Method for removing halogen fluoride, quantitative analysis method for gas component contained in halogen fluoride mixed gas, and quantitative analyzer
US-2022054972-A1 · Feb 24, 2022 · US
US12459880B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12459880-B2 |
| Application number | US-202118011416-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 16, 2021 |
| Priority date | Aug 24, 2020 |
| Publication date | Nov 4, 2025 |
| Grant date | Nov 4, 2025 |
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There is provided a halon purification method capable of simply, safely, and efficiently removing mixed bromine molecules to obtain high purity halon. The halon purification method is a method for removing bromine molecules from crude halon containing halon and the bromine molecules, and the method includes: a contact step of bringing the crude halon into contact with an absorbing liquid containing an aqueous solution containing metal iodide to obtain a mixed liquid containing the crude halon and the absorbing liquid; and a separation step of separating the halon from the mixed liquid to obtain the halon and the absorbing liquid having absorbed the bromine molecules.
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The invention claimed is: 1 . A halon purification method for removing bromine molecules from crude halon containing halon and the bromine molecules, the method comprising: a contact step of bringing the crude halon into contact with an absorbing liquid containing an aqueous solution containing metal iodide to obtain a mixed liquid containing the crude halon and the absorbing liquid; and a separation step of separating the halon from the mixed liquid to obtain the halon and the absorbing liquid having absorbed the bromine molecules. 2 . The halon purification method according to claim 1 , wherein the metal iodide is at least one selected from alkali metal iodides and alkaline earth metal iodides. 3 . The halon purification method according to claim 1 , wherein the metal iodide is potassium iodide. 4 . The halon purification method according to claim 1 , wherein the crude halon in a gaseous state is brought into contact with the absorbing liquid in the contact step, and the halon in a gaseous state is extracted from the mixed liquid by gas-liquid extraction in the separation step. 5 . The halon purification method according to claim 1 , wherein a number of carbons of the halon is 1 or more and 3 or less. 6 . The halon purification method according to claim 1 , wherein a number of carbons of halon is 1 or 2. 7 . The halon purification method according to claim 1 , wherein the halon is at least one of bromomethane, tribromofluoromethane, bromodifluoromethane, dibromodifluoromethane, bromotrifluoromethane, bromoethane, dibromotrifluoroethane, dibromotetrafluoroethane, tribromotrifluoroethane, bromofluoroethylene, bromodifluoroethylene, and bromotrifluoroethylene. 8 . The halon purification method according to claim 1 , wherein the absorbing liquid further contains potassium iodate or sodium iodate. 9 . The halon purification method according to claim 2 , wherein the crude halon in a gaseous state is brought into contact with the absorbing liquid in the contact step, and the halon in a gaseous state is extracted from the mixed liquid by gas-liquid extraction in the separation step. 10 . The halon purification method according to claim 3 , wherein the crude halon in a gaseous state is brought into contact with the absorbing liquid in the contact step, and the halon in a gaseous state is extracted from the mixed liquid by gas-liquid extraction in the separation step. 11 . The halon purification method according to claim 2 , wherein a number of carbons of the halon is 1 or more and 3 or less. 12 . The halon purification method according to claim 3 , wherein a number of carbons of the halon is 1 or more and 3 or less. 13 . The halon purification method according to claim 4 , wherein a number of carbons of the halon is 1 or more and 3 or less. 14 . The halon purification method according to claim 2 , wherein a number of carbons of halon is 1 or 2. 15 . The halon purification method according to claim 3 , wherein a number of carbons of halon is 1 or 2. 16 . The halon purification method according to claim 4 , wherein a number of carbons of halon is 1 or 2. 17 . The halon purification method according to claim 2 , wherein the halon is at least one of bromomethane, tribromofluoromethane, bromodifluoromethane, dibromodifluoromethane, bromotrifluoromethane, bromoethane, dibromotrifluoroethane, dibromotetrafluoroethane, tribromotrifluoroethane, bromofluoroethylene, bromodifluoroethylene, and bromotrifluoroethylene. 18 . The halon purification method according to claim 3 , wherein the halon is at least one of bromomethane, tribromofluoromethane, bromodifluoromethane, dibromodifluoromethane, bromotrifluoromethane, bromoethane, dibromotrifluoroethane, dibromotetrafluoroethane, tribromotrifluoroethane, bromofluoroethylene, bromodifluoroethylene, and bromotrifluoroethylene. 19 . The halon purification method according to claim 4 , wherein the halon is at least one of bromomethane, tribromofluoromethane, bromodifluoromethane, dibromodifluoromethane, bromotrifluoromethane, bromoethane, dibromotrifluoroethane, dibromotetrafluoroethane, tribromotrifluoroethane, bromofluoroethylene, bromodifluoroethylene, and bromotrifluoroethylene. 20 . The halon purification method according to claim 2 , wherein the absorbing liquid further contains potassium iodate or sodium iodate.
Bromine · CPC title
Halogens or halogen compounds · CPC title
of potassium · CPC title
of sodium · CPC title
Selection of liquid materials for use as absorbents · CPC title
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