Manufacture of green compacts from Na-β-aluminate

Patent metadata

Field	Value
Publication number	US-12459869-B2
Application number	US-202017771516-A
Country	US
Kind code	B2
Filing date	Nov 2, 2020
Priority date	Nov 6, 2019
Publication date	Nov 4, 2025
Grant date	Nov 4, 2025

Abstract

The invention relates to a method for manufacturing of a sinterable green body from sodium-β-aluminate- and/or precursor-particles bonded via binders by means of slip casting, wherein a castable slip containing the particles as well as dispersants and binders is introduced into a casting mold and, after solidification, is demolded as a green body.

First claim

The invention claimed is:

1 . A method for manufacturing sinterable green bodies from sodium-β-aluminate- and/or precursor-particles bonded via binders, said method comprising:
providing a casting mold formed from aggregate particles bonded with organic and/or inorganic binders, wherein the casting mold is provided by pouring a pourable mixture comprising the aggregate particles and the organic and/or inorganic binders into a negative of the casting mold and, after a partial setting and drying of the pourable mixture, removing the casting mold from the negative and drying it further;
introducing a castable slip containing the sodium-β-aluminate- and/or precursor-particles as well as dispersants and binders into the casting mold and, after solidification, demolding it as a sinterable green body; and
reusing the casting mold, wherein
the castable slip is an aqueous suspension,

the aggregate particles are particles of polyethylene glycol, titanium oxide, aluminum oxide, sodium aluminate or silicate, or mixtures thereof,
the inorganic binders are cementitious mixtures containing lime, and
the organic binders are selected from epoxy, phenolic, or polyester resins.

2 . The method according to claim 1 , wherein the Na-β-aluminate- and/or precursor-particles of the castable slip have a size distribution with a median-grain-size (d 50 -value) of below 10 μm.

3 . The method according to claim 1 , wherein the castable slip comprises 30-95 wt. % of the Na-β-aluminate- and/or precursor-particles, 10-60 wt. % of water and up to 30 wt. % of other constituents in the form of the dispersants, organic binders and optionally further auxiliaries.

4 . The method according to claim 1 , wherein the dispersants of the castable slip comprises of organic dispersants comprising carboxylic acids or other organic surfactants.

5 . The method according to claim 1 , wherein the binders in the castable slip comprise of organic binders.

6 . The method according to claim 1 , wherein the castable slip is free of organic solvents and/or free of acid.

7 . The method according to claim 1 , wherein the castable slip is prepared prior to the step of introducing the castable slip into the casting mold by mixing the Na-β-aluminate- and/or precursor-particles with water and the dispersants and the binders.

8 . The method according to claim 7 , wherein the mixing of the Na-β-aluminate- and/or precursor-particles with the water as well as the dispersants and the binders is carried out in a mill and that during the mixing the Na-β-aluminate- and/or precursor-particles are simultaneously comminuted.

9 . The method according to claim 1 , wherein the casting mold comprises 50-99 wt. % of the aggregate particles, wherein the proportion of the inorganic binder is up to 50 wt. % and the proportion of the organic binder is up to 20 wt. %.

10 . The method according to claim 1 , wherein the dwell time of the castable slip in the casting mold is between 5 and 20 minutes and/or in that the castable slip is pressurized during dwelling in the casting mold.

11 . The method according to claim 1 , wherein the sinterable green body is dried after expiry of a dwell time in the casting mold or after demolding thereof.

12 . The method according to claim 1 , wherein the sinterable green body is a hollow body closed on one side.

13 . A method for manufacturing a ceramic molded body from sintered sodium-β-aluminate-particles, comprising manufacturing the sinterable green body according to claim 1 and firing the sinterable green body.

14 . A method for manufacturing a sodium-high-temperature-battery comprising manufacturing the ceramic molded body according to claim 13 and using said ceramic molded body as a ceramic electrolyte within said sodium-high-temperature-battery.

15 . The method according claim 1 , wherein the castable slip comprises 50-85 wt. % of the Na-β-aluminate- and/or precursor-particles, 25-45 wt. % of water and up to 20 wt. % of other constituents in the form of the dispersants, organic binders, and optionally further auxiliaries.

16 . The method according to claim 1 , wherein the binders in the castable slip comprise (poly) saccharides, PVA, or carboxylic acids.

17 . The method according to claim 1 , wherein the castable slip is prepared prior to the step of introducing the castable slip into the casting mold by mixing the Na-β-aluminate- and/or precursor-particles with water and the dispersants and the binders, the castable slip being deaerated by applying a vacuum during or after mixing.

18 . The method according to claim 1 , wherein the casting mold comprises 70-90 wt. % of the aggregate particles, wherein the proportion of the inorganic binder is up to 30 wt. % and the proportion of the organic binder is up to 15 wt. %.

19 . The method according to claim 1 , wherein the sinterable green body is dried after expiry of a dwell time in the casting mold or after demolding thereof, the drying taking place under normal pressure.

Assignees

• Fraunhofer Ges Forschung
• Roesler Ceram Gmbh

Inventors

• Roesler Johannes
• Dirksen Cornelius
• Schulz Matthias
• Weidl Roland

Classifications

• C04B2235/6027

  Slip casting · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M10/39

  working at high temperature · CPC title

• C04B2235/602

  Making the green bodies or pre-forms by moulding · CPC title

• C04B2235/3222

  Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4) · CPC title