Polymer composition for blow molding

Patent metadata

Field	Value
Publication number	US-12460071-B2
Application number	US-201917289078-A
Country	US
Kind code	B2
Filing date	Nov 14, 2019
Priority date	Nov 15, 2018
Publication date	Nov 4, 2025
Grant date	Nov 4, 2025

Abstract

A polymer composition is provided, where the polymer composition includes
(A) a polyolefin; (B) one or more impact modifier(s); (C) one or more fluoropolymer(s); (D) one or more clarifying agent(s); and (E) one or more dispersing agent(s) in an amount of equal to or more than 100 ppm, based on the total weight amount of the polymer composition.

An article including the polymer composition and the use of the polymer composition for reducing haze and improving gloss of an extrusion blow molded (EBM) bottle are also provided.

First claim

The invention claimed is:

1 . A polymer composition comprising:
(A) from 85 to 96 wt % of a multimodal propylene random copolymer; (B) from 4.0 to 6.0 wt % of a multimodal copolymer of ethylene with one or more comonomer units selected from alpha-olefins having from 4 to 8 carbon atoms; (C) from 150 to 750 ppm of a terpolymer of vinylidene fluoride, tetrafluoroethylene, and hexafluoropropylene; (D) from 250 to 1000 ppm of 1,3:2,4-bis(3,4-dimethylbenzylidene) sorbitol (DMDBS); and (E) from 130 to 300 ppm of polyethylene glycol, wherein all weight amounts are based on the total weight amount of the polymer composition.

2 . The polymer composition according to claim 1 , wherein the weight ratio of the terpolymer of vinylidene fluoride, tetrafluoroethylene, and hexafluoropropylene (C) to the polyethylene glycol (E) in the polymer composition is in the range of from 1.2:1 to 4:1.

3 . The polymer composition according to claim 1 having a melt flow rate MFR 2 (2.16 kg, 230° C.) of from 1.0 to 5.0 g/10 min.

4 . An article comprising the polymer composition according to claim 1 .

5 . The article according to claim 4 being a blow molded article.

6 . The article according to claim 4 being an extrusion blow molded (EBM) bottle.

7 . The article according to claim 6 having a haze of not more than 35.0%, measured according to ASTM D 1003.

8 . The article according to claim 6 having a gloss at an angle of 20° C. on the inner side of the bottle of at least 31.0% and/or a gloss at an angle of 20° C. on the outer side of the bottle of at least 32.0%.

9 . The article according to claim 6 having gloss at an angle of 60° C. on the inner side of the bottle of at least 94.0% and/or a gloss at an angle of 60° C. on the outer side of the bottle of at least 93.0%.

10 . The article according to claim 6 having at least one of the following properties:
a bottle quality index at an angle of 20° (BQI-20) of at least 1.54, calculated as follows:
BQI-20=log((gloss 20IN·gloss 20 OUT·thickness)/haze);

a bottle quality index at an angle of 60° (BQI-60) of at least 2.48, calculated as follows:
BQI-60=log((gloss 60IN·gloss 60OUT·thickness)/haze);

and/or
a combined bottle quality index (BQF) of at least 2.53, calculated as follows:
BQF=log(((gloss 20 IN·gloss 20 OUT)+(gloss 60IN·gloss 60 OUT)·thickness)/haze).

Assignees

• Abu Dhabi Polymers Co Ltd Borouge
• Borealis Ag

Inventors

• Klimke Katja
• Van Cauwenberghe Hans Jozef Francois
• Abboud Philippe

Classifications

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L2203/10

  used for bottles · CPC title

• B29L2031/7158

  Bottles · CPC title

• B29K2995/0022

  Bright, glossy or shiny surface · CPC title

• B29K2427/18

  PTFE, i.e. polytetrafluoroethylene {, e.g. ePTFE, i.e. expanded polytetrafluoroethylene} · CPC title