the organic layer, and wherein the transition metal is one or more of Iron (Fe), Nickel (Ni), or Cobalt (Co), and the additive is one or more of metal salts, metal ions, and metal nanoparticles.

16 . The method according to claim 15 , further comprising:
adding a plurality of layers of anisotropic insulating and potentially porous materials, whereby the layers of anisotropic insulating and potentially porous materials disrupt continuous phonon transport; sandwiching transition metal ions and nanoparticles between polymeric/composite/ceramic layers, and wherein the transition metal ions and nanoparticles are configured to enable thermal conversion of polymers into ordered graphite; and adding ceramic foams filled with reversible phase transitioning waxes.

17 . The method according to claim 16 , wherein the adding the plurality of layers of anisotropic insulating and potentially porous materials comprises:
suspending anisotropic ceramic nanowires or glass nanowires in an aqueous polymer matrix; and depositing the ceramic nanowires or the glass nanowires in the aqueous polymer matrix on substrate by using 3-D printing, Langmuir-Blodgett coating, spin coating, dip coating, melt spinning, electrospinning, centrifugal jet spinning, or spray coating.

18 . The method according to claim 16 , further comprising:
generating a flexible wearable fabric by adding aromatic biopolymers into 3D printed designs and electrospun nanofibers.

19 . A method of coating a substrate with the multimodal coating of claim 1 , the method comprising:
applying an organic with a decomposition temperature tuned between 110° C. to 1000° C. to the substrate, the organic being an oligomer; and adding a waxy layer of a reversible phase transitioning wax on an upper surface of the organic, and wherein the organic forms an inner layer, and wherein upon exposure to heat, the inner layer decomposes and outgases, and wherein the waxy layer is configured to soften and enable expansion to afford formation of interlayers of pores filled with gas to reduce thermal conduction.

20 . The coating according to claim 5 , further comprising:
the metastable material includes a plurality of coatings of a metastable material on the substrate; transition metal ions and nanoparticles sandwiched between the plurality of coatings of the metastable material, and wherein the transition metal ions and nanoparticles are configured to enable thermal conversion of polymers into ordered graphite; and ceramic foams filled with reversible phase transitioning waxes configured to aid in energy absorption, or aromatic biopolymers, the aromatic biopolymers comprising lignin and tannins in 3D printed designs and electrospun nanofibers.

Assignees

• Univ California

Inventors

• Kisailus David
• Mohan Ramya

Classifications

• C09D197/005

  Lignin · CPC title

• C09D161/06

  of aldehydes with phenols · CPC title

• C09D133/20

  Homopolymers or copolymers of acrylonitrile (C09D155/02 takes precedence) · CPC title

• C09D129/04 Primary

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• C09D105/00

  Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00 · CPC title