Method for preparing a porous carbonaceous substrate having carbon nanotubes on its surface and its body

Patent metadata

Field	Value
Publication number	US-12459822-B2
Application number	US-201917269082-A
Country	US
Kind code	B2
Filing date	Aug 20, 2019
Priority date	Aug 21, 2018
Publication date	Nov 4, 2025
Grant date	Nov 4, 2025

Abstract

A method for providing a substrate made of a porous carbonaceous material with vertically aligned carbon nanotubes, the method having a first step of depositing a ceramic underlayer on the substrate followed by a second step of synthesizing, by catalytic chemical vapour deposition, the vertically aligned carbon nanotubes on the substrate obtained after the first step, the carbon source necessary for the synthesis during this second step being injected in a direction substantially perpendicular to the plane of the substrate and at a pressure less than 8104 Pa (800 mbar). The use of the substrate for preparing an electrode such as a supercapacitor electrode.

First claim

What is claimed is:

1 . A method for providing a substrate made of a porous carbonaceous material with vertically aligned carbon nanotubes on a surface and in a body thereof,
said method having a first step of depositing a ceramic sublayer on said substrate followed by a second synthesis step, by catalytic chemical vapour deposition, of said vertically aligned carbon nanotubes on the substrate obtained following the first step, to obtain a substrate having vertically aligned carbon nanotubes on the surface and in the body thereof, and wherein the vertically aligned carbon nanotubes on the surface and in the body of the substrate are vertically aligned relative to the plane of the substrate; and wherein a carbon source required for the synthesis during the second step is injected in a substantially perpendicular direction to the plane of the substrate and at a pressure between 3×10 4 Pa and 6×10 4 Pa.

2 . The method according to claim 1 , wherein said substrate made of a porous carbonaceous material is presented in the form of carbon fibres or a carbon foam.

3 . The method according to claim 1 , wherein said ceramic is an oxide ceramic.

4 . The method according to claim 1 , wherein said carbon source is co-injected with a catalytic source required for synthesis during said second step.

5 . The method according to claim 1 , wherein said first step and said second step are carried out in the same reaction chamber.

6 . The method according to claim 1 , wherein said first step and said second step are carried out respectively in a first chamber and in a second chamber.

7 . A method for preparing an electrode comprising a substrate made of a porous carbonaceous material, vertically aligned carbon nanotubes on the surface and in the body thereof and an electrically conducting polymer matrix, said method comprising the following successive steps:
a) providing a substrate made of a porous carbonaceous material with vertically aligned carbon nanotubes nanotubes on the surface and in the body thereof according to the method as defined in claim 1 ; b) depositing said polymer matrix electrochemically on said carbon nanotubes using an electrolytic solution comprising at least one precursor monomer of said matrix.

8 . The method according to claim 7 , wherein, following said step (a) and prior to said step (b), the vertically aligned carbon nanotubes are subjected to an oxidising treatment.

9 . The method according to claim 7 , wherein said electrochemical deposition method is carried out using a pulsed or continuous galvanostatic method.

10 . The method according to claim 7 , wherein, following said step (b), the method has a rinsing step and optionally a drying step.

11 . The method according to claim 7 , wherein said electrochemical deposition method is carried out using a pulsed or continuous potentiostatic method.

12 . The method according to claim 1 , wherein said ceramic is a silicon oxide of formula SiO x , where 0<x≤2.

13 . A method for providing a substrate made of a porous carbonaceous material with vertically aligned carbon nanotubes on a surface and in a body thereof,
said method having a first step of depositing a ceramic sublayer on said substrate followed by a second synthesis step, by catalytic chemical vapour deposition, of said vertically aligned carbon nanotubes on the substrate obtained following the first step, to obtain a substrate having vertically aligned carbon nanotubes on the surface and in the body thereof, and wherein the vertically aligned carbon nanotubes on the surface and in the body of the substrate are vertically aligned relative to the plane of the substrate; and wherein a carbon source required for the synthesis during the second step is injected in a substantially perpendicular direction to the plane of the substrate and at a pressure between 3.10 4 Pa and 6.10 4 Pa; and wherein the first step of depositing the ceramic sublayer on the substrate comprises injecting ceramic sublayer precursors on the substrate in a substantially perpendicular direction to the plane of the substrate and at a pressure between 3×10 4 Pa and 6×10 4 Pa.

Assignees

• Nawatechnologies
• Commissariat Energie Atomique
• Cy Cergy Paris Univ
• Univ Tours

Inventors

• Aubert Pierre-Henri
• Banet Philippe
• Boisset Aurélien
• Darchy Léa
• Descarpentries Jérémie
• Ghamouss Fouad
• Hauf Harald
• Mayne Martine
• Pinault Mathieu
• Tran Van François

Classifications

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/624

  Electric conductive fillers · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/0428

  Chemical vapour deposition · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title