Boron doped cement and concrete

Patent metadata

Field	Value
Publication number	US-12459866-B2
Application number	US-202117919692-A
Country	US
Kind code	B2
Filing date	Apr 20, 2021
Priority date	Apr 21, 2020
Publication date	Nov 4, 2025
Grant date	Nov 4, 2025

Abstract

Aspects of the present disclosure provide for cement, cement paste, cementitious paste, cementitious mortar, and concrete, methods of making cement, cement paste, cementitious paste, cementitious mortar, and concrete, structures incorporating the concrete, and the like, where the cement, cement paste, cementitious paste, cementitious mortar, and the concrete include elemental boron and/or one or more boron compounds (e.g., boron-doped cement, cement paste, cementitious paste, cementitious mortar, and concrete). The boron and/or a boron compound can be homogeneously distributed throughout the cement, cement paste, cementitious paste, cementitious mortar and/or concrete.

First claim

We claim:

1 . A concrete composition comprising: a cement paste, a fine aggregate, a coarse aggregate, and an admixture, wherein the admixture is selected from a mineral admixture and a liquid admixture, wherein the mineral admixture, the liquid admixture, or both comprise boron particles, wherein the boron particles comprise a boron compound, wherein the boron particles are dispersed homogeneously in the concrete composition, wherein the boron compound is one of the following: 1) an organoboron compound; 2) a borate ester or their hydrated form; or 3) an ionic borohydride.

2 . The concrete composition of claim 1 , wherein the admixture is the mineral admixture, wherein the mineral admixture comprises the boron particles.

3 . The concrete composition of claim 1 , wherein the admixture is the liquid admixture, wherein the liquid admixture comprises the boron particles.

4 . The concrete composition of claim 1 , wherein the fine aggregate includes fine aggregate particles, wherein the boron particles comprise a coating for the fine aggregate particles, wherein the fine aggregate particles are selected from the group consisting of: natural or synthetic sand, crushed stone, and gravel; wherein the coarse aggregate includes coarse aggregate particles, wherein the boron particles comprise a coating for the coarse aggregate particles, wherein the coarse aggregate particles are selected from the group consisting of: natural or synthetic sand, crushed stone, and gravel.

5 . The concrete composition of claim 4 , wherein the coating for the fine aggregate particles, the coating for the coarse aggregate particles, or both, reduces radiation-induced volumetric expansion of the one or more types of the fine aggregate particles and the coarse aggregate particles relative to concrete that does not include the coating.

6 . The concrete composition of claim 1 , wherein the boron content in the concrete composition is about 0.5-80 kg/m 3 .

7 . The concrete composition of claim 6 , wherein a 10 B abundance percentage in the boron compound is greater than the natural abundance of about 20 percent.

8 . The concrete composition of claim 6 , wherein the inclusion of the boron compound does not reduce concrete workability by more than 10% as measured by a slump cone in accordance with ASTM C143 relative to otherwise identical composition without the boron compound.

9 . The concrete composition of claim 6 , wherein the inclusion of the boron compound does not increase concrete initial or final setting times by more than 5% as measured by a penetration resistance in accordance with ASTM C403 relative to otherwise identical composition without the boron compound.

10 . The concrete composition of claim 6 , wherein the inclusion of the boron compound does not reduce concrete compressive strength by more than 20% as measured on cylindrical concrete specimens in accordance with ASTM C39 relative to otherwise identical composition without the boron compound.

11 . A concrete composition comprising: a cement paste, a fine aggregate, and a coarse aggregate, wherein the cement paste includes homogeneously dispersed cement particles, water, and boron particles, wherein the boron particles comprise a boron compound, wherein the boron particles have a largest least dimension of about 1 micron to 100 microns, wherein the boron particles are dispersed homogeneously in the cement paste, wherein the boron content in the cement paste is about 0.5-80 kg/m 3 , wherein the boron compound is one of the following: 1) an organoboron compound; 2) a borate ester or their hydrated form; or 3) an ionic borohydride.

12 . The concrete composition of claim 11 , wherein the fine aggregate includes fine aggregate particles, wherein the boron particles comprise a coating for the fine aggregate particles, wherein the fine aggregate particles are selected from the group consisting of: natural or synthetic sand, crushed stone, and gravel; wherein the coarse aggregate includes coarse aggregate particles, wherein the boron particles comprise a coating the coarse aggregate particles, wherein the coarse aggregate particles are selected from the group consisting of: natural or synthetic sand, crushed stone, and gravel.

13 . The concrete composition of claim 11 , wherein a 10 B abundance percentage in the boron compound is greater than the natural abundance of about 20 percent.

14 . The concrete composition of claim 11 , wherein the cement paste including the boron compound does not increase concrete initial or final setting times by more than 5% as measured by a penetration resistance in accordance with ASTM C403 relative to otherwise identical composition without the boron compound.

15 . The concrete composition of claim 11 , wherein the cement paste including the boron compound does not reduce concrete compressive strength by more than 20% as on measured cylindrical concrete specimens in accordance with ASTM C39 relative to otherwise identical composition without the boron compound.

16 . A concrete composition comprising: fine aggregate particles and coarse aggregate particles, wherein the fine aggregate particles and coarse aggregate particles each have a neutron shielding coating comprising a boron compound, wherein the boron compound is part of boron particles that have a largest least dimension of 1 micron to 100 microns, wherein the fine aggregate particles are selected from the group consisting of: natural or synthetic sand, crushed stone, and gravel, wherein the coarse aggregate particles are selected from the group consisting of: natural or synthetic sand, crushed stone, and gravel, wherein the boron content in the concrete composition is about 0.5-80 kg/m 3 , wherein the boron compound is one of the following: 1) an organoboron compound; 2) a borate ester or their hydrated form; or 3) an ionic borohydride.

Assignees

• Univ Florida
• Rj Lee Group Inc
• Electric Power Res Institute Inc

Inventors

• Ferraro Christopher C
• Paris Jerry M
• Baciak James E
• Riding Kyle A
• Patel Ashish D
• Scott David B
• Giannini Eric R

Classifications

• C04B2111/00862

  for nuclear applications, e.g. ray-absorbing concrete · CPC title

• C04B20/1055

  with inorganic materials · CPC title

• G21F1/042

  Concretes combined with other materials dispersed in the carrier · CPC title

• C04B28/065

  Calcium aluminosulfate cements, e.g. cements hydrating into ettringite · CPC title

• C04B28/06

  Aluminous cements (monolithic refractories or refractory mortars C04B35/66) · CPC title